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| Citation: | Wang Shuli, Zheng Mianping, Li Boyun, Wang Zhanwen, Wang Yinglin, Wang Fan, Su Kui, Li Jin, Wang Ying, 2022. Index System for Potassium Prospecting in Marine Potash Deposits: A Case Study of Cambrian Deep Brine from Tianxingqiao Structure of Northeast Sichuan in China. Earth Science, 47(1): 2-14. doi: 10.3799/dqkx.2021.107
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Through summary of long-term work, it is found that the value of Br×103/Cl, which is commonly used, is low. In this paper, it innovatively clarifies the index system for potassium prospecting of marine evaporative basin by using the "ancient test" leaching experiment and geological statistics method. This method fully considers the changes of seawater composition in different geological years and can also overcome the insufficiency of data for applying modern seawater under isothermal and pressure conditions. Through the leaching experiment of rock salt, potassium-bearing salt and potassium salt (including carnallite) of the typical potash deposits in the world, and combining the previous evaporation experiment results of sea water and marine brine, the index system for potassium prospecting in mineral deposit: Br×103/Cl, K×103/Cl, K/Br, nNa/nCl, nMg/nCl, is summarized. This study aims to trace the origin of the brine which is Cambrian deep brine from Tianxingqiao structure of Northeast Sichuan Basin by analyzing its hydrochemical characteristics (weight ratios of Br×103/Cl, K×103/Cl and K/Br, and molar ratios of nNa/nCl and nMg/nCl). The results show that the hydrochemical characteristics and δD and δ18O values of the brine from Tianxingqiao are similar to those of the brine from dissolution and that of the salt precipitates, but have distinct difference from that of the primary brine. Therefore, it is believed the formation brine from Tianxingqiao is sourced from meteoric water and the brine salinity come from saliferous strata, which might come from the dissolution of halite beds or even the sylvinite beds. This finding is in contrast to the previous studies which held that the brine is primary brine. This study provides new and important information for searching potash deposits in this area.
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