漓江流域碳氮同位素组成特征及其来源初探

任梦梦; 黄芬; 胡晓农; 曹建华; 张鹏

doi:10.3799/dqkx.2019.206

Volume 45 Issue 5

May 2020

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Article Navigation > Earth Science > 2020 > 45(5): 1830-1843

Ren Mengmeng, Huang Fen, X. Hu Bill, Cao Jianhua, Zhang Peng, 2020. Characteristics and Sources of Dissolved Inorganic Carbon and Nitrate in Lijiang River Basin. Earth Science, 45(5): 1830-1843. doi: 10.3799/dqkx.2019.206

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Ren Mengmeng, Huang Fen, X. Hu Bill, Cao Jianhua, Zhang Peng, 2020. Characteristics and Sources of Dissolved Inorganic Carbon and Nitrate in Lijiang River Basin. Earth Science, 45(5): 1830-1843. doi: 10.3799/dqkx.2019.206

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Characteristics and Sources of Dissolved Inorganic Carbon and Nitrate in Lijiang River Basin

doi: 10.3799/dqkx.2019.206

1.
School of Water Resources and Environment, China University of Geosciences, Beijing 100083, China
2.
Key Laboratory of Karst Dynamics, Guangxi Institute of Karst Geology, Chinese Academy of Geological Sciences, Ministry of Natural Resources, Guilin 541004, China

Received Date: 2019-08-17
Publish Date: 2020-05-15

Abstract

Abstract

The distribution characteristics and sources of DIC and nitrate in the Lijiang River basin are studied using isotope mass balance models, by which the hydrochemical composition of the surface and underground rivers in the Lijiang River basin, δ¹³C_DIC, δ¹⁵N-NO₃^- and δ¹⁸O-NO₃^- are measured and analyzed. The results show that the concentration of DIC (HCO₃^-) and inorganic carbon stable isotopes (δ¹³C_DIC) in Lijiang River basin range from 12.20 to 402.60 mg·L^-1, and from -17.29‰ to -10.01‰ respectively, with the average value of 140.3 mg·L^-1 and -13.06‰ respectively. The concentration of NO₃^- is between 2.37 and 35.38 mg·L^-1, and δ¹⁵N-NO₃^- is between 0.99‰ and 11.09‰, both showing obvious spatial variation characteristics. It is concluded that organic manure and sewage have the most significant contribution to nitrate in the Lijiang River basin, with a contribution ratio of 57.00%, which is followed by NH₄⁺ in fertilizer and precipitation, and soil N, with contribution ratios of 36.45% and 6.55% respectively. The source of DIC in the drainage basin is mainly due to the weathering of carbonate rocks and the dissolution of soil CO₂, which is also affected by the corrosion of carbonate rocks by nitric acid and atmospheric CO₂. The corrosion intensity of nitric acid on carbonate rocks is controlled not only by the degree of nitrogen pollution in water, but also by the source of nitrogen pollution. The results can provide a basis for customizing effective nitrate input channels and purifying water quality.
- Lijiang River,
- δ¹³C_DIC,
- dissolved inorganic carbon (DIC),
- δ¹⁵N-NO₃^-,
- δ¹⁸O-NO₃^-,
- nitrate,
- hydrogeology

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References(65)

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Characteristics and Sources of Dissolved Inorganic Carbon and Nitrate in Lijiang River Basin

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