石英E'心的热力学特征及其指示意义

邱登峰; 刘全有; 云金表; 朱东亚; 孟庆强; 刘佳宜; 孙冬胜

doi:10.3799/dqkx.2018.193

Volume 44 Issue 9

Sep. 2019

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Article Navigation > Earth Science > 2019 > 44(9): 2995-3006

Qiu Dengfeng, Liu Quanyou, Yun Jinbiao, Zhu Dongya, Meng Qingqiang, Liu Jiayi, Sun Dongsheng, 2019. The Thermodynamic Characteristics of Quartz E' Center and Their Significance. Earth Science, 44(9): 2995-3006. doi: 10.3799/dqkx.2018.193

Citation:

Qiu Dengfeng, Liu Quanyou, Yun Jinbiao, Zhu Dongya, Meng Qingqiang, Liu Jiayi, Sun Dongsheng, 2019. The Thermodynamic Characteristics of Quartz E' Center and Their Significance. Earth Science, 44(9): 2995-3006. doi: 10.3799/dqkx.2018.193

Citation:

Qiu Dengfeng, Liu Quanyou, Yun Jinbiao, Zhu Dongya, Meng Qingqiang, Liu Jiayi, Sun Dongsheng, 2019. The Thermodynamic Characteristics of Quartz E' Center and Their Significance. Earth Science, 44(9): 2995-3006. doi: 10.3799/dqkx.2018.193

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The Thermodynamic Characteristics of Quartz E' Center and Their Significance

doi: 10.3799/dqkx.2018.193

1.
State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing 100083, China
2.
Laboratory of Structural and Sedimentological Reservoir Geology, SINOPEC Petroleum Exploration & Production Research Institute, Beijing 100083, China

Received Date: 2017-08-27
Publish Date: 2019-09-15

Abstract

Abstract

The electron paramagnetic resonance of quartz is a dating technique through accumulated irradiation energy absorbed by minerals. Although it is commonly used in Quaternary period,the greatly enhanced EPR signals of quartz E' center after thermal activation provide opportunity for extending the dating range of EPR,while there are many different opinions on the thermal activation physical conditions and the formation and transformation mechanism of quartz E' center. In this paper,through the artificial γ ray radiation and stepwise annealing experiments to the granite and fault zone samples,the quartz E' center signal intensities under different irradiation conditions and different temperatures are measured by EPR technique,and the growth and formation mechanisms of quartz E' center are studied. The results indicate that the signal intensity of quartz E' center can be enhanced by normal artificial γ ray radiation under room temperature and by high temperature heating. The dating method and geological significance of E' center at normal and high temperature is discussed separately. The signal intensity of normal E' center is relatively constant below 150℃,and can be calibrated to calculate the accumulated dose and date fault forming age within Quaternary by normal additive dose method. The signal intensity of quartz E' center can be greatly enhanced by thermal activation and can be used to date geological age before Quaternary,but the activated peak signal intensity of known age quartz E' center should be used as a benchmark or the oxygen vacancy should be regenerated by high-dose γ ray irradiation or neutron irradiation. Then,the dose response curve of oxygen vacancy in quartz can be fitted to calculate the accumulated irradiation energy represented by the high temperature E' center. The thermodynamic peak of E' center should be determined by stepped annealing experiment and its signal intensity ratio (I₂/I₁) at high temperature and room temperature has the geological significance of recording irradiation energy and geological age.
- quartz E' center,
- electron paramagnetic resonance,
- oxygen vacancy,
- annealing experiment,
- geological age,
- structural geology

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