高压条件下CO<sub>2</sub>对页岩微观孔隙结构影响及其在页岩中的吸附特征

张臣; 周世新; 陈科; 李靖; 陈克非; 张玉红; 李朋朋; 孙泽祥; 付德亮

doi:10.3799/dqkx.2019.107

Volume 44 Issue 11

Nov. 2019

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Article Navigation > Earth Science > 2019 > 44(11): 3773-3782

Zhang Chen, Zhou Shixin, Chen Ke, Li Jing, Chen Kefei, Zhang Yuhong, Li Pengpeng, Sun Zexiang, Fu Deliang, 2019. Impact on Microscopic Pore Structure and Adsorption Behavior of Carbon Dioxide on Shale under High Pressure Condition. Earth Science, 44(11): 3773-3782. doi: 10.3799/dqkx.2019.107

Citation:

Zhang Chen, Zhou Shixin, Chen Ke, Li Jing, Chen Kefei, Zhang Yuhong, Li Pengpeng, Sun Zexiang, Fu Deliang, 2019. Impact on Microscopic Pore Structure and Adsorption Behavior of Carbon Dioxide on Shale under High Pressure Condition. Earth Science, 44(11): 3773-3782. doi: 10.3799/dqkx.2019.107

Citation:

Zhang Chen, Zhou Shixin, Chen Ke, Li Jing, Chen Kefei, Zhang Yuhong, Li Pengpeng, Sun Zexiang, Fu Deliang, 2019. Impact on Microscopic Pore Structure and Adsorption Behavior of Carbon Dioxide on Shale under High Pressure Condition. Earth Science, 44(11): 3773-3782. doi: 10.3799/dqkx.2019.107

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Impact on Microscopic Pore Structure and Adsorption Behavior of Carbon Dioxide on Shale under High Pressure Condition

doi: 10.3799/dqkx.2019.107

Zhang Chen^{1,2,3
,
,},
Zhou Shixin^{1,2
,
,},
Chen Ke⁴,
Li Jing^1,2,
Chen Kefei^1,2,3,
Zhang Yuhong^1,2,3,
Li Pengpeng^1,2,3,
Sun Zexiang^1,2,3,
Fu Deliang⁵

1.
Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, China
2.
Key Laboratory of Petroleum Resources of Gansu Province, Lanzhou 730000, China
3.
University of Chinese Academy of Sciences, Beijing 100049, China
4.
Oil & Gas Survey, China Geological Survey, Beijing 100083, China
5.
Key Laboratory of Coal Exploration and Comprehensive Utilization, Ministry of Natural Resources, Xi'an 710016, China

Received Date: 2019-05-23
Publish Date: 2019-11-15

Abstract

Abstract

In order to understand the transformation of microscopic pore structure and adsorption behavior of carbon dioxide (CO₂) on shale under high pressure condition, using low-pressure N₂ adsorption analysis and isothermal adsorption instrument based on gravimetric method, the microstructural characteristics before and after CO₂ treatment, and the adsorption behavior of CO₂ in Jiaoye 6 shale from Jiaoshiba area of Sichuan basin were studied. The results show that the shale specific surface area decreased, and the average pore size and pore volume increased with increasing CO₂ treatment temperature. Besides, the proportions of micropore and mesopore decreased, and the proportion of macropore increased with increasing temperature. CO₂ could change the pore structure of shale, and the degree of change is positively correlated with temperature. The results also show that the excess adsorption amount of CO₂ increased with increasing pressure, reached a maximum value, and then decreased. The absolute adsorption amount of CO₂ increased with increasing pressure, and then tended to be stable after 40 MPa. The adsorption behavior of CO₂ on shale is related to temperature and pressure. Langmuir model can still fit CO₂ adsorption on shale well under high pressure.
- shale gas,
- supercritical carbon dioxide,
- microscopic pore structure,
- adsorption,
- petroleum geology

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References(50)

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Impact on Microscopic Pore Structure and Adsorption Behavior of Carbon Dioxide on Shale under High Pressure Condition

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