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    中国百强科技报刊

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    Volume 37 Issue 5
    Sep.  2012
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    Article Contents
    HUA Shu-guang, WANG Li-juan, JIA Xiao-fang, CHEN Lei, LI Jian-wei, 2012. Occurrence and Enrichment Mechanism of Gold in the Qiuling Carlin-Type Gold Deposit, Zhen'an County, Shaanxi Province, China. Earth Science, 37(5): 989-1002. doi: 10.3799/dqkx.2012.107
    Citation: HUA Shu-guang, WANG Li-juan, JIA Xiao-fang, CHEN Lei, LI Jian-wei, 2012. Occurrence and Enrichment Mechanism of Gold in the Qiuling Carlin-Type Gold Deposit, Zhen'an County, Shaanxi Province, China. Earth Science, 37(5): 989-1002. doi: 10.3799/dqkx.2012.107

    Occurrence and Enrichment Mechanism of Gold in the Qiuling Carlin-Type Gold Deposit, Zhen'an County, Shaanxi Province, China

    doi: 10.3799/dqkx.2012.107
    • Received Date: 2011-11-08
      Available Online: 2021-11-10
    • Publish Date: 2012-09-15
    • Located in the western Qinling orogen, the Qiuling gold deposit is a typical Carlin-type gold deposit. Gold mineralization is hosted in calcareous siltstones, silty shales, and argillaceous limestones of the Upper Devonian Nanyangshan Formation and the Lower Carboniferous Yuanjiagou Formation. Pyrite and arsenopyrite dominate the metallic minerals, whereas quartz, calcite, and sericite are the main non-metallic alteration minerals. An integration of optical microscopy, scanning electron microscopy equipped with energy dispersive system, electron microprobe, and laser ablation ICP-MS was used to study the occurrence, distribution, and enrichment mechanism of gold in the Qiuling gold deposit. The results indicate that gold occurs as submicroscopic and, less significantly, microscopic species. The submicroscopic gold is present as nanoparticles of native gold (Au0) in the coarse-grained pyrite and solid solution (Au+) in the arsenian rims of zoned pyrite and arsenopyrite, with lesser amount of gold nanoparticles in the As-deficient core of zoned pyrite. The sub-microscopic gold particles in the core of zoned pyrite were likely formed during the diagenesis of the host rocks through adsorption, while the structure-bounded Au (Au0 and Au+) in fine-grained zoned pyrite and arsenopyrite may have been transported as sulfur and arsenic complexes in ore-forming fluids of the main hydrothermal stage. Microscopic gold grains are mostly less than 3 to 5 μm in size and are contained in the marginal areas fine-grained pyrite and included in hydrothermal sericite, quartz, and calcite. They formed likely due to local saturation of gold in the ore fluids or as a result of leaching of the submicroscopic gold by late-stage fluids and subsequent re-precipitation.

       

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    • Arehart, G.B., Chryssoulis, S.L., Kesler, S.E., 1993. Gold and arsenic in iron sulfides from sediment hosted disseminated gold deposits: implications for depositional processes. Economic Geology, 88(1): 171-185. doi: 10.2113/gsecongeo.88.1.171
      Bowell, R.J., Baumann, M., Gingrich, M., et al., 1999. The occurrence of gold at the Getchell mine, Nevada. Journal of Geochemical Exploration, 67(1-3): 127-143. doi. org/10.1016/S0375-6742(99)00062-X doi: 10.1016/S0375-6742(99)00062-X
      Cardile, C.M., Cashion, J.D., McGrath, A.C., et al., 1993. 197Au Mössbauer study of Au2S and gold adsorbed onto As2S3 and Sb2S3 substrates. Geochimica et Cosmochimica Acta, 57(11): 2481-2486. doi: 10.1016/0016-7037(93)90411-O
