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    中国百强科技报刊

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    Volume 48 Issue 4
    Apr.  2023
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    Article Contents
    Liu Ruobing, Wei Zhihong, Jia Aoqi, He Sheng, Hou Yuguang, He Qing, Wang Tao, Zeng Yu, Yang Rui, 2023. Fractal Characteristics of Pore Structure in Deep Overpressured Organic-Rich Shale in Wufeng-Longmaxi Formation in Southeast Sichuan and Its Geological Significance. Earth Science, 48(4): 1496-1516. doi: 10.3799/dqkx.2022.177
    Citation: Liu Ruobing, Wei Zhihong, Jia Aoqi, He Sheng, Hou Yuguang, He Qing, Wang Tao, Zeng Yu, Yang Rui, 2023. Fractal Characteristics of Pore Structure in Deep Overpressured Organic-Rich Shale in Wufeng-Longmaxi Formation in Southeast Sichuan and Its Geological Significance. Earth Science, 48(4): 1496-1516. doi: 10.3799/dqkx.2022.177

    Fractal Characteristics of Pore Structure in Deep Overpressured Organic-Rich Shale in Wufeng-Longmaxi Formation in Southeast Sichuan and Its Geological Significance

    doi: 10.3799/dqkx.2022.177
    • Received Date: 2022-01-19
    • Publish Date: 2023-04-25
    • To clarify the micropore structure and fractal characteristics of deep overpressured organic-rich shale in Wufeng and Longmaxi Formations in Southeast Sichuan basin, in this work it takes the organic-rich shales in Wufeng and Longmaxi Formations from four typical wells in the Dingshan and Dongxi areas as the research object. After ascertaining the mineralogical and geochemical characteristics of shale rocks, high-resolution scanning electron microscope, low-temperature gas (N2, CO2) adsorption, and mercury intrusion porosimetry experiments are used to qualitatively and quantitatively characterize the micropore structure of organic shale from the Wufeng and Longmaxi Formations. Based on gas (CO2 and N2) adsorption, mercury intrusion porosimetry and fractal theory, the fractal dimensions of pores in shale are calculated, and the internal relations between pore structure parameters, mineral composition, total organic carbon (TOC) content and fractal dimension of shale in different lithofacies are discussed. Results show that organic pores, inorganic pores (intergranular pores and intragranular pores) and microfractures are widely developed in these shale samples from Wufeng and Longmaxi Formations in the Dingshan and Dongxi areas. The pore morphology is dominated by wedge-shaped, slit-shaped or some parallel plate pores. The pore size distribution is multimodal. Mesoporeis the main contributor to the total pore volume (accounting for approximately 59%), and micropores are the minor contributor to the total pore volume (accounting for approximately 35%). The contribution of macropore to the total pore volume is relatively small. Influenced by the differences of rock composition, TOC content and diagenesis, the pores of different shale lithofacies show various evolution characteristics, resulting in strong heterogeneity and complex pore structure. The pores of the Wufeng-Longmaxi shale in the study area have obvious multi-scale fractal characteristics, and the pore fractal dimension characteristics between shale lithofacies at different scales are different, reflecting the extremely strong heterogeneous characteristics. Among them, the micropore fractal dimension D1 and mesopore fractal dimension D2 of siliceous shale are the largest, developing a more complex micropore and mesopore pore structure network, which can provide a large number of gas adsorption sites and storage space. In contrast, silicon-rich argillaceous shale has the largest macropore fractal dimension D3, indicating that the macropore pore structure is relatively more complex, which can provide more pore space and facilitate the storage of free shale gas.

       

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