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    中国百强科技报刊

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    Volume 38 Issue 3
    May  2013
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    Article Contents
    SHAN Hui-mei, MA Teng, TAN Ting, LUO Zhao-hui, QI Zhi-chong, ZHAI Ming-zhe, Lekgowe Oteng M., 2013. Sources and Genesis of Subsurface Brine in Sua Pan, Botswana. Earth Science, 38(3): 607-615. doi: 10.3799/dqkx.2013.061
    Citation: SHAN Hui-mei, MA Teng, TAN Ting, LUO Zhao-hui, QI Zhi-chong, ZHAI Ming-zhe, Lekgowe Oteng M., 2013. Sources and Genesis of Subsurface Brine in Sua Pan, Botswana. Earth Science, 38(3): 607-615. doi: 10.3799/dqkx.2013.061

    Sources and Genesis of Subsurface Brine in Sua Pan, Botswana

    doi: 10.3799/dqkx.2013.061
    • Received Date: 2012-05-21
    • Publish Date: 2013-05-15
    • The salt lake of Sua Pan, one of the largest salt lakes in Botswana, is important resources of natural alkali. To identify the sources and genesis of subsurface brine in this salt lake, groundwater and surface water near this lake, in addition to subsurface brine water in the lake and salt crystals from solar salt field were collected and determined. The contents of major cation and anion, the isotope compositions of D, 18O and 37Cl, and the 14C age of groundwater were calculated. It is found that the subsurface brine is characterized by enriched Na and K, and depleted Ca and Mg. Results of D, 18O and 37Cl show that surface water is closely connected with subsurface brine in Sua Pan, while the role of groundwater recharge on it is weak (the difference of 37Cl is 0.04‰-0.06‰). Relationships of TDS-γNa/γCl indicate that leaching of halite affects the formation of this subsurface brine (γNa/γCl≈1), and the age of 14C (about 20 000 years ago)indicates that the fluctuation of ancient climate is considered to be an important factor of the formation of Sua Pan. Based on the above knowledge, inverse simulation of subsurface brine in Sua Pan is modeled by PHREEQC software, which further verifies that salt lake of Sua Pan is mainly the result of strong evaporation and concentration of surface water and halite leaching by groundwater.

       

