近临界特性的地层水及其对烃源岩生排烃过程的影响

郑伦举; 何生; 秦建中; 马中良

doi:10.3799/dqkx.2011.009

Volume 36 Issue 1

Jan. 2011

Turn off MathJax

Article Contents

Article Navigation > Earth Science > 2011 > 36(1): 83-92

ZHENG Lun-ju, HE Sheng, QIN Jian-zhong, MA Zhong-liang, 2011. Formation Water of Near-Critical Properties and Its Effects on the Processes of Hydrocarbon Generation and Expulsion. Earth Science, 36(1): 83-92. doi: 10.3799/dqkx.2011.009

Citation:

ZHENG Lun-ju, HE Sheng, QIN Jian-zhong, MA Zhong-liang, 2011. Formation Water of Near-Critical Properties and Its Effects on the Processes of Hydrocarbon Generation and Expulsion. Earth Science, 36(1): 83-92. doi: 10.3799/dqkx.2011.009

Citation:

ZHENG Lun-ju, HE Sheng, QIN Jian-zhong, MA Zhong-liang, 2011. Formation Water of Near-Critical Properties and Its Effects on the Processes of Hydrocarbon Generation and Expulsion. Earth Science, 36(1): 83-92. doi: 10.3799/dqkx.2011.009

PDF( 366 KB)

Formation Water of Near-Critical Properties and Its Effects on the Processes of Hydrocarbon Generation and Expulsion

doi: 10.3799/dqkx.2011.009

1.
Key Laboratory of Tectonics and Petroleum Resources of Ministry of Education, China University of Geosciences, Wuhan 430074, China
2.
Exploration and Development Research Institute, SINOPEC, Wuxi Research Institute of Petroleum Geology, Wuxi 214151, China

Received Date: 2010-05-31
Publish Date: 2011-01-01

Abstract

Abstract

A special simulation experimental device using a high pressure liquid water system in the similar geological pore space with fluid pressures around 38±2 MPa and temperatures ranging from 290 ℃ to 390 ℃ is used to simulate hydrocarbon generation and expulsion from source rocks in this study. The new experimental results show many important phenomena about the generation and expulsion influenced by high-pressure liquid water linking with fluid pressure and pore space. It is found that high-pressure liquid water medium condition facilitates the generation and preservation of liquid oil and improves the potential of hydrocarbon generation from kerogen and the efficiency of oil expulsion but it is not conducive to the conversion of liquid hydrocarbon to gaseous hydrocarbon. It is considered that these new experimental phenomena may be mainly related to the effects of high-pressure liquid water of near-critical properties. It is further inferred that the high-pressure liquid water of near-critical characteristics is involved in the conversion of kerogen to oil and gas reactions, to increase the solubility of the oil and gas in water. Under the appropriate geological conditions, hydrocarbon generation and expulsion from source rocks occur at temperatures ranging from 100 ℃ to 200 ℃ and pressures ranging from 30 MPa to 120 MPa in most cases, suggesting that actual formation pore water could be a compressed state liquid water with near-critical properties at a relatively low temperature and high-pressure environment. This high-pressure liquid water of near-critical characteristics may have important effect on the processes of petroleum generation and expulsion. However, the mechanism and geological significance for petroleum exploration of these phenomena are still not clear. Further studies are necessary for such simulation experiments under high pressure liquid water condition for better understanding of the actual roles of the factors such as the near-critical water medium, fluid pressure and pore space. It is believed that this study may assist to establish the improving models of dynamics of hydrocarbon generation and expulsion in geological scale.

FullText(HTML)

References(68)

References

Carr, A.D., Snape, C.E., Meredith, W., et al., 2009. The effect of water pressure on hydrocarbon generation reactions: some inferences from laboratory experiments. Petroleum Geoscience, 15: 17-26. doi: 10.1144/1354-079309-797

Chen, J.Y., Liu, G.Y., Jin, L.J., 2009. Water in the earth's interior and abiotic formation of hydrocarbon. Earth Science Frontiers, 16(1): 33-40 (in Chinese with English abstract).

