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    中国百强科技报刊

    湖北出版政府奖

    中国高校百佳科技期刊

    中国最美期刊

    Volume 43 Issue 5
    May  2018
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    Article Contents
    Chen Tianhu, Xie Qiaoqin, Liu Haibo, Xie Jingjing, Zhou Yuefei, 2018. Nano-Minerals and Nano-Mineral Resources. Earth Science, 43(5): 1439-1449. doi: 10.3799/dqkx.2018.403
    Citation: Chen Tianhu, Xie Qiaoqin, Liu Haibo, Xie Jingjing, Zhou Yuefei, 2018. Nano-Minerals and Nano-Mineral Resources. Earth Science, 43(5): 1439-1449. doi: 10.3799/dqkx.2018.403

    Nano-Minerals and Nano-Mineral Resources

    doi: 10.3799/dqkx.2018.403
    • Received Date: 2017-09-01
    • Publish Date: 2018-05-15
    • To promote the understanding, further research, and exploration and application of nano-minerals and nan-mineral resources, the narrow and broad conception of mineral nano-particle and nano-mineral as well as the types of nano-minerals and their morphological types are elaborated in this paper. Then, the nature of the formation and stability of nano-minerals in terms of crystal structure and crystal chemistry are discussed. It is found that formation of nano-minerals and mineral nano-particles are controlled by intrinsic factors and extrinsic factors. In addition, this paper presents the research field of nano-mineralogy and its importance in the research of critical zone. Finally, it proposes the conception and properties of nano-mineral resources and its potential applications.

       

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    • Banfield, F., Barker, W.W., 1994.Direct Observation of Reactant-Product Interfaces Formed in Natural Weathering of Exsolved, Defective Amphibole to Smectite:Evidence for Episodic, Isovolumetric Reactions Involving Structural Inheritance.Geochimica et Cosmochimica Acta, 58(5):1419-1429. doi: 10.1016/0016-7037(94)90546-0
      Banfield, F., Jillian, F., Navrotsky, A., 2001.Nanoparticle and the Environment.Reviews in Mineralogy and Geochemistry, 44:1-349. doi: 10.2138/rmg.2001.44.01
      Banfield, F., Welch, S.A., Zhang, H., et al., 2000.Aggregation-Based Crystal Growth and Microstructure Development in Natural Iron Oxyhydroxide Biomineralization Products.Science, 289(5480):751-754. doi: 10.1126/science.289.5480.751
      Bao, T., Chen, T.H., Liu, H.B., et al., 2014.Preparation of Magnetic Porous Ceramsite and Its Application in Biological Aerated Filters.Journal of Water Process Engineering, 4:185-195. doi: 10.1016/j.jwpe.2014.10.004
      Brown, G.E., Foster, A.L., Ostergren, J.D., 1999.Mineral Surfaces and Bioavailability of Heavy Metals:A Molecular-Scale Perspective.Proceedings of the National Academy of Sciences USA, 96:3388-3395. doi: 10.1073/pnas.96.7.3388
      Buseck, P.R., Dunin-Borkowski, R.E., Devouard, B., et al., 2001.Magnetite Morphology and Life on Mars.Proceedings of the National Academy of Sciences USA, 98(24):13490-13495. doi: 10.1073/pnas.241387898
      Buseck, P.R., Pósfai, M., 1999.Airborne Minerals and Related Aerosol Particles:Effects on Climate and the Environment.Proceedings of the National Academy of Sciences USA, 96:3372-3379. doi: 10.1073/pnas.96.7.3372
      Cai, D.Q., Wu, Z.Y., Jiang, J., 2009.A Unique Technology to Transform Inorganic Nanorods into Nano-Networks.Nanotechnology, 20(25):255-302. https://www.researchgate.net/publication/26258565_A_unique_technology_to_transform_inorganic_nanorods_into_nano-networks
      Cai, D.Q., Wu, Z.Y., Jiang, J.M., et al., 2014.Controlling Nitrogen Migration through Micro-Nano Networks.Scientific Reports, 4:36-65.
