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    Volume 44 Issue 9
    Sep.  2019
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    Article Navigation >  Earth Science  > 2019  >  44(9): 2978-2994
    Liu Wen, Li Huan, Chen Zhengshan, Feng Yunfu, Ji Guosun, Tian Yonghong, 2019. Geochemical Characteristics and Metal Enrichment Rules of Black Shales in the Zhuxi Vanadium Ore Field, Eastern Guizhou. Earth Science, 44(9): 2978-2994. doi: 10.3799/dqkx.2019.019
    Citation: Liu Wen, Li Huan, Chen Zhengshan, Feng Yunfu, Ji Guosun, Tian Yonghong, 2019. Geochemical Characteristics and Metal Enrichment Rules of Black Shales in the Zhuxi Vanadium Ore Field, Eastern Guizhou. Earth Science, 44(9): 2978-2994. doi: 10.3799/dqkx.2019.019
    shu

    Geochemical Characteristics and Metal Enrichment Rules of Black Shales in the Zhuxi Vanadium Ore Field, Eastern Guizhou

    doi: 10.3799/dqkx.2019.019
    • 1.

      No. 117 Geological Team, Bureau of Geology and Mineral Exploration of Guizhou Province, Guiyang 550018, China

    • 2.

      Key Laboratory of Metallogenic Prediction of Nonferrous Metals and Geological Environment Monitoring of Ministry of Education, School of Geosciences and Info-Physics, Central South University, hangsha 410083, China

    • Received Date: 2019-02-16
    • Publish Date: 2019-09-15
      Abstract
    • There is an urgent need to analyze the forming environment,the metal enrichment process and ore-forming rules of the Zhuxi vanadium ore field in eastern Guizhou Province. This paper systematically studies the major and trace element compositions of ore-bearing rocks and ore strata from three typical black shale sections in the ore field. The results show that ore-bearing rocks contain high contents/values of SiO2,MnO,Ce/Ce* and Eu/Eu*,while ore strata have higher concentrations of Al2O3,Fe2O3,TiO2,CaO,Na2O,K2O,P2O5,V2O5,REE,As,Cu,Pb,Zn,Mo,Ni,Ti,Cr,Rb,Sr,Th,U and V. The major and trace element geochemical characteristics of ore-bearing rocks and ores indicate that the ore-forming source of the Zhuxi vanadium ore field had a certain degree of continental material input,whilst both hydrothermal and biological processes played a significant role during the ore-forming process. In addition,the intensities of hydrothermal process decreased from southern to northern sections and the sedimentary environment of both ore-bearing rocks and ores was anoxic. The ores from the Pingshao lithological sections were formed in the most reducing environment than those from other sections. Therefore,the V enrichment and mineralization in the Zhuxi ore field has mainly been controlled by reducing paleoenvironment and hydrothermal activity,and the reducing environment has been more significant for V mineralization. It can be inferred that ores from the Pingshao section should have been deposited in the deepest seawater environment while the ores from northern Zhongdong section had the shallowest seawater level. Exhalative fluid brought abundant V and other metal elements depositing in the vent and adjacent areas,leading to the large-scale mineralization.

       

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