长期低温模拟实验下松柏萜类化合物的早期演化特征

秦身钧; 孙玉壮; 唐跃刚; 王双杰; 张寿鑫

doi:10.3799/dqkx.2011.013

Volume 36 Issue 1

Jan. 2011

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Article Navigation > Earth Science > 2011 > 36(1): 122-130

QIN Shen-jun, SUN Yu-zhuang, TANG Yue-gang, WANG Shuang-jie, ZHANG Shou-xin, 2011. Early Evolution of Coniferous Terpenoids in the Long Period Simulation at Low Temperature. Earth Science, 36(1): 122-130. doi: 10.3799/dqkx.2011.013

Citation:

QIN Shen-jun, SUN Yu-zhuang, TANG Yue-gang, WANG Shuang-jie, ZHANG Shou-xin, 2011. Early Evolution of Coniferous Terpenoids in the Long Period Simulation at Low Temperature. Earth Science, 36(1): 122-130. doi: 10.3799/dqkx.2011.013

Citation:

QIN Shen-jun, SUN Yu-zhuang, TANG Yue-gang, WANG Shuang-jie, ZHANG Shou-xin, 2011. Early Evolution of Coniferous Terpenoids in the Long Period Simulation at Low Temperature. Earth Science, 36(1): 122-130. doi: 10.3799/dqkx.2011.013

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Early Evolution of Coniferous Terpenoids in the Long Period Simulation at Low Temperature

doi: 10.3799/dqkx.2011.013

1.
Key Laboratory of Resource Exploration Research of Hebei Province, Hebei University of Engineering, Handan 056038, China
2.
College of Geosciences and Surveying Engineering, China University of Mining and Technology, Beijing 100083, China

Received Date: 2010-05-31
Publish Date: 2011-01-01

Abstract

Abstract

Conifer samples were simulated for more than five years at low temperature (80 ℃) in order to study their early alteration processes. The samples were analyzed by chromatography and gas chromatography-mass spectrometry when the simulation lasted approximately one year and five and a half years, respectively. The results show that the alkanes and terpenoids of coniferous organic matter can undergo a remarkable and rapid alteration after sedimentation. Some seldom reported evolutionary intermediates of terpenoids, i.e. two cadinatetraenes, one abietatetraene and three norabietatetraenes, were identified based on their mass fragments. Then the early evolutionary pathways of cadalane-type sesquiterpenoids and abietane-type diterpenoids were proposed. In these processes, the dehydrogenated and aromatic terpenoids are main evolutionary products, which may be mediated by undefined bacteria.
- geochemistry,
- coniferous organic matter,
- terpenoids,
- chromatography-mass spectrometry,
- low temperature simulation

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Early Evolution of Coniferous Terpenoids in the Long Period Simulation at Low Temperature

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