      Chen, P., Chen, T.H., Xu, L., et al., 2017.Mn-Rich Limonite from the Yeshan Iron Deposit, Tongling District, China:A Natural Nanocomposite.Journal of Nanoscience and Nanotechnology, 17:6931-6935. doi: 10.1166/jnn.2017.14410
      Chen, T.H., Chen, J., Ji, J.F., et al., 2005.Nano Meter-Scale Investigation on the Loess of Luochuan:Nano-Rod Calcite.Geological Review, 51(6):713-718 (in Chinese with English abstract). https://www.deepdyve.com/lp/elsevier/morphological-characters-and-multi-element-isotopic-signatures-of-ZWRFrPAU0s
      Chen, T.H., Huang, X.M., Pan, M., et al., 2009.Treatment of Coking Wastewater by Using Manganese and Magnesium Ores.Journal of Hazardous Materials, 168:843-847. doi: 10.1016/j.jhazmat.2009.02.101
      Chen, T.H., Ji, J.F., Xu, H.F., et al., 2003.Transmission Electron Microscope Observation and Genetic Analysis of Strong Magnetic Minerals in Loess.Chinese Science Bulletin, 48(17):1883-1889 (in Chinese).
      Chen, T.H., Liu, H.B., Li, J.H., et al., 2011.Effects of Thermal Treatment on Ammonia and Sulfur Dioxide Adsorption-Desorption of Palygorskite:Change of Surface Acid-Alkali Properties.Chemical Engineering Journal, 166(3):1017-1021. doi: 10.1016/j.cej.2010.11.094
      Chen, T.H., Wang, J., Xie, J., et al., 2010.Goethite-Enhanced Anaerobic Bio-Decomposition of Sulfate Minerals.Frontiers of Earth Science in China, 4(2):160-166. doi: 10.1007/s11707-010-0020-x
      Chen, T.H., Wang, J., Zhou, Y.F., et al., 2014.Synthetic Effect between Iron Oxide and Sulfate Mineral on the Anaerobic Transformation of Organic Substance.Bioresource Technology, 151:1-5. https://doi.org/10.1016/j.biortech.2013.10.014
      Chen, T.H., Wang, J.Z., Wang, J., et al., 2015.Phosphorus Removal from Aqueous Solutions Containing Low Concentration of Phosphate Using Pyrite Calcinate Sorbent.International Journal of Environmental Science and Technology, 12:885-892. doi: 10.1007/s13762-013-0450-6
      Chen, T.H., Xie, Q.Q., 2005.The Age of Electron Microscopy and Nanometer Earth Science.Journal of Hefei University of Technology (Natural Science Edition), 28(9):1126-1129 (in Chinese with English abstract). https://en.wikipedia.org/wiki/Scanning_electron_microscope
      Chen, T.H., Xie, Q.Q., Xu, X.C., 2012.Nano Minerals in Chinese Loess.Science Press, Beijing, 110-116 (in Chinese). https://www.deepdyve.com/lp/elsevier/characteristics-and-genesis-of-maghemite-in-chinese-loess-and-UURvDP4SvD
      Chen, T.H., Xu, H.F., 2003.TEM Investigation of Atmospheric Particle Settlings and Its Significance in Environmental Mineralogy.Acta Petrologica et Mineralogica, (Suppl.1):425-428 (in Chinese with English abstract).
      Chen, T.H., Xu, H.F., Peng, S.C., et al., 2004a.Direct Evidence for the Transformation of Smectite to Palygorskite:Transmission Electron Microscopy.Science China Earth Sciences, 34(3):248-255 (in Chinese). doi: 10.1360%2F03yd0509.pdf
      Chen, T.H., Xu, X.C., Yue, S.C., 2004b.Nanometer Mineralogy and Geochemistry of Palygorskite Clays in the Border of Jiangsu and Anhui Provinces.Science Press, Beijing, 65-139 (in Chinese).