      Chen, M.H., Mao, J.W., Chen, Z.Y., et al., 2009. Mineralogy of arsenian pyrites and arsenopyrites of Carlin type gold deposits in Yunnan-Guizhou-Guangxi "golden triangle" area, southwestern China. Mineral Deposits, 28(5): 539-557 (in Chinese with English abstract). http://www.zhangqiaokeyan.com/academic-journal-cn_mineral-deposits_thesis/0201254126328.html
      Chen, Y.J., Zhang, J., Zhang, F.X., et al., 2004. Carlin and Carlin-like gold deposit in western Qinling mountains and their metallogenic time, tectonic setting and model. Geological Review, 50(2): 134-152(in Chinese with English abstract). http://www.cnki.com.cn/Article/CJFDTotal-DZLP200402004.htm
      Cline, J.S., 2001. Timing of gold and arsenic sulfide mineral deposition at the Getchell Carlin type gold deposit, North-Central Nevada. Economic Geology, 96(1): 75-89. doi: 10.2113/gsecongeo.96.1.75
      Fleet, M.E., Maclean, P.J., Barbier, J., 1989. Oscillatory-zoned As-bearing pyrite from strata-bound and stratiform gold deposits; an indicator of ore fluid evolution. Economic Geology Monographs, 6: 356-362. http://www.researchgate.net/publication/285109315_Oscillatory-zoned_As-bearing_pyrite_from_strata-bound_and_stratiform_gold_deposits_An_indicator_of_ore_fluid_evolution
      Fleet, M.E., Mumin, A.H., 1997. Gold-bearing arsenian pyrite and marcasite and arsenopyrite from Carlin Trend gold deposits and laboratory synthesis. American Mineralogist, 82(1-2): 182-193. doi: 10.2138/am-1997-1-220
      Gold Command of Chinese People's Armed Police Force. 1997. Geology of Jinlongshan microscopic disseminated gold deposit in Shaanxi Province. Earthquake Publishing House, Beijing, 5-114 (in Chinese).
      Hofstra, A.H., Cline, J.S., 2000. Characteristics and models for Carlin-type gold deposits. Reviews in Economic Geology, 13: 163- 220. http://www.researchgate.net/publication/304335923_Characteristics_and_models_for_Carlin-type_gold_deposits
      Hu, J.M., Cui, J.T., Meng, Q.R., et al., 2004. The U-Pb age of zircons separated from the Zhashui granite in Qinling orogen and its significance. Geological Review, 50(2): 323-329 (in Chinese with English abstract). http://www.researchgate.net/publication/313508610_The_U-Pb_age_of_zircons_separated_from_the_Zhashui_granite_in_Qinling_orogen_and_its_significance
      Hu, M.A., 2003. Tracer significance of normal alkane for gold mineralization of Gaolong Carlin-type gold deposit. Earth Science—Journal of China University of Geosciences, 28 (3): 301-305 (in Chinese with English abstract). http://www.researchgate.net/publication/296530394_Tracer_significance_of_normal_alkane_for_gold_mineralization_of_Gaolong_Carlin_type_gold_deposit
      Kesler, S.E., Fortuna, J., Ye, Z., et al., 2003. Evaluation of the role of sulfidation in deposition of gold, screamer section of the Betze-Post Carlin-type deposit, Nevada. Economic Geology, 98(6): 1137-1157. doi: 10.2113/gsecongeo.98.6.1137
      Li, J.L., Qi, F., Xu, Q.S., 2002. The negative valence gold in mineral: a further study on the chemical state of "bound gold" in arsenian pyrites and arsenopyrites. Progress in Natural Science, 12(9): 952-958 (in Chinese).
      Liu, D.S., Tan, Y.J., Wang, J.Y., et al., 1994. Carlin-type (fine-grain disseminated) gold deposits in China. Nanjing University Press, Nanjing (in Chinese).
      Longerich, H.P., Jackson, S.E., Günther, D., 1996. Intor-laboratory note. Laser ablation inductively coupled plasma mass spectrometric transient signal data acquisition and analyte concentration calculation. Journal of Analytical Atomic Spectrometry, 11: 899-904. doi: 10.1039/JA9961100899
      Ma, G., Liu, J.S., Gong, L., 2004. Geological feature of Carlin-type gold deposit in the Qinling area. Gold, 25(3): 8-11 (in Chinese with English abstract).
