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    中国百强科技报刊

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    Volume 44 Issue 11
    Nov.  2019
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    Article Contents
    Tian Wei, Wang Chuanshang, Bai Yunshan, Li Peijun, 2019. Shale Geochemical Characteristics and Enrichment Mechanism of Organic Matter of the Upper Devonian Shetianqiao Formation Shale in Lianyuan Sag, Central Hunan. Earth Science, 44(11): 3794-3811. doi: 10.3799/dqkx.2019.156
    Citation: Tian Wei, Wang Chuanshang, Bai Yunshan, Li Peijun, 2019. Shale Geochemical Characteristics and Enrichment Mechanism of Organic Matter of the Upper Devonian Shetianqiao Formation Shale in Lianyuan Sag, Central Hunan. Earth Science, 44(11): 3794-3811. doi: 10.3799/dqkx.2019.156

    Shale Geochemical Characteristics and Enrichment Mechanism of Organic Matter of the Upper Devonian Shetianqiao Formation Shale in Lianyuan Sag, Central Hunan

    doi: 10.3799/dqkx.2019.156
    • Received Date: 2019-06-28
    • Publish Date: 2019-11-15
    • The Upper Devonian Shetianqiao Formation shale is one of the most important shale gas exploration beds in Lianyuan sag of Xiangzhong depression. In order to discuss the organic matter enrichment mechanism of the Shetianqiao Formation shale, 20 shale core samples collected systematically from Well XXD-3 were chosen.The organic carbon content, major, trace and rare earth elements were analyzed to investigate the paleo-salinity, paleo-climate, paleo-redox and paleo-productivity characteristics of the Upper Devonian sedimentary environment in Lianyuan sag of Xiangzhong depression. Research illustrates that the organic carbon content is higher (1.28%-2.68%) at the bottom of Shetianqiao Formation, with an average of 1.69%. Major components of shale include SiO2(50.27%), Al2O3(13.66%), CaO (11.55%). Trace elements Rb, Sr and Zr are enriched while Co, Mo, Sc and Hf are depleted. The ratio of Sr/Ba, CIA, Th/U, V/Sc, V/Cr, and δU suggest that Shetianqiao Formation organic-rich shales should be deposited in fresh-brackish water, arid climate and suboxic to anoxic environment, while organic-poor shales were mostly deposited in salt water, arid to semi-arid climate and oxygen-enriched environment. Combining with the regional sequence stratigraphic characteristics, comprehensive comparison of the correlation among organic carbon content (TOC), paleo-redox and paleo-productivity conditions, it is revealed that the main controlling factors of organic matter enrichment of Shetianqiao Formation organic-rich shales are redox environment. The changes in organic matter content of Shetianqiao Formation organic-poor shales are predominantly controlled by terrigenous supply.

       

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