      Chen, T.H., Xu, H.F., Wang, Y.F., et al., 2006.Structural Evolvement of Heating Treatment of Mg/Al-LDH and Preparation of Mineral Mesoporous Materials.Acta of Geologica Sinica (English Edition), 80(2):170-174. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dzxb-e200602002
      Cornell, R., Schwertmann, U., 1997.The Iron Oxide:Sructure, Properties, Reactions, Occurrence, and Use.Corrosion Science, 39:1499-1500. doi: 10.1016/S0010-938X(97)00096-6
      Dong, F.Q., Zhou, S.P., Li, S., 2014.Research Advance on Biological Activities of Inorganic (Mineral) Nanoparticles.Acta Mineralogic Sinica, 34(1):1-6 (in Chinese with English abstract). doi: 10.1016/j.chnaes.2013.09.003
      Duan, Y., Yao, Y.C., Qiu, X., et al., 2017.Dolomite Formation Facilitated by Three Halophilic Archaea.Earth Science, 42(3):389-396 (in Chinese with English abstract). https://doi.org/10.3799/dqkx.2017.029
      Echigo, T., Monsegue, N., Aruguete, D.M., et al., 2013.Nanopores in Hematite (α-Fe2O3) Nanocrystals Observed by Electron Tomography.American Mineralogist, 98:154-162. doi: 10.2138/am.2013.4120
      Guggenheim, S., Krekeler, P.S.M., 2011.The Structures and Microtextures of the Palygorskite-Sepiolite Group Minerals.Developments in Clay Science, 3:3-32. doi: 10.1016/B978-0-444-53607-5.00001-3
      He, X., Fu, L.J., Yang, H.M., 2014.Insight into the Nature of Au-Au2O3 Functionalized Palygorskite.Applied Clay Science, 100:118-122. doi: 10.1016/j.clay.2014.04.004
      Hochella, M.F., 2002.Nanoscience and Technology:The Next Revolution in the Earth Sciences.Earth and Planetary Science Letters, 203:593-605. doi: 10.1016/S0012-821X(02)00818-X
      Hochella, M. F., Deborah, A., Kim, B., et al., 2012. Naturally Occurring Inorganic Nanoparticles: General Assessment and a Global Budget for One of Earth's Last Unexplored Major Geochemical Components. Pan Stanford Publishing Pte. Ltd., New York, 1-31.
      Hochella, M.F., Lower, S.K., Maurice, P.A., et al., 2008.Nanominerals, Mineral Nanoparticles, and Earth Systems.Science, 319(5870):1631-1635. doi: 10.1126/science.1141134
      Huo, C.L., Yang, H.M., 2010.Synthesis and Characterization of ZnO/Palygorskite.Applied Clay Science, 50(3):362-366. doi: 10.1016/j.clay.2010.08.028
      Komeili, A., 2012.Molecular Mechanisms of Compartmentalization and Biomineralization in Magnetotactic Bacteria.FEMS Microbiology Reviews, 36(1):232-255. doi: 10.1111/j.1574-6976.2011.00315.x
      Lafay, R., Fernandez-Martinez, A., Montes-Hernandez, G., et al., 2016.Dissolution-Reprecipitation and Self-Assembly of Serpentine Nanoparticles Preceding Chrysotile Formation:Insights into the Structure of Proto-Serpentine.American Minerlogist, 101(12):2666-2676. doi: 10.2138/am-2016-5772
      Li, Q., Liu, H.B., Chen, T.H., et al., 2017.Characterization and SCR Performance of Nano-Structured Iron-Manganese Oxides:Effect of Annealing Temperature.Aerosol and Air Quality Research, 17(9):2328-2337. doi: 10.4209/aaqr.2017.07.0229
      Li, Q.L., Yi, H.S., Xia, G.Q., et al., 2017.Characteristics and Implication of Carbon and Oxygen Isotopes in Ga-Rich Manganese-Bearing Rock Series in Dongping, Guangxi.Earth Science, 42(9):1508-1518 (in Chinese with English abstract). https://doi.org/10.3799/dqkx.2017.530
      Liao, Y.Chen, D., Zou, S.J., et al., 2016.A Recyclable Naturally Derived Magnetic Pyrrhotite for Elemental Mercury Recovery from the Flue Gas.Environmental Science & Technology, 50:10562-10569.
