二氧化锰改性粉煤灰制备及其对地下水中砷的吸附特性

王丽楠; 杨保国; 谢作明; 赵欣鑫; 石天池

doi:10.3799/dqkx.2022.198

Volume 49 Issue 3

Mar. 2024

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Article Navigation > Earth Science > 2024 > 49(3): 1005-1016

Wang Linan, Yang Baoguo, Xie Zuoming, Zhao Xinxin, Shi Tianchi, 2024. Preparation of Fly Ash Modified with Manganese Dioxide to Enhance As(Ⅲ) and As(Ⅴ) Adsorption from Groundwater. Earth Science, 49(3): 1005-1016. doi: 10.3799/dqkx.2022.198

Citation:

Wang Linan, Yang Baoguo, Xie Zuoming, Zhao Xinxin, Shi Tianchi, 2024. Preparation of Fly Ash Modified with Manganese Dioxide to Enhance As(Ⅲ) and As(Ⅴ) Adsorption from Groundwater. Earth Science, 49(3): 1005-1016. doi: 10.3799/dqkx.2022.198

Citation:

Wang Linan, Yang Baoguo, Xie Zuoming, Zhao Xinxin, Shi Tianchi, 2024. Preparation of Fly Ash Modified with Manganese Dioxide to Enhance As(Ⅲ) and As(Ⅴ) Adsorption from Groundwater. Earth Science, 49(3): 1005-1016. doi: 10.3799/dqkx.2022.198

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Preparation of Fly Ash Modified with Manganese Dioxide to Enhance As(Ⅲ) and As(Ⅴ) Adsorption from Groundwater

doi: 10.3799/dqkx.2022.198

Wang Linan^{1
,
,},
Yang Baoguo^{1, 2
,
,},
Xie Zuoming^{1, 3},
Zhao Xinxin¹,
Shi Tianchi²

1.
School of Environmental Studies, China University of Geosciences, Wuhan 430078, China
2.
Geophysical and Geochemical Survey Institute of the Ningxia Hui Autonomous Region, Yinchuan 750001, China
3.
State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Wuhan 430078, China

Received Date: 2022-04-04
Available Online: 2024-04-12
Publish Date: 2024-03-25

Abstract

Abstract

High arsenic groundwater is widely distributed in China, and it is of great significance to develop green and efficient arsenic removal materials for the sake of regional development and safety of drinking water for residents. In this study, the fly ash modified with manganese dioxide (MFA150) was prepared using co-precipitation method combined with NaOH hydrothermal process, to investigate its adsorption of As(Ⅲ) and As(Ⅴ) in groundwater. The results show that the vitreous structure of the raw fly ash was destroyed to generate zeolite phase in NaOH hydrothermal process, and the specific surface area of fly ash increased from 1.30 m²/g to 40.26 m²/g. After loading MnO₂, the specific surface area of the adsorbent further increased to 148.82 m²/g, and the content of -OH on the surface was significantly increased to provide more adsorption sites for As(Ⅲ) and As(Ⅴ). The adsorption of As(Ⅲ) and As(Ⅴ) was in accordance with the Elovich model and the Freundlich model. The adsorption capacities of MFA150 for As(Ⅴ) and As(Ⅲ) under neutral condition were 2.55 mg/g and 9.71 mg/g, respectively, and showed stronger adsorption ability under acidic condition. Coexisting HCO₃^‒ and PO₄^3‒ inhibited the adsorption of As(Ⅲ) and As(Ⅴ), while SO₄^2‒ slightly promoted the removal of As(Ⅲ) and As(Ⅴ). In simulated groundwater, the removal rate of total As reached 91.90% by MFA150. Since preparation of MFA150 is simple and the raw material is cheap and easy to obtain, MFA150 is expected to be used in the treatment of the high arsenic groundwater owing to the better adsorption performance for As(Ⅴ) and As(Ⅲ).
- high arsenic,
- groundwater,
- fly ash,
- manganese oxide,
- adsorption,
- resource utilization,
- environmental geology

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References(42)

References

Algoufi, Y. T., Hameed, B. H., 2014. Synthesis of Glycerol Carbonate by Transesterification of Glycerol with Dimethyl Carbonate over K⁃Zeolite Derived from Coal Fly Ash. Fuel Processing Technology, 126: 5-11. https://doi.org/10.1016/j.fuproc.2014.04.004

Asl, S. M. H., Javadian, H., Khavarpour, M., et al., 2019. Porous Adsorbents Derived from Coal Fly Ash as Cost⁃Effective and Environmentally⁃Friendly Sources of Aluminosilicate for Sequestration of Aqueous and Gaseous Pollutants: A Review. Journal of Cleaner Production, 208: 1131-1147. https://doi.org/10.1016/j.jclepro.2018.10.186

Cuong, D. V., Wu, P. C., Chen, L. I., et al., 2021. Active MnO₂/Biochar Composite for Efficient As(Ⅲ) Removal: Insight into the Mechanisms of Redox Transformation and Adsorption. Water Research, 188: 116495. https://doi.org/10.1016/j.watres.2020.116495

Deschamps, E., Ciminelli, V. S. T., Höll, W. H., 2005. Removal of As(Ⅲ) and As(Ⅴ) from Water Using a Natural Fe and Mn Enriched Sample. Water Research, 39(20): 5212-5220. https://doi.org/10.1016/j.watres.2005.10.007

Fendorf, S., Michael, H. A., van Geen, A., 2010. Spatial and Temporal Variations of Groundwater Arsenic in South and Southeast Asia. Science, 328(5982): 1123-1127. https://doi.org/10.1126/science.1172974

Feng, W. L., Lü, X. B., Xiong, J., et al., 2021. Research Progress of High Added Value Utilization of Coal Fly Ash. Inorganic Chemicals Industry, 53(4): 25-31 (in Chinese with English abstract).

