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    Volume 45 Issue 4
    Apr.  2020
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    Article Navigation >  Earth Science  > 2020  >  45(4): 1213-1226
    Hu Rongguo, Zhao Yilai, Cai Yongfeng, Feng Zuohai, Liu Xijun, Zhou Zhihui, Sha Peizhe, 2020. Characteristics of Biotite in the Granite Porphyry and Its Significance for Petrogenesis and Mineralization of Dachang Sn-Polymetallic Ore Deposit, Guangxi. Earth Science, 45(4): 1213-1226. doi: 10.3799/dqkx.2019.130
    Citation: Hu Rongguo, Zhao Yilai, Cai Yongfeng, Feng Zuohai, Liu Xijun, Zhou Zhihui, Sha Peizhe, 2020. Characteristics of Biotite in the Granite Porphyry and Its Significance for Petrogenesis and Mineralization of Dachang Sn-Polymetallic Ore Deposit, Guangxi. Earth Science, 45(4): 1213-1226. doi: 10.3799/dqkx.2019.130
    shu

    Characteristics of Biotite in the Granite Porphyry and Its Significance for Petrogenesis and Mineralization of Dachang Sn-Polymetallic Ore Deposit, Guangxi

    doi: 10.3799/dqkx.2019.130
    • 1.

      Guangxi Key Laboratory of Hidden Metallic Ore Deposits Exploration, College of Earth Sciences, Guilin University of Technology, Guilin 541004, China

    • 2.

      Liuzhou Huaxi Co. Ltd., Liuzhou 545006, China

    • Received Date: 2019-05-30
    • Publish Date: 2020-04-15
      Abstract
    • The Dachang Sn-polymetallic ore deposit,Guangxi,is one of the largest tin deposits in the world. The granite porphyry occurs in the eastern side of the Tongkeng-Changpo-Bali-Longtoushan area,which is mainly controlled by nearly SN extensional tectonics and has superimposed and reformed the ore bodies formed in the early stage. To further evaluate the petrogenesis and associated hydrothermal mineralization of the granite porphyry,detailed electron microprobe analyses were performed on three modes of biotite occurrence:inclusions enclosed in quartz,phenocrysts and matrix as one of rock-forming minerals. The biotites of different occurrences are all classified as magmatic ferrobiotites,reflecting that their host rock has high basicity. Biotite matrixes contain higher FeOt,MnO and Li2O but lower MgO and TiO2 than those occur as phenocryst and inclusion. The estimated crystallization temperatures for phenocryst and inclusion biotites are 688-715℃ and pressure conditions range from 1.7 to 2.3 kbar,equivalent to emplacement depth of 6.3-8.4 km. In contrast,the calculated crystallization temperatures for matrix biotites are 630-673℃ and pressure conditions range from 1.6 to 2.0 kbar,equivalent to emplacement depth of 6.0-7.4 km. Systematic differences in oxygen fugacity between biotites related to inclusion (-17.0 to -16.6),phenocryst (-17.0 to -16.1) and matrix (-19.0 to -17.4) are found,which are characterized by a trend of decreasing oxygen fugacities in the direction of magma upwelling,suggesting that the diagenetic conditions change from relative oxidizing condition to reducing condition. Magmatic biotite composition is useful in the calculation of the halogen fugacity in magma during its crystallization,which are represented by lg(fH2O/fHF)Fluid,lg(fH2O/fHCl)Fluid and lg(fHF/fHCl)Fluid values. These values for phenocrystys are 3.41-3.82,3.78-4.07 and -0.54 to -0.17 respectively; for inclusions are 3.90-4.11,3.86-4.11 and -0.74 to -0.43 respectively; and for matrix are 3.90-4.39,3.85-4.96 and -0.61-0.25 respectively,which indicates that the coexisting hydrothermal fluids associated with phenocrysty,inclusion and matrix biotite crystallization are not continuous episode but differences in composition. The changes in the composition of biotites regarding to inclusion,phenocrysts and matrix,indicate that the early stage of the magma crystallization is characterized by high temperature,high basicity and low oxygen fugacity. These characteristics could have been beneficial to the activation,migration and concentration of the Sn element,as well as to further transformation on the earlier formed deposit.

       

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