      Liu, H.B., Chen, T.H., Chang, D.Y., et al., 2012a.Effect of Aging Time and Al Substitution on the Morphology of Aluminious Goethite.Journal of Colloid and Interface Science, 385(1):81-86. doi: 10.1016/j.jcis.2012.07.016
      Liu, H.B., Chen, T.H., Chang, D.Y., et al., 2012b.The Difference of Thermal Stability between Fe-Substituted Palygorskite and Al-Rich Palygorskite.Journal of Thermal Analysis and Calorimetry, 111(1):409-415. doi: 10.1007%2Fs10973-012-2363-x
      Liu, H.B., Chen, T.H., Xie, Q.Q., et al., 2012c.Kinetic Study of Goethite Dehydrate and the Effect of Aluminium Substitution on the Dehydrate.Thermochimica Acta, 545:20-25. doi: 10.1016/j.tca.2012.06.024
      Liu, H.B., Chen, T.H., Chang, D.Y., et al., 2013a.Effect of Rehydration on Structure and Surface Property of Thermally Treated Palygorskite.Journal of Colloid and Interface Science, 393:87-91. doi: 10.1016/j.jcis.2012.10.062
      Liu, H.B., Chen, T.H., Qing, C.S., et al., 2013b.Confirmation of the Assignment of Vibrations of Goethite:An ATR and IES Study of Goethite Structure.Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy, 116:154-159. doi: 10.1016/j.saa.2013.06.102
      Liu, H.B., Chen, T.H., Zou, X.H., et al., 2013c.Removal of Phosphorus Using NZVI Derived from Reducing Natural Goethite.Chemical Engineering Journal, 234:80-87. doi: 10.1016/j.cej.2013.08.061
      Liu, H.B., Chen, T.H., Zou, X.H., et al., 2013d.The Effect of Hydroxyl Groups and Surface Area of Hematite Derived from Annealing Goethite on Removal of Phosphate.Journal of Colloid and Interface Science, 398:88-94. doi: 10.1016/j.jcis.2013.02.016
      Liu, H.B., Chen, T.H., Zou, X.H., et al., 2013e.Thermal Treatment of Natural Goethite:Thermal Transformation and Physical Properties.Thermochimica Acta, 568:115-12. doi: 10.1016/j.tca.2013.06.027
      Liu, H.B., Chen, T.H., Zou, X.H., et al., 2013f.Effect of Al Content on the Structure of Al-Substituted Goethite:A Micro-Raman Spectroscopy Study.Journal of Raman Spectroscopy, 44:1608-1614. doi: 10.1002/jrs.4376/abstract
      Liu, H.B., Li, M.X., Chen, T.H., et al., 2017a.New Synthesis of nZVI/C Composites as Efficient Adsorbent for the Uptake of U(Ⅵ) from Aqueous Solutions.Environmental Science & Technology, 51(16):9227-9234. https://www.researchgate.net/publication/318688143_New_Synthesis_of_nZVIC_Composites_as_an_Efficient_Adsorbent_for_the_Uptake_of_UVI_from_Aqueous_Solutions
      Liu, H.B., Zhang, Z.X., Li, Q., et al., 2017b.Novel Method for Preparing Controllable Nanoporous-Fe2O3 and Its Reactivity to SCR de-NOx.Aerosol and Air Quality Research, 17(7):1898-1908. doi: 10.4209/aaqr.2017.05.0188
      Liu, H.B., Zhu, Y.K., Xu, B., et al., 2017c.Mechanical Investigation of U(Ⅵ) on Pyrrhotiteby Batch, EXAFS and Modelling Techniques.Journal Hazardous Materials, 322:488-498. doi: 10.1016/j.jhazmat.2016.10.015
      Liu, S.B., Xu, L., Chen, P., et al., 2016.Mineralogy of the Limonite Ore from the Xinqiao Sulfide Iron Deposit in the Tongling Ore Concentration Area of Anhui Province and Its Implications.Acta Petrologica et Mineralogica, 35(3):531-542 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=yskwxzz201603012
      McHale, J.M., Auroux, A., Perrotta, A.J., et al., 1997.Surface Energies and Thermodynamic Phase Stability in Nanocrystalline Aluminas.Science, 277:788-791. https://doi.org/10.1126/science.277.5327.788
      Mu, B., Zhang, W.B., Shao, S.J., et al., 2014.Glycol Assisted Synthesis of Graphene/MnO2/Polyaniline Ternary Composites for High Performance Supercapacitor Electrodes.Physical Chemistry Chemical Physics, 16:7872-7880. doi: 10.1039/c4cp00280f
      Navrotsky, A., Mazeina, L., Majzla, J., 2008.Size-Driven Structural and Thermodynamic Complexity in Iron Oxides.Science, 319:1635-1637. doi: 10.1126/science.1148614
      Nieto, F., Livi, K., 2013. Minerals at the Nanoscale. European Mineralogical Union Notes in Mineralogy, Vol. 14. The European Mineralogical Union and the Mineralogical Society of Great Britain & Ireland, London.
