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    Volume 47 Issue 2
    Feb.  2022
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    Luo Yipeng, Deng Yamin, Du Yao, Xue Jiangkai, Sun Xiaoliang, 2022. Occurrence and Formation of High Iodine Groundwater Inoxbows of the Middle Reach of the Yangtze River. Earth Science, 47(2): 662-673. doi: 10.3799/dqkx.2021.031
    Citation: Luo Yipeng, Deng Yamin, Du Yao, Xue Jiangkai, Sun Xiaoliang, 2022. Occurrence and Formation of High Iodine Groundwater Inoxbows of the Middle Reach of the Yangtze River. Earth Science, 47(2): 662-673. doi: 10.3799/dqkx.2021.031

    Occurrence and Formation of High Iodine Groundwater Inoxbows of the Middle Reach of the Yangtze River

    doi: 10.3799/dqkx.2021.031
    • Received Date: 2021-03-29
    • Publish Date: 2022-02-25
    • High iodine groundwater (iodine concentration greater than 100 μg/L) is widely distributed in coastal areas and arid inland basins in China, threatening the drinking water safety of nearly ten million people, but the understanding of the distribution andformationof iodine in groundwater in humid areas is still very weak. In this study, 75 shallow groundwater samples and 7 surface water samples were collected fromoxbowsof the middle reach of the Yangtze River for hydrogeochemical analysis, the spatial distribution characteristics of iodine in groundwater were identified, the water environmental factors and hydrogeochemical process of iodine enrichment were identified by principal component analysis, and the control effect of sedimentary environment evolution on iodine enrichment was discussed through the lithological analysis of four boreholes at different locations. The concentration of iodine in groundwater ranged from 0.78 μg/L to 1 590 μg/L, and 25% of the samples exceed the determination value of water iodine content in water source areas with high iodine content in China (100 μg/L). The high iodine groundwater mainly occurs in the shallow confined aquifer, distributed in the concave bank of the Yangtze River and the clayfilled oxbow lake. The strong reducing environment rich in organic matter buried under the deposition in oxbows of the middle reach of Yangtze River is conducive to the release of iodine from the sediments to groundwater. Microbially degradation of organic matter and reductive dissolution of iron hydroxide in aquifer sediments are the main hydrogeochemical processes controlling the formation of high iodine groundwater in the study area. The low-permeability clay packing in the later period of the oxbow lake and the thick clay layer deposited on the concave bank of the river meander created a closed and stagnant groundwater environment for iodine enrichment.

       

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