南堡凹陷原油高分辨质谱特征及其地球化学意义

万中华; 李素梅; 王政军; 任苗颂; 张红臣; 孟祥兵; 孙爱艳

doi:10.3799/dqkx.2015.164

Volume 40 Issue 11

Nov. 2015

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Article Navigation > Earth Science > 2015 > 40(11): 1834-1845

Wan Zhonghua, Li Sumei, Wang Zhengjun, Ren Miaosong, Zhang Hongchen, Meng Xiangbing, Sun Aiyan, 2015. Characterization of Crude Oils from Nanpu Depression by High Resolution Mass Spectrometry and Its Geochemical Significance. Earth Science, 40(11): 1834-1845. doi: 10.3799/dqkx.2015.164

Citation:

Wan Zhonghua, Li Sumei, Wang Zhengjun, Ren Miaosong, Zhang Hongchen, Meng Xiangbing, Sun Aiyan, 2015. Characterization of Crude Oils from Nanpu Depression by High Resolution Mass Spectrometry and Its Geochemical Significance. Earth Science, 40(11): 1834-1845. doi: 10.3799/dqkx.2015.164

Citation:

Wan Zhonghua, Li Sumei, Wang Zhengjun, Ren Miaosong, Zhang Hongchen, Meng Xiangbing, Sun Aiyan, 2015. Characterization of Crude Oils from Nanpu Depression by High Resolution Mass Spectrometry and Its Geochemical Significance. Earth Science, 40(11): 1834-1845. doi: 10.3799/dqkx.2015.164

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Characterization of Crude Oils from Nanpu Depression by High Resolution Mass Spectrometry and Its Geochemical Significance

doi: 10.3799/dqkx.2015.164

1.
State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum, Beijing 102249, China
2.
Research Center of Basin and Reservoir, China University of Petroleum, Beijing 102249, China
3.
Research Institute of Exploration and Development, Jidong Oilfield Company, PetroChina, Tangshan 063004, China
4.
Heavy Oil Development Company, Xinjiang Oilfield, PetroChina, Karamay 834000, China

Received Date: 2015-06-06
Publish Date: 2015-11-15

Abstract

Abstract

Nanpu depression is abundant in deep oil and gas resources, but the origin of the hydrocarbon is still unclear. High resolution mass spectrometry (negative-ion electrospray ionization (ESI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS)) is utilized to carry out the composition and distribution of heteroatom compounds of crude oils from the Nanpu depression and its geochemical significance for the first time. The heteroatoms, N₁, N₁O₁, N₁O₂, N₁O₃, N₂, O₁, O₂, O₃ and O₄ class species, were identified by negative-ion ESI FT-ICR MS. And N₁, O₁, O₂ class species are universal in all samples with higher relative abundance. It is found that thermal maturity obviously controls the distribution of carbon numbers and the degree of condensation of N₁ and O₁ class species. It is observed that parameters like C_16—20/C_21—50-DBE₁₂-N₁, C_20—24/C_25—50-DBE₁₅-N₁, DBE₁₂/DBE₉-N₁ and DBE_8—9/DBE₄-O₁ have a good correlation with Ts/Tm and TMNr. They could be used as indicators of thermal maturity of crude oils in the depression, reflecting the kinetics of thermal evolution of hydrocarbons. Significant difference was found among different layers of oils detected by negative-ion ESI FT-ICR MS, indicating that it can be applied to characterize source rocks. After a comprehensive investigation, we believe that FT-ICR MS technique is applicable in multiple geochemical aspects, such as maturity level estimation and source rock and relevant hydrocarbons determination. FT-ICR MS is significant in both the compositional characterization of the NSO compounds and the application in petroleum exploration.
- Nanpu depression,
- crude oil,
- high resolution mass spectrometry,
- maturity,
- geochemisitry.

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Characterization of Crude Oils from Nanpu Depression by High Resolution Mass Spectrometry and Its Geochemical Significance

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