      Nishikiori, H., Matsunaga, S., Furuichi, N., et al., 2017.Influence of Allophane Distribution on Photocatalytic Activity of Allophane-Titania Composite Films.Applied Clay Science, 146:43-49. doi: 10.1016/j.clay.2017.05.026
      Paikaray, S., Schroeder, C., Peiffer, S., 2017.Schwertmannite Stability in Anoxic Fe(Ⅱ)-Rich Aqueous Solution.Geochimica et Cosmochimica Acta, 217:292-305. doi: 10.1016/j.gca.2017.08.026
      Penn, R.L., Banfield, J.F., 1998.Imperfect Oriented Attachment:Dislocation Generation in Defect-Free Nanocrystals.Science, 281:969-971. doi: 10.1126/science.281.5379.969
      Penn, R.L., Banfield, J.F., 1999.Morphology Development and Crystal Growth in Nanocrystalline Aggregates under Hydrothermal Conditions:Insights from Titania.Geochimica et Cosmochimica Acta, 63(10):1549-1557. doi: 10.1016/S0016-7037(99)00037-X
      Post, J.E., 1999.Manganese Oxide Minerals:Crystal Structures and Economic and Environmental Significance.Proceedings of the National Academy of Sciences USA, 96:3447-3454. doi: 10.1073/pnas.96.7.3447
      Sheng, X.F., Chen, J., Ji, J.F., et al., 2008.Morphological Characters and Multi-Element Isotopic Signatures of Carbonates from Chinese Loess-Paleosol Sequences.Geochimica et Cosmochimica Acta, 72:4323-4337. doi: 10.1016/j.gca.2008.06.024
      Siponen, M., Legrand, P., Widdrat, M., et al., 2013.Structural Insight into Magnetochrome-Mediated Magnetite Biomineralization.Nature, 100(7473):1-5. http://adsabs.harvard.edu/abs/2013Natur.502..681S
      Song, S.X., Campos-Toro, E.F., Zhang, Y.M., et al., 2013.Morphological and Mineralogical Characterizations of Oolitic Ironore in the Exi Region, China.International Journal of Minerals, Metallurgy and Materials, 20(2):113-118. doi: 10.1007/s12613-013-0701-z
      Sun, Y.S., Han, Y.X., Gao, P., et al., 2016.Growth Kinetics of Metallic Iron Phase in Coal-Based Reduction of Ooliticiron Ore.ISIJ International, 56(10):1697-1704. doi: 10.2355/isijinternational.ISIJINT-2016-253
      Sun, Z.Y., Liu, S.R., 1995.Gold and Silver Nanominerlas in Carbonaceous Material of Micrograin Gold Deposite from Guizhou, China.Journal of Chinese Electron Microscopy Society, (4):307-311 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-KWXB199001009.htm
      Tan, W., He, H.P., Wang, C.Y., et al., 2016.Magnetite Exsolution in Ilmenite from the Fe-Ti Oxide Gabbro in the Xinjie Intrusion (SW China) and Sources of Unusually Strong Remnant Magnetization.American Mineralogist, 101(12):2759-2767. doi: 10.2138/am-2016-5688
      Thill, A., Picot, P., Belloni, L.A., 2017.Mechanism for the Sphere/Tube Shape Transition of Nanoparticles with an Imogolite Local Structure (Imogolite and Allophane).Applied Clay Science, 141:308-315. doi: 10.1016/j.clay.2017.03.011
      Wang, H.L., Liu, H.B., Xie, J.J., et al., 2017.An Insight into the Carbonation of Calcined Clayey Dolomite and Its Performance to Remove Cd(Ⅱ).Applied Clay Science, 150:63-70. https://doi.org/10.1016/j.clay.2017.09.012