      Mao, S.D., Yang, R.S., Qin, Y., et al., 2009. Characteristics of gold-bearing mineral and occurrence of gold in the Yangshan gold field, Gansu Province. Acta Petrologica Sinica, 25(11): 2776-2790 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-YSXB200911010.htm
      Meng, Q.R., Zhang, G.W., 2000. Geologic framework and tectonic evolution of the Qinling orogen, central China. Tectonophysics, 323(1-3): 183-196. doi: /10.1016/S0040-1951(00)00106-2
      Palenik, C.S., Utsunomiya, S., Reich, M., et al., 2004. "Invisible" gold revealed: direct imaging of gold nanoparticles in a Carlin-type deposit. American Mineralogist, 89(10): 1359-1366. doi: 10.2138/am-2004-1002
      Pals, D.W., Spry, P.G., Chryssoulis, S., 2003. Invisible gold and tellurium in arsenic-rich pyrite from the emperor gold deposit, Fiji: implications for gold distribution and deposition. Economic Geology, 98(3): 479-493. doi: 10.2113/gsecongeo.98.3.479
      Radtke, A.S., Taylor, C.M., Dickson, F.W., et al., 1974. Thallium-bearing orpiment, Carlin gold deposit, Nevada. Journal of Research of the U.S. Geological Survey, 2(3): 341-342.
      Reich, M., Kesler, S.E., Utsunomiya, S., et al., 2005. Solubility of gold in arsenian pyrite. Geochimica et Cosmochimica Acta, 69(11): 2781-2796. doi:/ 10.1016/j.gca.2005.01.011
      Renders, P.J., Seward, T.M., 1989. The adsorption of thio gold (I) complexes by amorphous As2S3 and Sb2S3 at 25 and 90 ℃. Geochimica et Cosmochimica Acta, 53(2): 255-267. doi: 10.1016/0016-7037(89)90378-5
      Scaini, M.J., Bancroft, G.M., Knipe, S.W., 1998. Reactions of aqueous Au(super 1+) sulfide species with pyrite as a function of pH and temperature. American Mineralogist, 83(3-4): 316-322. doi: 10.2138/am-1998-3-415
      Seward, T.M., 1973. Thio complexes of gold and the transport of gold in hydrothermal ore solutions. Geochimica et Cosmochimica Acta, 37(3): 379-399. doi: 10.1016/0016-7037(73)90207-X
      Simon, G., Kesler, S.E., Chryssoulis, S., 1999. Geochemistry and textures of gold-bearing arsenian pyrite, Twin Creeks, Nevada: implications for deposition of gold in Carlin-type deposits. Economic Geology, 94(3): 405-422. doi: 10.2113/gsecongeo.94.3.405
      Su, W.C., Xia, B., Zhang, H.T., et al., 2008. Visible gold in arsenian pyrite at the Shuyindong Canlin-type gold deposit, Guizhou, China: implications for the environment and processes of ore formation. Ore Geology Reviews, 33(3-4): 667-679. doi:/ 10.1016/j.oregeorev.2007.10.002
      Wang, J.H., Zhang, F.X., Yu, Z.P., et al., 2002. Minerogenetic series of metallic ore deposits in the Qinling mountains and tectondynamic background of the continental orogenic belts. Geology in China, 29(2): 192-196(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DIZI200202015.htm
      Wang, J., Jin, Q., Lai, S.C., et al., 2008. Research of geochemistry and petrogenesis of the Wulong granites in the Fuping region, south Qinling mountains. J. Mineral Petrol. , 28(1): 79-87(in Chinese with English abstract).
      Wang, J.Y., Liu, L.L., 1995. Mineralization model of Carlin-type gold deposits in Qinling area. Mineral Resources and Geology, 9(4): 243-246(in Chinese).
