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    Volume 37 Issue 3
    May  2012
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    WANG Hao, LING Wen-li, DUAN Rui-chun, YANG Hong-mei, CHEN Zi-wan, QIN Ya-dong, 2012. Os Isotopic Geochemistry of Neoproterozoic-Cambrian Black Shales in Eastern Three Gorges of Yangtze Craton and Its Geological Significance. Earth Science, 37(3): 451-462. doi: 10.3799/dqkx.2012.052
    Citation: WANG Hao, LING Wen-li, DUAN Rui-chun, YANG Hong-mei, CHEN Zi-wan, QIN Ya-dong, 2012. Os Isotopic Geochemistry of Neoproterozoic-Cambrian Black Shales in Eastern Three Gorges of Yangtze Craton and Its Geological Significance. Earth Science, 37(3): 451-462. doi: 10.3799/dqkx.2012.052

    Os Isotopic Geochemistry of Neoproterozoic-Cambrian Black Shales in Eastern Three Gorges of Yangtze Craton and Its Geological Significance

    doi: 10.3799/dqkx.2012.052
    • Received Date: 2011-04-10
      Available Online: 2021-11-09
    • Publish Date: 2012-05-01
    • This paper presents an integrated Re-Os isotope and trace element investigation of the Neoproterozoic to Cambrian organic-bearing black mudstones in the eastern Three Gorges, the Yangtze Craton. Their sedimentary environmental evolution and geological significance are then discussed. It shows that (1) initial Os isotopic ratios of fine-grained sedimentary rocks from the strata display regular variations along the stratigraphic column. Of the strata, layers with negative δ13C excursions are coupled with high initial Os isotopic ratios; (2) the Nantuo tillite displays higher initial Os isotopic ratio than that of the overlying cap carbonate, while the overlying successive strata show an increase trend with several fluctuations; (3) geochemical features of U/Th ratio and δU value for the samples suggest that the Liantuo sandstone and Nantuo tillite were formed within oxidation environments, whereas black mudstones of the Doushantuo, Dengying and Shuijingtuo Formations were formed within reductive environments; (3) negative correlation between Y/Ho ratio and δCe value for the black mudstones is likely indicative of variable involvement of seafloor hydrothermal activity during some sediments deposited, which likely accounts for their low Os isotopic ratios. The correlation between high initial Os isotopic ratios and pulsed oxidation of deep ocean as well as appearance of metazoan in Late Neoproterozoic-Early Cambrian afford a new clue for the linking of continental weathering extent with oxygen content in atmosphere and ocean. These Os isotopic and trace element features infer that the Nantuo tillites were formed in an environment where the earth's surface had not been fully covered by ice layer, and continent-derived inputs by intensive weathering played an important role.

       

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