      Wang, Q., Zhang, J.P., Wang, A.Q., 2014.Freeze-Drying:A Versatile Method to Overcome Re-Aggregation and Improve Dispersion Stability of Palygorskite for Sustained Release of Ofloxacin.Applied Clay Science, 87:7-13. doi: 10.1016/j.clay.2013.11.017
      Wang, W.B., Wang, A.Q., 2016.Recent Progress in Dispersion of Palygorskite Crystal Bundles for Nanocomposites.Applied Clay Science, 119:18-30. doi: 10.1016/j.clay.2015.06.030
      Wang, Y.X., Mao, X.M., Depaolo, D., 2011.Nanoscale Fluid-Rock Interaction in CO2 Geological Storage.Earth Science, 36(1):163-171 (in Chinese with English abstract). https://doi.org/10.3799/dqkx.2011.017
      Wu, Z.W., Sun, X.M., Xu, H.F., et al., 2016.Occurrences and Distribution of "Invisible" Precious Metals in Sulfide Deposits from the Edmond Hydrothermal Field, Central Indian Ridge.Ore Geology Reviews, 79:105-132. doi: 10.1016/j.oregeorev.2016.05.006
      Xie, J.J., Chen, T.H., Chen, D., et al., 2013.27Al Magic Angle Rotating Nuclear Magnetic Resonance Study of Al Coordination Change in Heat Treated Attapulgite Structure.Journal of the Chinese Ceramic Society, 41(2):235-239 (in Chinese with English abstract).
      Xie, J.J., Chen, T.H., Qing, C.S., et al., 2014.Structure Evolution of Palygorskite under Heat Treatment.Earth Science Frontiers, 21(5):338-345 (in Chinese with English abstract).
      Xie, J.J., Chen, T.H., Xing, B.B., et al., 2016.The Thermochemical Activity of Dolomite Occurred in Dolomite-Palygorskite Clay.Applied Clay Science, 119:42-48. doi: 10.1016/j.clay.2015.07.014
      Xie, Q.Q., Chen, T.H., Fan, Z.L., et al., 2014.Morphological Characteristics and Genesis of Colloform Pyrite in Xinqiao Fe-S Deposit, Tongling, Anhui Province.Science China Earth Sciences, 44(12):2665-2674 (in Chinese). https://www.researchgate.net/publication/306175735_Morphological_characteristics_and_genesis_of_colloform_pyrite_in_Xinqiao_Fe-S_deposit_Tongling_Anhui_Province
      Xie, Q.Q., Chen, T.H., Xu, X.C., et al., 2008.Sudy on the Occurrence of Magnetic Minerals in Chinese Loess.Science China Earth Sciences, 38(11):1404-1412 (in Chinese). https://www.deepdyve.com/lp/elsevier/origin-of-the-magnetic-susceptibility-signal-in-chinese-loess-F4JHZj7cDb
      Xie, Q.Q., Chen, T.H., Xu, X.C., et al., 2013.Mechanism of Palygorskite Formation in the Red Clay Formation on the Chinese Loess Plateau, Northwest China.Geoderma, 192(1):39-49. https://www.deepdyve.com/lp/elsevier/mechanism-of-palygorskite-formation-in-the-red-clay-formation-on-the-jpnmyLrJwf
      Xing, B.B., Chen, T.H., Liu, H.B., et al., 2017.Removal of Phosphate from Aqueous Solution by Activated Siderite Ore:Preparation, Performance and Mechanism.Journal of the Taiwan Institute of Chemical Engineers, 80:875-882. doi: 10.1016/j.jtice.2017.07.016
      Xu, H.F., Chen, T.H., Konishi, H., 2010.HRTEM Investigation of Trilling Todorokite and Nano-Phases in Manganese Dendrites.American Mineralogist, 95(4):556-562. doi: 10.2138/am.2010.3211