Chen, J.Y., Zhang, H., Zheng, H.F., et al., 2006. Insitu visualization of pyrolysis of organic matter in high-temperature and high-pressure water—taking kerogen and asphalt as an example. Petroleum Geology & Experiment, 28(1): 73-77 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-SYSD200601013.htm

Chen, X.D., Wang, X.B., 1999. Pressure effect on organic matter maturation and petroleum generation. Advance in Earth Sciences, 14(1): 31-36 (in Chinese with English abstract). http://www.researchgate.net/publication/308019972_Pressure_effect_on_organic_matter_maturation_and_petroleum_generation

Cheng, K.M., Wang, Z.Y., Zhong, N.N., et al., 1996. Theory and practice of oil and gas's generation in carbonate rock. Petroleum Industry Press, Beijing, 139-175 (in Chinese).

Evans, R.J., Felbeck, G.T., 1983a. High temperature simulation of petroleum formation—(Ⅰ) the pyrolysis of Green River Shale. Org. Geochem. , 4: 135-144. doi: 10.1016/0146-6380(83)90034-7

Evans, R.J., Felbeck, G.T., 1983b. High temperature simulation of petroleum formation—(Ⅱ) effect of inorganic sedimentary constituents on hydrocarbon formation. Org. Geochem. , 4: 145-152. doi: 10.1016/0146-6380(83)90034-7

Gao, F., Lü, X.Y., 2006. Kinetics of pinacol rearrangement in high temperature liquid water. Journal of Chemical Industry and Engineering, 57(1): 57-60 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-HGSZ200601010.htm

Gao, G., 2000. Method of petroleum-generating simulation and its petroleum geological significance. Natural Gas Geoscience, 11(2): 25-29 (in Chinese with English abstract).

Guan, D.F., Wang, G.L., Zhang, J.G., et al., 2005. New idea about hydrocarbon generation and pool formation. Petroleum Geology & Experiment, 27(5): 425-432 (in Chinese with English abstract). http://d.wanfangdata.com.cn/Periodical/sysydz200505001

He, S., He, Z.L., Yang, Z., et al., 2009. Characteristics, well-log responses and mechanisms of overpressures within the Jurassic formation in the central part of Junggar basin. Earth Science—Journal of China University of Geosciences, 34(3): 457-470 (in Chinese with English abstract). doi: 10.3799/dqkx.2009.051

Helgeson, H.C., Knox, A.M., Owens, C.E., et al., 1993. Petroleum, oil field waters and authigenic mineral assemblages are they in metastable equilibrium in hydrocarbon reservoirs. Geochimica et Cosmochimica Acta, 57(14): 3295-3339. doi: 10.1016/0016-7037(93)90541-4

Hu, B.Q., Lü, G.X., Wang, F.Z., et al., 2008. The critical singularities of water and its significance in the hydrothermal mineralization of uranium. Uranium Geology, 24(3): 129-136 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-YKDZ200803000.htm

Huang, Z.L., Zhang, S.H., Zhong, N.N., 2003. Simulation experiment of gas generation in carbonate rocks. Chinese Journal of Geology, 38(4): 455-459 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DZKX200304003.htm

Jiang, F., Zhang, Y.L., Du, J.G., 1996. Advance of pyrolysis experimentation on hydrocarbon genesis. Advance in Earth Sciences, 11(5): 453-459 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DXJZ605.004.htm

Kuhlmann, B., Amett, E.M., Siskin, M., 1994. Classical organic reactions in pure superheated water. J. Org. Chem. , 59(11): 3098-3101. doi: 10.1021/jo00090a030

Lewan, M.D., 1997. Experiments on the role of water in petroleum formation. Geochimica et Cosmochimica Acta, 61(17): 3691-3723. doi: 10.1016/S0016-7037(97)00176-2

Lewan, M.D., 1998. Sulphur-radical control on petroleum formation rates. Nature, 391: 164-166. doi: 10.1038/34391

Lewan, M.D., Winters, J.C., Mcdonald, J.H., 1979. Generation of oil-like pyrolyzates from organic-rich shales. Science, 203(4383): 897-899. doi: 10.1126/science.203.4383.897

