湖南锡田钨锡多金属矿床流体包裹体显微测温和LA-ICP-MS原位分析对成矿流体演化的制约

周云; 黄惠兰; 于玉帅; 李芳; 谭靖

doi:10.3799/dqkx.2020.364

Volume 46 Issue 4

Apr. 2021

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Article Navigation > Earth Science > 2021 > 46(4): 1248-1268

Zhou Yun, Huang Huilan, Yu Yushuai, Li Fang, Tan Jing, 2021. Constraints on the Evolution of Ore-Forming Fluids from Microthermometric and In Situ LA-ICP-MS Analyses of Fluid Inclusions in Xitian Tungsten Tin Polymetallic Deposit, Hunan Province. Earth Science, 46(4): 1248-1268. doi: 10.3799/dqkx.2020.364

Citation:

Zhou Yun, Huang Huilan, Yu Yushuai, Li Fang, Tan Jing, 2021. Constraints on the Evolution of Ore-Forming Fluids from Microthermometric and In Situ LA-ICP-MS Analyses of Fluid Inclusions in Xitian Tungsten Tin Polymetallic Deposit, Hunan Province. Earth Science, 46(4): 1248-1268. doi: 10.3799/dqkx.2020.364

Citation:

Zhou Yun, Huang Huilan, Yu Yushuai, Li Fang, Tan Jing, 2021. Constraints on the Evolution of Ore-Forming Fluids from Microthermometric and In Situ LA-ICP-MS Analyses of Fluid Inclusions in Xitian Tungsten Tin Polymetallic Deposit, Hunan Province. Earth Science, 46(4): 1248-1268. doi: 10.3799/dqkx.2020.364

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Constraints on the Evolution of Ore-Forming Fluids from Microthermometric and In Situ LA-ICP-MS Analyses of Fluid Inclusions in Xitian Tungsten Tin Polymetallic Deposit, Hunan Province

doi: 10.3799/dqkx.2020.364

Zhou Yun^{1, 2
,
,},
Huang Huilan¹,
Yu Yushuai^{1, 2
,
,},
Li Fang¹,
Tan Jing¹

1.
Wuhan Center of Geological Survey, China Geological Survey, Wuhan 430205, China
2.
Research Center for Petrogenesis and Mineralization of Granitoid Rocks, China Geological Survey, Wuhan 430205, China

Received Date: 2020-06-19
Publish Date: 2021-04-15

Abstract

Abstract

In order to understand the evolution process of ore-forming fluid and the migration mechanism of ore-forming elements in Xitian tungsten tin polymetallic deposit, to further reveal the ore-forming mechanism and guide the next exploration work in this area. The fluid inclusions of wolframite, cassiterite and transparent minerals were studied by petrographic observation, infrared microthermometry and in situ LA-ICP-MS analysis of fluid inclusions. The results show that fluid-melt inclusions are developed in beryl and wolframite in Xitian tungsten tin polymetallic deposit, and the highest homogenization temperature is 760℃. At the early stage of mineralization, the fluid homogenization temperature is 360-500℃, the salinity is mainly 28.44%-41.50% NaCl_eqv. At the main mineralization stage, the homogenization temperature is 280-450℃, the salinity is mainly 3.0%-20.03% NaCl_eqv. At the late mineralization stage, the homogenization temperature is 120-280℃, and the salinity is 0.35%-6.58% NaCl_eqv. LA-ICP-MS analysis shows that W, Cu, Mo elements are preferentially enriched in the volatile, while Pb, Zn, Sn, Fe, Mn elements are preferentially enriched in the high salinity brine phase. The ore forming fluid in Xitian W-Sn polymetallic deposit comes from Yanshanian granite, and the mineralization of W-Sn started from the stage of magma-hydrothermal transition, and the ore-forming fluid has the characteristics of high temperature, high salinity and rich CO₂. The ore-forming fluid comes from the dissolution of magmatic fluid, which has experienced two immiscible processes in the evolution process. In the process of immiscible phase separation, the ore-forming elements migrate selectively and distribute unevenly in each phase. Fluid immiscibility, water rock reaction, fluid mixing and fluid cooling are the main reasons for the precipitation of W-Sn minerals in the deposit.
- magma-hydrothermal transition,
- immiscibility,
- metallogenic fluid evolution,
- W-Sn deposit,
- mineral deposits,

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References(84)

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Constraints on the Evolution of Ore-Forming Fluids from Microthermometric and In Situ LA-ICP-MS Analyses of Fluid Inclusions in Xitian Tungsten Tin Polymetallic Deposit, Hunan Province

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