      Wang, K.R., Zhou, Y.Q., Li, F.Q., et al., 1992. SPM and SEM study on the occurrence of micrograined gold in the Jinya gold deposit, Guangxi. Chinese Science Bulletin, 37(22): 1906-1910. http://qikan.cqvip.com/Qikan/Article/Detail?id=1005219412
      Wang, K.Y., 2000. The geological conditions of formation and mineralization features of micro-fine disseminated gold deposits in China. Journal of Precious Metallic Geology, 9(3): 160-165 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-GJSD200003005.htm
      Wilson, S.A., Ridley, W.I., Koenig, A.E., 2002. Development of sulfide calibration standards for the laser ablation inductively-coupled plasma mass spectrometry technique. Journal of Analytical Atomic Spectrometry, 17: 406-409. doi: 10.1039/B108787H
      Xiang, C.F., Zhuang, X.G., Lu, Y.M., et al., 2002. Formation of Carlin-type gold deposit by hydrocarbon fluid and its correlation to accumulation and dispersion of petroleum in Youjiang basin, South China. Earth Science—Journal of China University of Geosciences, 27(1): 35-39 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DQKX200201006.htm
      Zachariáš, J., Frda, J., Paterova, B., et al., 2004. Arsenopyrite and As-bearing pyrite from the Roudn deposit, Bohemian Massif. Mineralogical Magazine, 68(1): 31-46. doi: 10.1180/0026461046810169
      Zhang, F.X., Chen, Y.J., Li, C., et al., 2000. Geological and geochemical character and genesis of the Jinlongshan-Qinling gold deposits in Qinling orogen: metallogenic mechanism of the Qinling-pattern Carlin-type gold deposits. Science in China (Series D), 43(Suppl. 1): 95-107. doi: 10.1007/BF02911936
      Zhang, F.X., Ma, J.Q., Chen, Y.J., 1999. The study on geochemistry of gold and arsenic mineralization in Carlin type gold deposits, Qinling region. Geochimica, 28(5): 453-463 (in Chinese with English abstract).
      Zhang, F.X., Shen, P., 1996. Study on metallogenic physicochemical conditions and metallogenic mechanish of the Qiuling micro-disseminated gold deposit in Zhen'an county, Shannxi Province. Geology and Prospecting, 32(5): 8-15 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DZKT605.001.htm
      Zhang, G.W., Guo, A.L., Yao, A.P., 2004. Western Qinling-Songpan continental tectonic nodein China's continental tectonics. Earth Science Frontiers, 11(3): 23-32 (in Chinese with English abstract). http://en.cnki.com.cn/article_en/cjfdtotal-dxqy200403004.htm
      Zhang, H.T., Su, W.C., Tian, J.J., et al., 2008. The occurrence of gold at shuiyindong Carlin-type gold deposit, Guizhou. Acta Mineralogical Sinica, 28(1): 17-24(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-KWXB200801004.htm
      Zhang, J., Chen, Y.J., Zhang, F.X., et al., 2002. Geochemical study of ore Fluid in Jinlongshan Carlin-type gold ore belt in southwestern Shaanxi Province. Mineral Deposits, 21(3): 283-291 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-KCDZ200203009.htm
      Zhao, L.Q., Chen, X., Zhou, H., et al., 2000. Characteristics of pyrites and arsenopyrites of Jinlongshan sediment-hosted gold deposit, southern Qinling mountain. Journal of Precious Metallic Geology, 9(4): 193-199(in Chinese with English abstract).
      Zhao, L.Q., Feng, Z.Y., 2000. Control of favorable lithology on Jinlongshan micro-fine disseminated gold deposits, southern Qinling mountains. Science in China (Series D), 45(2): 123-132. doi: 10.1007/BF02879789
      Zhu, L.M., Zhang, G.W., Liu, J.J., et al., 2009. Calin-type and Carlin-like gold deposits in the western Qinling orogen and the Songpan-Ganzi tectonic terrain: tectonic setting, problems, and future research. Acta Mineralogica Sinica, 29(S1): 201-204(in Chinese).
      陈懋弘, 毛景文, 陈振宇, 等, 2009. 滇黔桂"金三角"卡林型金矿含砷黄铁矿和毒砂的矿物学研究. 矿床地质, 28(5): 539-557. doi: 10.3969/j.issn.0258-7106.2009.05.002
      陈衍景, 张静, 张复新, 等, 2004. 西秦岭地区卡林-类卡林型金矿床及其成矿时间、构造背景和模式. 地质论评, 50(2): 134-152. doi: 10.3321/j.issn:0371-5736.2004.02.004
      胡建民, 崔建堂, 孟庆任, 等, 2004. 秦岭柞水岩体锆石U-Pb年龄及其地质意义. 地质论评, 50(3): 323-329. doi: 10.3321/j.issn:0371-5736.2004.03.016
      胡明安, 2003. 正构烷烃的成矿意义——以广西田林高龙卡林型金矿为例. 地球科学——中国地质大学学报, 28(3): 301-305. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200303010.htm
      李九玲, 亓锋, 徐庆生, 2002. 矿物中呈负价态之金——毒砂和含砷黄铁矿中"结合金"化学状态的进一步研究. 自然科学进展, 12(9): 952-958. doi: 10.3321/j.issn:1002-008X.2002.09.011
      刘东升, 谭运金, 王见业, 等, 1994. 中国卡林型(微细浸染型)金矿. 南京: 南京大学出版社.