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    • Burrough, S.L., Thomas, D.S.G., Bailey, R.M., 2009. Mega-Lake in the Kalahari: A Late Pleistocene Record of the Palaeolake Makgadikgadi System. Quaternary Science Reviews, 28(15-16): 1392-1411. doi: 10.1016/j.quascirev.2009.02.007
      Cao, B.X., 1995. Geomorphology and Quaternary Geology. China University of Geosciences Press, Wuhan (in Chinese).
      Clayton, R.N., Friedman, I., Graf, D.L. et al., 1966. The Origin of Saline Formation Waters 1. Isotopic Composition. Journal of Geophysical Research-Atmospheres, 71 (16): 3869-3882. doi: 10.1029/JZ071i016p03869
      Eckardt, F.D., Bryant, R.G., McCulloch, G., et al., 2008. The Hydrochemistry of a Semi-arid Pan Basin Case Study: Sua Pan, Makgadikgadi, Botswan. Applied Geochemistry, 23 (6): 1563-1580. doi: 10.1016/j.apgeochem.2007.12.033
      Fan, Q.S., Ma, H.Z., Tan, H.B., et al., 2007. Characteristics and Origin of Brines in Western Qaidam Basin. Geochimica, 36(6): 601-611(in Chinese with English abstract). http://d.wanfangdata.com.cn/periodical/dqhx200706008
      Holmgren, K., Lee-Thorp, J.A., Cooper, G.R.J., et al., 2003. Persistent Millennial-Scale Climatic Variability over the Past 25 000 Years in Southern Africa. Quaternary Science Reviews, 22(21-22): 2311-2326. doi: 10.1016/S0277-3791(03)00204-X
      Liu, H.Y., 2002. Quaternary Ecology and Global Change. Science Press, Beijing (in Chinese).
      Liu, W.G., Xiao, Y.K., Sun, D.P., et al., 1995. Characteristics and Significance of Chlorine Isotope of Brine and Deposits in the Mahai Salt Lakes. Journal of Salt Lake Science, 3(2): 29-33(in Chinese with English abstract). http://www.researchgate.net/publication/285751263_Characteristics_and_significance_of_chlorine_isotope_of_brine_and_deposits_in_the_Mahai_salt_lakes
      Liu, W.G., Xiao, Y.K., Sun, D.P., et al., 1996. Chlorine Isotopic Composition in Qaidam Basin. Geochimica, 25(3): 296-303 (in Chinese with English abstract).
      McCulloch, G.P., Irvine, K., Eckardt, F., et al., 2008. Hydrochemical Fluctuations and Crustacean Community Composition in an Ephemeral Saline Lake (Sua Pan, Makgadikgadi Botswana). Hydrobiologia, 596(1): 31-46. doi: 10.1007/s10750-007-9055-8
      Ringrose, S., Huntsman-Mapila, P., Kampunzu, A.B., et al., 2005. Sedimentological and Geochemical Evidence for Palaeo-Environmental Change in the Makgadikgadi subbasin, in Relation to the MOZ Rift Depression, Botswana. Palaeo, 217(3-4): 265-287. doi: 10.1016/j.palaeo.2004.11.024
      Servant, M., Maley, J., Turcq, B., et al., 1993. Tropical Forest Changes during the Late Quaternary in African and South American Lowlands. Global and Planetary Change, 7(1-3): 25-40. http://www.researchgate.net/profile/Jean_Maley2/publication/32975443_Tropical_forest_changes_during_the_Late_Quaternary_in_African_and_South_American_lowlands/links/0deec521daf6da3824000000.pdf
      Shaw, P.A., Cooke, H.J., 1986. Geomorphic Evidence for the Late Quaternary Palaeoclimates of the Middle Kalahari of Northern Botswana. Catena, 13(4): 349-359. doi: 10.1016/0341-8162(86)90009-3
      Shaw, P.A., Thomas, D.S., G., Nash, D.J., 1992. Late Quaternary Fluvial Activity in the Dry Valleys (mekgacha) of the Middle and Southern Kalahari, Southern Africa. Journal of Quaternary Science, 7(4): 273-281. doi: 10.1002/jqs.3390070402
      Taylor, H.P., 1974. The Application of Oxygen and Hydrogen Isotope Studies to Problems of Hydrothermal Alteration and Ore Deposition. Economic Geology, 69 (6): 843-883. doi: 10.2113/gsecongeo.69.6.843
      Thomas, D.S.G., Shaw, P.A., 1991. The Kalahari Environment. Cambridge University Press, Cambridge.
      Wan, J.W., Liu, C.F., Chao, N.Y., et al., 2003. Isotope Hydrology Theory and Practice. China University of Geosciences Press, Wuhan (in Chinese).
      Wang, M.L., Yang, Z.C., Liu, C.L., et al., 1996. The Northern Qaidam Basin Salt Lake Potash Deposit and Its Development Prospects. Geological Publishing House, Beijing (in Chinese).
      Wang, Z.Y., Meng, G.L., Wang, S.Q., 2003. Geochemistry Modeling of Quaternary Subsurface Brines in South Coast of the Laizhou Bay, the Bohai Sea—Taking Brines from Core-aoli501 in Changyi Area as an Example. Marine Geology & Quaternary Geology, 23(1): 49-53 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-HYDZ200301008.htm
      Xiao, Y.K., Jin, L., Liu, W.G., et al., 1994. Chlorine Isotope Composition in Big Tsaidam Lake. Chinese Science Bulletin, 39(14): 1319-1322(in Chinese). doi: 10.1360/csb1994-39-14-1319
      Yang, L., Liu, S.F., Wang, J.S., 1998. General Geology Brief Tutorial. China University of Geosciences Press, Wuhan (in Chinese).
      Zhang, C.D., 2006. Present Situation of Trona Development in Botswana. Soda Industry, (4): 3-6(in Chinese).
      Zhang, Z.G., 2009. Unconfined Brine Hydrochemistry Characteristic and Brine Cause Analysis of East Section of Qarhan Salt Lake. Journal of Salt Lake Research, 17(1): 19-26(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-YHYJ200901006.htm
      Zheng, M.P., 2006. Salinology: Research and Prospects. Geological Review, 52(6): 737-746(in Chinese with English abstract). http://www.cqvip.com/Main/Detail.aspx?id=23387131
      Zheng, Y.H., Chen, J.F., 2000. Stable Isotope Geochemistry. Science Press, Beijing (in Chinese).
      曹博勋, 1995. 地貌学及第四纪地质学. 武汉: 中国地质大学出版社.
      樊启顺, 马海州, 谭红兵, 等, 2007. 柴达木盆地西部卤水特征及成因探讨. 地球化学, 36 (6): 601-611. doi: 10.3321/j.issn:0379-1726.2007.06.008
      刘鸿雁, 2002. 第四纪生态学与全球变化. 北京: 科技出版社.
      刘卫国, 肖应凯, 孙大鹏, 等, 1995. 马海盐湖区卤水和盐类矿物的氯同位素特征及意义. 盐湖研究, 3(2): 29-33. https://www.cnki.com.cn/Article/CJFDTOTAL-YHYJ502.004.htm
      刘卫国, 肖应凯, 孙大鹏, 等, 1996. 柴达木盆地氯同位素组成特征. 地球化学, (3): 296-303. doi: 10.3321/j.issn:0379-1726.1996.03.011
      万军伟, 刘存富, 晁念英, 等, 2003. 同位素水文学理论与实践. 武汉: 中国地质大学出版社.
      王弭力, 杨智琛, 刘成林, 等, 1996. 柴达木盆地北部盐湖钾矿床及其开发前景. 北京: 地质出版社.
      王珍岩, 孟广兰, 王少青, 2003. 渤海莱州湾南岸第四纪地下卤水演化的地球化学模拟. 海洋地质与第四纪地质. 23(1): 49-53. https://www.cnki.com.cn/Article/CJFDTOTAL-HYDZ200301008.htm
      肖应凯, 金琳, 刘卫国, 等, 1994. 大柴达木湖的氯同位素组成. 科学通报, 39(14): 1319-1322. https://www.cnki.com.cn/Article/CJFDTOTAL-KXTB199414021.htm
      杨伦, 刘少峰, 王家生, 1998. 普通地质学简明教程. 武汉: 中国地质大学出版社.
      张晨鼎, 2006. 博茨瓦纳天然碱的开发现状. 纯碱工业, (4): 3-6. doi: 10.3969/j.issn.1005-8370.2006.04.001
      张兆广, 2009. 察尔汗盐湖东段潜卤水水文地球化学特征及卤水成因分析. 盐湖研究, 17 (1): 19-26. https://www.cnki.com.cn/Article/CJFDTOTAL-YHYJ200901006.htm
      郑绵平, 2006. 盐湖学的研究与展望. 地质论评, 52 (6): 737-746. doi: 10.3321/j.issn:0371-5736.2006.06.003
      郑永红, 陈江峰, 2000. 稳定同位素地球化学. 北京: 科学出版社.
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