长江中游沿岸地下水中有机质分子组成特征及其对碘富集的指示

薛江凯; 邓娅敏; 杜尧; 罗义鹏; 程一涵

doi:10.3799/dqkx.2020.398

Volume 46 Issue 11

Nov. 2021

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Article Navigation > Earth Science > 2021 > 46(11): 4140-4149

Xue Jiangkai, Deng Yamin, Du Yao, Luo Yipeng, Cheng Yihan, 2021. Molecular Characterization of Dissolved Organic Matter (DOM) in Shallow Aquifer along Middle Reach of Yangtze River and Its Implications for Iodine Enrichment. Earth Science, 46(11): 4140-4149. doi: 10.3799/dqkx.2020.398

Citation:

Xue Jiangkai, Deng Yamin, Du Yao, Luo Yipeng, Cheng Yihan, 2021. Molecular Characterization of Dissolved Organic Matter (DOM) in Shallow Aquifer along Middle Reach of Yangtze River and Its Implications for Iodine Enrichment. Earth Science, 46(11): 4140-4149. doi: 10.3799/dqkx.2020.398

Citation:

Xue Jiangkai, Deng Yamin, Du Yao, Luo Yipeng, Cheng Yihan, 2021. Molecular Characterization of Dissolved Organic Matter (DOM) in Shallow Aquifer along Middle Reach of Yangtze River and Its Implications for Iodine Enrichment. Earth Science, 46(11): 4140-4149. doi: 10.3799/dqkx.2020.398

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Molecular Characterization of Dissolved Organic Matter (DOM) in Shallow Aquifer along Middle Reach of Yangtze River and Its Implications for Iodine Enrichment

doi: 10.3799/dqkx.2020.398

Xue Jiangkai^{1
,
,},
Deng Yamin^{2
,
,
,},
Du Yao²,
Luo Yipeng¹,
Cheng Yihan²

1.
Institute of Geological Survey, China University of Geosciences, Wuhan 430074, China
2.
School of Environmental Studies, China University of Geosciences, Wuhan 430078, China

Received Date: 2020-11-25
Available Online: 2021-12-04
Publish Date: 2021-11-30

Abstract

Abstract

Long-term uptake of high iodine groundwater (iodine concentration > 100 μg/L) leads to thyroid dysfunction. Natural organic matter is considered to be the key factor affecting the formation of high iodine groundwater. In order to figure out the impact of molecular composition of dissolved organic matter(DOM) on iodine enrichment in groundwater, the DOM in shallow groundwater with different iodine concentrations along the Middle Reach of the Yangtze River was characterized by FT-ICR-MS. Results indicate that iodine was easily enriched in strong reducing environment, and iodine concentrations in groundwater had no significant relationship with DOC concentrations, but had a significant positive correlation with numbers of DOM molecules. Compared with low iodine groundwater, DOM in high iodine groundwater characterized with greater uniformity and diversity, more oxidized and unsaturated molecular composition, containing more aromatic structures. The enrichment of iodine in shallow groundwater along the Middle Reach of the Yangtze River was closely related to the molecular composition of DOM. Complexation of DOM molecules containing aromatic structure with iodine plays an important role in the formation of high iodine groundwater.
- groundwater,
- iodine,
- dissolved organic matter,
- molecular composition,
- FT-ICR-MS,
- hydrogeology

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References(45)

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Molecular Characterization of Dissolved Organic Matter (DOM) in Shallow Aquifer along Middle Reach of Yangtze River and Its Implications for Iodine Enrichment

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