LA-ICP-MS微区原位准确分析含水硅酸盐矿物主量和微量元素

陈春飞; 刘先国; 胡兆初; 宗克清; 刘勇胜

doi:10.3799/dqkx.2014.050

Volume 39 Issue 5

May 2014

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Article Navigation > Earth Science > 2014 > 39(5): 525-536

Chen Chunfei, Liu Xianguo, Hu Zhaochu, Zong Keqing, Liu Yongsheng, 2014. In Situ Analysis of Major and Trace Element Compositions of Hydrous Silicate Minerals by LA-ICP-MS. Earth Science, 39(5): 525-536. doi: 10.3799/dqkx.2014.050

Citation:

Chen Chunfei, Liu Xianguo, Hu Zhaochu, Zong Keqing, Liu Yongsheng, 2014. In Situ Analysis of Major and Trace Element Compositions of Hydrous Silicate Minerals by LA-ICP-MS. Earth Science, 39(5): 525-536. doi: 10.3799/dqkx.2014.050

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In Situ Analysis of Major and Trace Element Compositions of Hydrous Silicate Minerals by LA-ICP-MS

doi: 10.3799/dqkx.2014.050

1.
State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, China
2.
School of Environmental Studies, China University of Geosciences, Wuhan 430074, China

Received Date: 2013-08-12
Publish Date: 2014-05-01

Abstract

Abstract

This paper presents a calibration strategy for LA-ICP-MS accurate analysis of major and trace elements of hydrous silicate minerals, which is internal standard-independent and applies multiple reference materials for external calibration. The total content of the volatile components in the hydrous silicate minerals was firstly calculated based on the mineral constant stoichiometry. Then, major and trace elements were quantified by calibrating against multiple reference materials (e.g., MPI-DING and USGS glasses) combined with normalization of all metal oxides to the sum of 100% minus the total volatile components. Analyses of amphibole, tremolite, tourmaline as well as epidote by LA-ICP-MS using the calibration strategy match the results of electron microprobe analyses within 5% uncertainty for the major elements which are homogeneous in samples. The results are consistent with the analysis of solution-ICP-MS combined with microsampling (diameter=300 μm) within generally 10% uncertainty for trace elements, except for those elements distributed heterogeneously in the samples. The results show that major and trace elements of hydrous silicate minerals can be accurately analyzed by LA-ICP-MS without applying internal standardization when using MPI-DING and USGS reference glasses as multiple reference materials for calibration.
- LA-ICP-MS,
- hydrous silicate mineral,
- trace element,
- accurate analysis,
- microsampling,
- geochemsitry

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References(42)

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