鄂西晚泥盆世含磷鲕状铁矿石中磷的赋存状态与形成

柴辛娜; 李明; 金振民; 高山

doi:10.3799/dqkx.2011.047

Volume 36 Issue 3

May 2011

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Article Navigation > Earth Science > 2011 > 36(3): 440-454

CHAI Xin-na, LI Ming, JIN Zhen-min, GAO Shan, 2011. Occurrence and Formation of Phosphorus in Late Devonian Phosphate-Bearing Ooidal Ironstones from Western Hubei, China. Earth Science, 36(3): 440-454. doi: 10.3799/dqkx.2011.047

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CHAI Xin-na, LI Ming, JIN Zhen-min, GAO Shan, 2011. Occurrence and Formation of Phosphorus in Late Devonian Phosphate-Bearing Ooidal Ironstones from Western Hubei, China. Earth Science, 36(3): 440-454. doi: 10.3799/dqkx.2011.047

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Occurrence and Formation of Phosphorus in Late Devonian Phosphate-Bearing Ooidal Ironstones from Western Hubei, China

doi: 10.3799/dqkx.2011.047

CHAI Xin-na^{1, 2
,},
LI Ming^{1, 2, 3},
JIN Zhen-min^{1, 2, 3},
GAO Shan^{1, 2, 3
,
,}

1.
State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, China
2.
Faculty of Earth Science, China University of Geosciences, Wuhan 430074, China
3.
Key Laboratory of Earth Material and Regional Resources and Environment, China University of Geosciences, Wuhan 430074, China

Received Date: 2011-02-05
Publish Date: 2011-05-01

Abstract

Abstract

Ningxiang-type iron deposits are widely distributed in Devonian strata in southern China with huge reserves, but exploitation of this type iron deposits have been severely circumscribed due to their high phosphorus content. Occurrences of phosphorus are theoretical foundations for dephosphorization researches, which should be solved first. Preliminary researches of occurrence, formation and origin of phosphorus in Late Devonian phosphate-bearing ooidal ironstones from Western Hubei in China have been done in this study by means of whole-rock element analysis (wet chemical whole-rock analysis, inductively coupled plasma mass spectrometry), mineral phase analysis (scanning electron microscopy, X-ray diffraction analysis) and in-situ element analysis (electron microprobe analysis, laser ablation inductively coupled plasma mass spectrometry). Phosphorous-bearing minerals are mainly carbonate fluorapatite in ironstone and there are three formations, including prismatic apatite crystal particles (more than 65% particle sizes < 20 μm), apatite intraclasts (very coarse and coarse sand size level particles concentrate in lenticular and banded beddings), and layered gelatinous apatite entangled by hematite in ooids (layer thickness are of 10-50 μm). Apatite crystals recrystallized from pore water, and might have originated from phosphorite in late Sinian strata. Apatite intraclasts were the product of in-situ chemical deposition in seawater, and might have come from land around paleo-ocean. Gelatinous apatite also was in-situ chemical deposition product, but formed at iron deposition position and mixed or mutual parcel with chamosite and formed ooids.
- ooidal ironstones,
- phosphorus,
- occurrence,
- Late Devonian,
- western Hubei,
- geochemistry

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References(71)

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Occurrence and Formation of Phosphorus in Late Devonian Phosphate-Bearing Ooidal Ironstones from Western Hubei, China

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