Liu, B.Q., Cai, B., Fang, J., 1990. A simulation aboutexperiment of petroleum origin on kerogen from shales of the Lower Xiamaling Formation in the Upper Proterozoic. Experimental Petroleum Geology, 12 (2): 147-161(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-SYSD199002004.htm

Liu, W.H., Wang, W.C., 2000. The organic (biogenic) and inorganic (non-biogenic) sources of hydrocarbons—thought on theory of oil and gas formation. Bulletin of Mineralogy, Petrology and Geochemistry, 19(3): 179-186 (in Chinese with English abstract). http://www.researchgate.net/publication/313167944_The_organic_biogenic_and_inorganic_nonbiogenic_sources_of_hydrocarbons-thought_on_theory_of_oil_and_gas_formation

Lü, X.Y., He, L., Zheng, Z.S., et al., 2003. Green chemical processes in near critical water. Chemical Industry and Engineering Progress, 22(4): 477-481 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-HGJZ200305009.htm

Qin, J.Z., Liu, J.W., Liu, B.Q., et al., 2002. Hydrocarbon yield and geochemical parameters affected by heating time and added water amount in the simulation test. Petroleum Geology & Experiment, 24(2): 152-157 (in Chinese with English abstract).

Seewald, J.S., 2003. Organic-inorganic interactions in petroleum producing sedimentary basins. Nature, 426(20): 327-333. doi: 10.1038/nature02132

Song, C.C., Hu, H.Q., 2002. Thermochemical liquefaction of biomass in high pressure water. Journal of Sichuan University (Engineering Science Edition), 34(5): 59-62 (in Chinese with English abstract). http://www.en.cnki.com.cn/Article_en/CJFDTOTAL-SCLH200205014.htm

Song, C.C., Wang, G., Hu, H.Q., 2004. Progress in thermochemical liquefaction of biomass. Acta Energiae Solaris Sinica, 25(2): 242-248 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-TYLX200402022.htm

Sun, H., Lü, X.Y., Chen, L., 2007. Comparison of hydrolysis kinetics of different vegetable oils in near-critical water. Journal of Chemical Industry and Engineering, 58(4): 925-929 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-HGSZ200704021.htm

Tissot, B.P., Welte, D.H., 1978. Petroleum formation and occurrence—a new approach to oil and gas exploration. Springer-Verlag, Berlag, Berlin Heidelgerg, New York.

Wang, X., Duan, P.G., Dai, L.Y., 2005. Application of supercritical/near-critical water in organic chemical reactions. Chemical Bulletin, 68(53): 1-6 (in Chinese with English abstract).

Wang, X.F., Liu, W.H., Xu, S.C., et al., 2006. The thermal simulation experiment of water in the organic matter in the formation of gaseous hydrocarbon evolution. Advance in Sciences, 16(10): 1275-1281 (in Chinese with English abstract).

Wang, X.X., Wang, G.L., Cai, J.G., et al., 2006. Organic-clay complex and hydrocarbon generation. Petroleum Industry Press, Beijing, 126-134 (in Chinese).

Wang, Z.M., Luo, X.R., Chen, R.Y., et al., 2006. Effect and influences of pore pressures on organic matter's maturation. Advances in Earth Science, 21(1): 39-46 (in Chinese with English abstract). http://www.researchgate.net/publication/310828747_Effect_and_influences_of_pore_pressures_on_organic_matter's_maturation

Wang, Z.P., Fu, X.T., Lu, S.F., et al., 2001. An analogue experiment of gas generating by crude oil cracking, characters of products and its significance. Natural Gas Industry, 21(3): 12-15 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-TRQG200103004.htm

Xiong, Y.Q., Geng, A.S., Wang, Y.P., et al., 2001. The simulation of secondary hydrocarbon generation of kerogen dynamics. Science in China (Ser. D), 31(4): 315-320 (in Chinese).

