利用低品位菱锰矿矿石热处理制备纳米材料

张常爱; 庆承松; 陈天虎; 刘海波; 陈冬; 胡玮

doi:10.3799/dqkx.2018.420

Volume 43 Issue 5

May 2018

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Article Navigation > Earth Science > 2018 > 43(5): 1670-1679

Zhang Changai, Qing Chengsong, Chen Tianhu, Liu Haibo, Chen Dong, Hu Wei, 2018. A Nanomineral Material from Thermally Treated Low Grade Natural Rhodochrosite. Earth Science, 43(5): 1670-1679. doi: 10.3799/dqkx.2018.420

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Zhang Changai, Qing Chengsong, Chen Tianhu, Liu Haibo, Chen Dong, Hu Wei, 2018. A Nanomineral Material from Thermally Treated Low Grade Natural Rhodochrosite. Earth Science, 43(5): 1670-1679. doi: 10.3799/dqkx.2018.420

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A Nanomineral Material from Thermally Treated Low Grade Natural Rhodochrosite

doi: 10.3799/dqkx.2018.420

Zhang Changai^{1,2
,},
Qing Chengsong^1,2,
Chen Tianhu^{1,2
,
,},
Liu Haibo^1,2,
Chen Dong^1,2,
Hu Wei^1,2

1.
School of Resources & Environmental Engineering, Hefei University of Technology, Hefei 230009, China
2.
Laboratory for Nanomineralogy and Environmental Material, Hefei University of Technology, Hefei 230009, China

Received Date: 2017-11-08
Publish Date: 2018-05-15

Abstract

Abstract

A nanomineral material was prepared from thermally treated low grade natural rhodochrosite in this study. The composition of natural rhodochrosite was investigated by combining XRF, TEM and chemical method. The substance and structure after calcination were characterized by TG-MS, XRD, SEM, BET, and XPS. The results show that the mineral constituents of the rhodochrosite ore are rhodochrosite, quartz, pyrite and sulfate oxidized from pyrite. When the temperature increases to 550℃, the rhodochrosite calcines gradually, releasing a great amount of CO₂, forming hausmannite and other species of MnO_x. As a result, the porous structure (massive accumulation) occurs on the surface of rhodochrosite, which has the pore sizes in 3-7 nanometer, in particular, the maximum specific surface area is 31.5 m²/g. NH₃-SCR results show that the sample R550 exhibited a high denitration performance. R550 also has a good removal efficiency of cadmium, lead and copper ions. It is indicated that the nano-porous material with better specific surface area can be prepared through calcining rhodochrosite ore at 550℃.
- rhodochrosite,
- heat treatment,
- hausmannite,
- nano-mineral,
- specific surface area,
- heavy metal,
- environmental geology

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References(48)

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A Nanomineral Material from Thermally Treated Low Grade Natural Rhodochrosite

doi: 10.3799/dqkx.2018.420

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