岩溶洞穴系统SO42-、NO3-来源及其对水岩作用的影响

石亮星; 周忠发; 张恒; 安丹; 丁圣君; 黄静; 董慧

doi:10.3799/dqkx.2021.115

Volume 47 Issue 2

Feb. 2022

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Article Navigation > Earth Science > 2022 > 47(2): 607-621

Shi Liangxing, Zhou Zhongfa, Zhang Heng, An Dan, Ding Shengjun, Huang Jing, Dong Hui, 2022. Sources of SO42- and NO3- and Their Disturbances to Water Rock Processes in Karst Cave Systems. Earth Science, 47(2): 607-621. doi: 10.3799/dqkx.2021.115

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Shi Liangxing, Zhou Zhongfa, Zhang Heng, An Dan, Ding Shengjun, Huang Jing, Dong Hui, 2022. Sources of SO₄^2- and NO₃^- and Their Disturbances to Water Rock Processes in Karst Cave Systems. Earth Science, 47(2): 607-621. doi: 10.3799/dqkx.2021.115

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Sources of SO₄^2- and NO₃^- and Their Disturbances to Water Rock Processes in Karst Cave Systems

doi: 10.3799/dqkx.2021.115

Shi Liangxing^{1, 2
,
,},
Zhou Zhongfa^{1, 2
,
,
,},
Zhang Heng^{1, 2},
An Dan^{1, 2},
Ding Shengjun^{1, 2},
Huang Jing^{1, 2},
Dong Hui^{1, 2}

1.
College of Karst Institute/Geography and Environmental Science, Guizhou Normal University, Guiyang 550001, China
2.
National Key Laboratory Breeding Base of Karst Mountain Ecological Environment in Guizhou Province, Guiyang 550001, China

Received Date: 2021-10-26
Publish Date: 2022-02-25

Abstract

Abstract

In order to reveal the source of SO₄^2-and NO₃^-in the cave water and their influence on the hydrogeochemical process, a complete hydrological year monitoring was carried out at six monitor points in Mahuang Cave from August 2018 to July 2019. The results showed as follows: (1)The cave waters hydrochemical types are HCO₃-Ca·Mg and HCO₃·SO₄-Ca·Mg; (2)SO₄^2- and NO₃^- are mainly derived by agricultural activities, atmospheric deposition and gypsum dissolution, and their sources are different at different drip points. NO₃^- in the Mahuang cave is mainly caused by agricultural activities and atmospheric N deposition, while SO₄^2- is supplemented by agricultural activities and gypsum dissolution; The SO₄^2- and NO₃^- both participate in the karstification and accelerate the dissolution of bedrock; (3)Based on the estimation of hydrochemistry method and stable isotope technique, the contribution of DIC of SO₄^2- and NO₃^-cave water ranges from 0.05 to 0.61. The release of DIC also changes the ion concentration in the water, causing disturbance to karstification and presenting a general pattern of Dry season > Rainy season and dripwaters > fissure water. Similarly, due to the complexity and unknowability of karst area, the combination and comparison of various methods should be paid attention to in the systematic study of karst area, so as to improve the accuracy and credibility of the study.
- Karst caves,
- water-rock process,
- SO₄^2-and NO₃^-,
- Mahuang Cave,
- hydrogeology

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References(43)

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Sources of SO42- and NO3- and Their Disturbances to Water Rock Processes in Karst Cave Systems

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Sources of SO₄^2- and NO₃^- and Their Disturbances to Water Rock Processes in Karst Cave Systems