Xu, Y.S., Hou, W., Zheng, H.F., et al., 1995. The particularity of supercritical water and the connotation of study on deep earth's materials. Advance in Earth Sciences, 10(5): 445-449 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DXJZ505.009.htm

Zhang, R.H., Zhang, X.T., Hu, S.M., 2009. Critical fluids and mineral (rock) interactions in extreme conditions of the Earth interior. Earth Science Frontiers, 16(1): 53-67 (in Chinese with English abstract).

Zheng, L.J., Qin, J.Z., He, S., et al., 2009. Preliminary study of formation porosity thermocompression simulation experiment of hydrocarbon generation and expulsion. Petroleum Geology & Experiment, 31(3): 296-302, 306 (in Chinese with English abstract). http://www.cqvip.com/QK/95265X/200903/30850386.html

Zhou, S.X., Zou, H.L., Xie, Q.L., et al., 2006. Organic-inorganic interactions during the formation of oils in sedimentary basin. Natural Gas Geoscience, 17(1): 42-47 (in Chinese with English abstract). http://www.oalib.com/paper/1417808

Zou, Y.R., Shuai, Y.H., Kong, F., et al., 2004. Experiments on petroleum generation-considerations and outlook. Petroleum Geology & Experiment, 26(4): 375-382 (in Chinese with English abstract). http://www.en.cnki.com.cn/Article_en/CJFDTOTAL-SYSD200404012.htm

陈晋阳, 刘桂洋, 金鹿江, 2009. 地球内部水与无机成烃. 地学前缘, 16(1): 33-40. doi: 10.3321/j.issn:1005-2321.2009.01.006

陈晋阳, 张红, 郑海飞, 等, 2006. 高温高压下水中有机质降解过程的原位观测—以干酪根和沥青质为例. 石油实验地质, 28(1): 73-77. doi: 10.3969/j.issn.1001-6112.2006.01.014

陈晓东, 王先彬, 1999. 压力对有机质成熟和油气生成的影响. 地球科学进展, 14(1): 31-36. doi: 10.3321/j.issn:1001-8166.1999.01.008

程克明, 王兆云, 钟宁宁, 等, 1996. 碳酸盐岩油气生成理论与实践. 北京: 石油工业出版社, 139-175.

高飞, 吕秀阳, 2006. 高温液态水中的频那醇重排反应动力学. 化工学报, 57(1): 57-60. doi: 10.3321/j.issn:0438-1157.2006.01.011

高岗, 2000. 油气生成模拟方法及其石油地质意义. 天然气地球科学, 11(2): 25-29. https://www.cnki.com.cn/Article/CJFDTOTAL-TDKX200002004.htm

关德范, 王国力, 张金功, 等, 2005. 成烃成藏理论新思维. 石油实验地质, 27(5): 425-432. doi: 10.3969/j.issn.1001-6112.2005.05.001

何生, 何治亮, 杨智, 等, 2009. 准噶尔盆地腹部侏罗系超压特征和测井响应以及成因. 地球科学——中国地质大学学报, 34(3): 457- 470.

胡宝群, 吕古贤, 王方正, 等, 2008. 水的临界奇异性及其对热液铀成矿作用的意义. 铀矿地质, 24(3): 129-136. doi: 10.3969/j.issn.1000-0658.2008.03.001

黄志龙, 张四海, 钟宁宁, 2003. 碳酸盐岩生气的热模拟实验. 地质科学, 38(4): 455-459. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKX200304003.htm

姜峰, 张友联, 杜建国, 1996. 油气生成热模拟实验研究进展. 地球科学进展, 11(5): 453-459. doi: 10.3321/j.issn:1001-8166.1996.05.005

刘宝泉, 蔡冰, 方杰, 1990. 上元古界下马岭组页岩干酪根的油气生成模拟实验. 石油实验地质, 12 (2): 147-161. https://www.cnki.com.cn/Article/CJFDTOTAL-SYSD199002004.htm

刘文汇, 王万春, 2000. 烃类的有机(生物)与无机(非生物)来源——油气成因理论思考之二. 矿物岩石地球化学通报, 19(3): 179-186. doi: 10.3969/j.issn.1007-2802.2000.03.007