      马光, 刘继顺, 宫丽, 2004. 秦岭地区卡林型金矿地质特征. 黄金, 25(4): 8-11. https://www.cnki.com.cn/Article/CJFDTOTAL-HJZZ200403003.htm
      毛世东, 杨荣生, 秦艳, 等, 2009. 甘肃阳山金矿田载金矿物特征及金赋存状态研究. 岩石学报, 25(11): 1-15. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXB200911010.htm
      王靖华, 张复新, 于在平, 等, 2002. 秦岭金属矿床成矿系列与大陆造山带构造动力学背景. 中国地质, 29(2): 192-196. doi: 10.3969/j.issn.1000-3657.2002.02.016
      王娟, 金强, 赖绍聪, 等, 2008. 南秦岭佛坪地区五龙花岗质岩体的地球化学特征及成因研究. 矿物岩石, 28(1): 79-87. doi: 10.3969/j.issn.1001-6872.2008.01.012
      王建业, 刘鸾玲, 1995. 秦岭地区卡林型金矿成矿模式. 矿产与地质, 9(4): 243-246. https://www.cnki.com.cn/Article/CJFDTOTAL-KCYD1995Z1005.htm
      王可勇, 2000. 我国微细浸染型金矿床的形成条件及成矿作用特征. 贵金属地质, 9(3): 160-165. doi: 10.3969/j.issn.1671-1947.2000.03.006
      王奎仁, 周有勤, 李凡庆, 等, 1992. 广西金牙金矿微细粒金赋存状态的质子探针和扫描电镜研究. 科学通报, 37(9): 832-835. doi: 10.3321/j.issn:0023-074X.1992.09.001
      向才富, 庄新国, 陆友明, 等, 2002. 有机流体成矿作用与古油藏成藏作用相互耦合. 地球科学——中国地质大学学报, 27(1): 35-39. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX200201006.htm
      张复新, 申萍, 1996. 陕西镇安丘岭微细浸染型金矿床成矿物理化学条件及成矿机制研究. 地质与勘探, 32(5): 8-15. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKT605.001.htm
      张复新, 马建泰, 陈衍景, 1999. 秦岭卡林型金矿床金、砷地球化学探讨. 地球化学, 28(5): 453-463. doi: 10.3321/j.issn:0379-1726.1999.05.005
      张复新, 陈衍景, 李超, 等, 2000. 金龙山-丘岭金矿床地质地球化学特征及成因: 秦岭式卡林型金矿成矿动力学机制. 中国科学(D辑: 地球科学), 30(S1): 73-81. https://www.cnki.com.cn/Article/CJFDTOTAL-JDXK2000S1009.htm
      张国伟, 郭安林, 姚安平, 2004. 中国大陆构造中的西秦岭-松潘大陆构造结. 地学前缘, 11(3): 23-32. doi: 10.3321/j.issn:1005-2321.2004.03.004
      张弘弢, 苏文超, 田建吉, 等, 2008. 贵州水银洞卡林型金矿床金的赋存状态初步研究. 矿物学报, 28(1): 17-24. doi: 10.3321/j.issn:1000-4734.2008.01.004
      张静, 陈衍景, 张复新, 等, 2002. 陕西金龙山卡林型金矿带成矿流体地球化学研究. 矿床地质, 21(3): 283-291. doi: 10.3969/j.issn.0258-7106.2002.03.010
      中国人民武装警察部队黄金指挥部, 1997. 陕西省金龙山微细浸染型金矿地质. 北京: 地震出版社, 5-114.
      赵利青, 陈祥, 周红, 等, 2000. 南秦岭赋存于沉积岩中的金龙山金矿带主要载金矿物黄铁矿、毒砂研究. 贵金属地质, 9(4): 193-199. https://www.cnki.com.cn/Article/CJFDTOTAL-GJSD200004000.htm
      朱赖民, 张国伟, 刘家军, 等, 2009. 西秦岭-松潘构造结中的卡林型-类卡林型金矿床: 成矿构造背景、存在问题和研究趋势. 矿物学报, 29 (S1): 201-204. https://www.cnki.com.cn/Article/CJFDTOTAL-KWXB2009S1104.htm
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