      Xu, H.F., Shen, Z.Z., Konishi, H., 2014a.Si-Magnetite Nano-Precipitates in Silician Magnetite from Banded Iron Formation:Z-Contrast Imaging and Ab Initio Study.American Mineralogist, 99(11-12):2196-2202. http://adsabs.harvard.edu/abs/2014AmMin..99.2196X
      Xu, J.X., Wang, W.B., Wang, A.Q., 2014b.Enhanced Microscopic Structure and Properties of Palygorskite by Associated Extrusion and High-Pressure Homogenization Process.Applied Clay Science, 95(6):365-370. https://www.deepdyve.com/lp/elsevier/enhanced-microscopic-structure-and-properties-of-palygorskite-by-EYYV0HVq2W
      Xu, J.X., Wang, W.B., 2013.Effects of Solvent Treatment and High-Pressure Homogenization Process on Dispersion Properties of Palygorskite.Powder Technology, 235:52-660. https://www.sciencedirect.com/science/article/pii/S003259101200784X
      Xu, L., Xie, Q.Q., Chen, T.H., et al., 2017.Constraint of Nanometer-Sized Pyrite Crystals on Oxidation Kinetics and Weathering Products.Journal of Nanoscience & Nanotechnology, 17(9):6962-6966. https://www.researchgate.net/publication/318272344_Constraint_of_Nanometer-Sized_Pyrite_Crystals_on_Oxidation_Kinetics_and_Weathering_Products
      Yang, H.M., Tang, A.D., Ou, Y.J., et al., 2010.From Natural Attapulgite to Mesoporous Materials:Methodology, Characterization and Structural Evolution.The Journal of Physical Chemistry B, 114(7):2390-2398. doi: 10.1021/jp911516b
      Yang, Y., Chen, T.H., Morrison, L., et al., 2017.Nanostructured Pyrrhotite Supports Autotrophic Denitrification for Simultaneous Nitrogen and Phosphorus Removal from Secondary Effluents.Chemical Engineering Journal, 328:511-518. doi: 10.1016/j.cej.2017.07.061
      Ye, Y., Shen, Z.Y., Xiao, D.H., et al., 2002.Accumulation of Nature Nano-Submicro-Minerals:A Typical Unconventional Mineral Resources.Progress in Geophysics, 17(4):651-658 (in Chinese with English abstract).
      Yue, T.B., Chen, T.H., Xie, Q.Q., 2010.Distribution of Palygorskite in the Zhaojiachuan Section of Chinese Loess Plateau and Its Paleoclimate Significance.Geological Journal of China Universities, 16(3):383-387 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=gxdzxb201003012
      Zhang, Y.J., Zhang, J.P., Wang, A.Q., 2016.From Maya Blue to Biomimetic Pigments:Durable Biomimetic Pigments with Self-Cleaning Property.Journal of Materials Chemistry A, 4(3):901-907. doi: 10.1039/C5TA09300G
      Zou, X.H., Chen, T.H., Zhang, P., et al., 2013.Structural Characteristic of Heat Treatment Products of Natural Goethite.Journal of the Chinese Ceramic Society, 41(10):1442-1446 (in Chinese with English abstract). http://minersoc.org/pages/Archive-MM/Volume_51/51-361-437.pdf
      Zou, X.H., Chen, T.H., Liu, H.B., et al., 2016.Catalytic Cracking of Toluene over Hematite Derived from Thermally Treated Natural Limonite.Fuel, 177:180-189. doi: 10.1016/j.fuel.2016.02.094
      陈天虎, 陈骏, 季峻峰, 等, 2005.洛川黄土纳米尺度观察:纳米棒状方解石.地质论评, 51(6):713-718. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dzlp200506014
      陈天虎, 谢巧勤, 2005.电子显微镜时代与纳米地球科学.合肥工业大学学报(自然科学版), 28(9):1126-1129. http://www.cqvip.com/QK/90962X/200509/20242993.html
      陈天虎, 谢巧勤, 徐晓春, 2012.中国黄土中的纳米矿物.北京:科学出版社, 110-116.