吕秀阳, 何龙, 郑赞胜, 等, 2003. 近临界水中的绿色化工过程. 化工进展, 22(4): 477-481. https://www.cnki.com.cn/Article/CJFDTOTAL-HGJZ200305009.htm

秦建中, 刘井旺, 刘宝泉, 等, 2002. 加温时间、加水量对模拟实验油气产率及地化参数的影响. 石油实验地质, 24(2): 152-157. doi: 10.3969/j.issn.1001-6112.2002.02.011

宋春财, 胡浩权, 2002. 生物质秸秆在水中热化学液化研究. 四川大学学报(工程科学版), 34(5): 59-62. doi: 10.3969/j.issn.1009-3087.2002.05.015

宋春财, 王刚, 胡浩权, 2004. 生物质热化学液化技术研究进展. 太阳能学报, 25(2): 242-248. doi: 10.3321/j.issn:0254-0096.2004.02.022

孙辉, 吕秀阳, 陈良, 2007. 不同植物油脂在近临界水中水解反应动力学的比较. 化工学报, 58(4): 925-929. doi: 10.3321/j.issn:0438-1157.2007.04.022

王晓峰, 刘文汇, 徐水昌, 等, 2006. 水在有机质形成气态烃演化中作用的热模拟实验研究. 自然科学进展, 16(10): 1275-1281. doi: 10.3321/j.issn:1002-008X.2006.10.011

王行信, 王国力, 蔡进攻, 等, 2006. 有机粘土复合体与油气生成. 北京: 石油工业出版社, 126-134.

王炫, 段培高, 戴立益, 2005. 超(近)临界水在有机化学反应中的应用. 化学通报, 68(53): 1-6.

王兆明, 罗晓容, 陈瑞银, 等, 2006. 有机质热演化过程中地层压力的作用与影响. 地球科学进展, 21(1): 39-46. doi: 10.3321/j.issn:1001-8166.2006.01.006

王振平, 付晓泰, 卢双舫, 等, 2001. 原油裂解成气模拟实验、产物特征及其意义. 天然气工业, 21(3): 12-15. https://www.cnki.com.cn/Article/CJFDTOTAL-TRQG200103004.htm

熊永强, 耿安松, 王云鹏, 等, 2001. 干酪根二次生烃动力学模拟实验研究. 中国科学(D辑), 31(4): 315-320. https://www.cnki.com.cn/Article/CJFDTOTAL-JDXK200104006.htm

徐有生, 侯渭, 郑海飞, 等, 1995. 超临界水的特性及其对地球深部物质研究的意义. 地球科学进展, 10(5): 445-449. https://www.cnki.com.cn/Article/CJFDTOTAL-DXJZ505.009.htm

张荣华, 张雪彤, 胡书敏, 2009. 临界区流体与矿物和岩石在地球内部极端条件下的反应. 地学前缘, 16(1): 53-67. https://www.cnki.com.cn/Article/CJFDTOTAL-DXQY200901013.htm

郑伦举, 秦建中, 何生, 等, 2009. 地层孔隙热压生排烃模拟实验初步研究. 石油实验地质, 31(3): 296-302, 306. doi: 10.3969/j.issn.1001-6112.2009.03.017

周世新, 邹红亮, 解启来, 等, 2006. 沉积盆地油气形成过程中有机-无机相互作用. 天然气地球科学, 17(1): 42-47. doi: 10.3969/j.issn.1672-1926.2006.01.008

邹艳荣, 帅燕华, 孔枫, 等, 2004. 油气生成过程实验研究的思考与展望. 石油实验地质, 26(4): 375-382. doi: 10.3969/j.issn.1001-6112.2004.04.012

Relative Articles

Supplements(0)

Cited By

Proportional views

Proportional views

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Figures(2) / Tables(2)

Get Citation

PDF

XML

Article views (3623) PDF downloads(159)

Formation Water of Near-Critical Properties and Its Effects on the Processes of Hydrocarbon Generation and Expulsion

doi: 10.3799/dqkx.2011.009

Abstract

References

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Proportional views

Export File

Citation

Format

Content