燕山地区中-新元古界烃源岩地球化学特征及油源对比

孙中良; 陈媛; 李志明; 申宝剑; 祝庆敏; 贾梦瑶; 吴琰

doi:10.3799/dqkx.2022.125

Volume 49 Issue 5

May 2024

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Article Navigation > Earth Science > 2024 > 49(5): 1844-1864

Sun Zhongliang, Chen Yuan, Li Zhiming, Shen Baojian, Zhu Qingmin, Jia Mengyao, Wu Yan, 2024. Geochemical Characteristics of the Meso-Neoproterozoic Source Rocks and Oil-Source Correlations in the Yanshan Area. Earth Science, 49(5): 1844-1864. doi: 10.3799/dqkx.2022.125

Citation:

Sun Zhongliang, Chen Yuan, Li Zhiming, Shen Baojian, Zhu Qingmin, Jia Mengyao, Wu Yan, 2024. Geochemical Characteristics of the Meso-Neoproterozoic Source Rocks and Oil-Source Correlations in the Yanshan Area. Earth Science, 49(5): 1844-1864. doi: 10.3799/dqkx.2022.125

Citation:

Sun Zhongliang, Chen Yuan, Li Zhiming, Shen Baojian, Zhu Qingmin, Jia Mengyao, Wu Yan, 2024. Geochemical Characteristics of the Meso-Neoproterozoic Source Rocks and Oil-Source Correlations in the Yanshan Area. Earth Science, 49(5): 1844-1864. doi: 10.3799/dqkx.2022.125

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Geochemical Characteristics of the Meso-Neoproterozoic Source Rocks and Oil-Source Correlations in the Yanshan Area

doi: 10.3799/dqkx.2022.125

Sun Zhongliang^{1, 2, 3, 4
,
,},
Chen Yuan^{1, 2, 3, 4},
Li Zhiming^{1, 2, 3, 4},
Shen Baojian^{1, 2, 3, 4},
Zhu Qingmin^{1, 2, 3, 4},
Jia Mengyao^{1, 2, 3, 4},
Wu Yan⁵

1.
Wuxi Research Institute of Petroleum Geology, Petroleum Exploration & Production Research Institute, SINOPEC, Wuxi 214126, China
2.
State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Wuxi 214126, China
3.
State Energy Center for Shale Oil Research and Development, Wuxi 214126, China
4.
Key Laboratory of Hydrocarbon Accumulation Mechanism, SINOPEC, Wuxi 214126, China
5.
China University of Geosciences, Wuhan 430074, China

Received Date: 2022-03-20
Available Online: 2024-06-04
Publish Date: 2024-05-25

Abstract

Abstract

The enrichmentof Meso-Neoproterozoic oil and gas in Yanshan area has been the hot topic focused on by scholars. Total Organic Carbon (TOC) test, pyrolysis, gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) and other methods are applied in this paper to discuss organic geochemical characteristics of samples. Especially, the biomarker compounds, organic matter sources and sedimentary environment are discussed in detail. The geochemical and biomarker characteristics of oil seepage/asphalt and source rocks are compared to identify the major source rocks of Meso-Neoproterozoic strata in Yanshan Region. The results show that the source rocks of the Xiamaling and Hongshuizhuang formations, featured with high content of organic carbons, great hydrocarbon generation potential and moderate degree of thermal evolution, are good and supreme source rocks.The source rocks of Tieling Formation are poor-medium source rocks, and the degree of thermal evolution of Gaoyuzhuang Formation is excessively high to determine the type of source rocks. According to the characteristics of biomarkers in the researched area, the source rocks are divided into two categories. Wherein, the source rocks of Hongshuizhuang, Tieling and Xiamaling Formations are classified into Category Ⅰ. The relative contents of acyclic isoprene pristane (Pr) and phytane (Ph) are very low, with certain abundance of regular C₂₀ tricyclic terpane (C₂₀TT), C₁₉TT and special 13α (n-alkyl) - tricyclic terpanes, rich in tetracyclic terpane (C₂₄TeT), norneohopane (Ts and C₂₉Ts) and rearranged hopanes (C₃₀Dia), and are characterized by the absence of sterane compound.Revealing moderate degree of thermal evolution, anoxic sedimentary environment and a special hydrocarbon generating organism of Category Ⅰ source rocks. Gaoyuzhuang Formation, provided with Category Ⅱsource rocks, is characterized with high abundance of C₂₃-C₂₅TT and regular hopane, common C₂₇-C₂₉ regular steranes, low abundance of C₂₄ tetracyclic terpane, norneohopane and rearranged hopane, and no drimane and 13α (n-alkyl)-featured with tricyclic terpene serial compound is detected, showing the characteristics of crude oil in typical marine carbonate sedimentary environment and indicating various biological sources. The oil and source rock correlation shows that Category Ⅰ oil seepage/asphalt mainly originates from the source rocks of Hongshuizhuang Formation, while the organic geochemical composition characteristics of CategoryⅡasphalt sandstone are extremely similar to the source rocks of Gaoyuzhuang Formation.
- Yanshan area,
- Meso-Neoproterozoic,
- characteristics of source rocks,
- biomarker compound,
- oil-source correlation,
- geochemistry,
- petroleum geology

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