      陈天虎, 季峻峰, 徐惠芳, 等, 2003.黄土中强磁性矿物透射电子显微镜观察和成因分析.科学通报, 48(17):1883-1889. doi: 10.3321/j.issn:0023-074X.2003.17.014
      陈天虎, 徐惠芳, 2003.大气降尘TEM观察及其环境矿物学意义.岩石矿物学杂志, (增刊1):425-428. http://www.cqvip.com/QK/94932X/2003z1/1000358575.html
      陈天虎, 徐惠芳, 彭书传, 等, 2004a.蒙脱石向凹凸棒石转化的直接证据——透射电镜观察.中国科学:地球科学, 34(3):248-255. http://mall.cnki.net/magazine/Article/JDXK200403005.htm
      陈天虎, 徐晓春, 岳书仓, 2004b.苏皖地区凹凸棒石粘土纳米矿物学及地球化学.北京:科学出版社, 65-139.
      董发勤, 周世平, 李帅, 2014.无机纳米(矿物)颗粒的生物活性研究进展.矿物学报, 34(1):1-6. http://mall.cnki.net/magazine/Article/KXTB201402007.htm
      段勇, 药彦辰, 邱轩, 等, 2017.三株嗜盐古菌诱导形成白云石.地球科学, 42(3):389-396. http://www.earth-science.net/WebPage/Article.aspx?id=3542
      李启来, 伊海生, 夏国清, 等, 2017.广西东平富Ga含锰岩系碳、氧同位素特征及意义.地球科学, 42(9):1508-1518. http://www.earth-science.net/WebPage/Article.aspx?id=3648
      刘诗贝, 徐亮, 陈平, 等, 2016.铜陵新桥矿田褐铁矿矿物组成及成因.岩石矿物学杂志, 35(3):531-542. http://www.cnki.com.cn/Article/CJFDTOTAL-YSKW201603012.htm
      孙振亚, 刘世荣, 1995.微细粒金矿床碳质中的纳米金银矿物.电子显微学报, (4):307-311. http://www.cqvip.com/QK/94421X/199504/1720547.html
      王焰新, 毛绪美, DePaolo, D., 2011.CO2地质储存的纳米尺度流体-岩石相互作用研究.地球科学, 36(1):163-171. http://www.earth-science.net/WebPage/Article.aspx?id=2075
      谢晶晶, 陈天虎, 陈冬, 等, 2013.27Al魔角旋转核磁共振研究热处理凹凸棒石结构中Al配位变化.硅酸盐学报, 41(2):235-239. http://www.cnki.com.cn/Article/CJFDTOTAL-GXYB201302020.htm
      谢晶晶, 陈天虎, 庆承松, 等, 2014.热处理凹凸棒石的结构演化.地学前缘, 21(5):338-345. http://www.cnki.com.cn/Article/CJFDTOTAL-DXQY201405035.htm
      谢巧勤, 陈天虎, 范子良, 等, 2014.铜陵新桥硫铁矿床中胶状黄铁矿微尺度观察及其成因.中国科学:地球科学, 44(12):2665-2674. http://www.oalib.com/paper/4152553
      谢巧勤, 陈天虎, 徐晓春, 等, 2008.中国黄土中磁性矿物的赋存形式研究.中国科学:地球科学, 38(11):1404-1412. http://www.cnki.com.cn/Article/CJFDTOTAL-JDXK200811008.htm
      叶瑛, 沈忠悦, 肖旦红, 等, 2002.天然纳米-亚微米矿物堆积体:一种典型的非传统矿产资源.地球物理学进展, 17(4):651-658. http://industry.wanfangdata.com.cn/dl/Detail/Periodical?id=Periodical_dqwlxjz200204014
      岳统波, 陈天虎, 谢巧勤, 2010.甘肃西峰赵家川黄土-红粘土剖面坡缕石分布及其古气候意义.高校地质学报, 16(3):383-387. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=gxdzxb201003012
      邹雪华, 陈天虎, 张萍, 2013.天然针铁矿热处理产物的结构特征.硅酸盐学报, 41(10):1442-1446. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=gsyxb201310021
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