Ferguson, J. F., Gavis, J., 1972. A Review of the Arsenic Cycle in Natural Waters. Water Research, 6(11): 1259-1274. https://doi.org/10.1016/0043⁃1354(72)90052⁃8

Gollakota, A. R. K., Volli, V., Shu, C. M., 2019. Progressive Utilisation Prospects of Coal Fly Ash: A Review. Science of the Total Environment, 672: 951-989. https://doi.org/10.1016/j.scitotenv.2019.03.337

Ho, Y. S., 2006. Review of Second⁃Order Models for Adsorption Systems. Journal of Hazardous Materials, 136(3): 681-689. https://doi.org/10.1016/j.jhazmat.2005.12.043

Huang, X. R., Zhao, H. H., Hu, X. F., et al., 2020a. Optimization of Preparation Technology for Modified Coal Fly Ash and Its Adsorption Properties for Cd²⁺. Journal of Hazardous Materials, 392: 122461. https://doi.org/10.1016/j.jhazmat.2020.122461

Huang, X. R., Zhao, H. H., Zhang, G. B., et al., 2020b. Potential of Removing Cd(Ⅱ) and Pb(Ⅱ) from Contaminated Water Using a Newly Modified Fly Ash. Chemosphere, 242: 125148. https://doi.org/10.1016/j.chemosphere.2019.125148

Jiang, L., 2020. Comprehensiveutilization Situation of Fly Ash in Coal⁃Fired Power Plants and Its Development Suggestions. Clean Coal Technology, 26(4): 31-39 (in Chinese with English abstract).

Jiang, L., Chen, J. Y., Li, X. M., et al., 2011. Adsorption of Phosphate from Wastewater by Fly Ash Ceramsite. Acta Scientiae Circumstantiae, 31(7): 1413-1420 (in Chinese with English abstract).

Karanac, M., Đolić, M., Veljović, Đ., et al., 2018. The Removal of Zn²⁺, Pb²⁺, and As(Ⅴ) Ions by Lime Activated Fly Ash and Valorization of the Exhausted Adsorbent. Waste Management, 78: 366-378. https://doi.org/10.1016/j.wasman.2018.05.052

Liang, J., Li, X. M., Yu, Z. G., et al., 2017. Amorphous MnO₂ Modified Biochar Derived from Aerobically Composted Swine Manure for Adsorption of Pb(Ⅱ) and Cd(Ⅱ). ACS Sustainable Chemistry & Engineering, 5(6): 5049-5058. https://doi.org/10.1021/acssuschemeng.7b00434

Lou, Z. M., Cao, Z., Xu, J., et al., 2017. Enhanced Removal of As(Ⅲ)/(Ⅴ) from Water by Simultaneously Supported and Stabilized Fe⁃Mn Binary Oxide Nanohybrids. Chemical Engineering Journal, 322: 710-721. https://doi.org/10.1016/j.cej.2017.04.079

Manning, B. A., Fendorf, S. E., Bostick, B., et al., 2002. Arsenic(Ⅲ) Oxidation and Arsenic(Ⅴ) Adsorption Reactions on Synthetic Birnessite. Environmental Science & Technology, 36(5): 976-981. https://doi.org/10.1021/es0110170

Min, X. Z., Han, C. Y., Yang, L., et al., 2021. Enhancing As(Ⅴ) and As(Ⅲ) Adsorption Performance of Low Alumina Fly Ash with Ferric Citrate Modification: Role of FeSiO₃ and Monosodium Citrate. Journal of Environmental Management, 287: 112302. https://doi.org/10.1016/j.jenvman.2021.112302

Pengthamkeerati, P., Satapanajaru, T., Chatsatapattayakul, N., et al., 2010. Alkaline Treatment of Biomass Fly Ash for Reactive Dye Removal from Aqueous Solution. Desalination, 261(1-2): 34-40. https://doi.org/10.1016/j.desal.2010.05.050

Qiu, R. F., Cheng, F. Q., Huang, H. M., 2018. Removal of Cd²⁺ from Aqueous Solution Using Hydrothermally Modified Circulating Fluidized Bed Fly Ash Resulting from Coal Gangue Power Plant. Journal of Cleaner Production, 172: 1918-1927. https://doi.org/10.1016/j.jclepro.2017.11.236

Rathi, B. S., Kumar, P. S., 2021. A Review on Sources, Identification and Treatment Strategies for the Removal of Toxic Arsenic from Water System. Journal of Hazardous Materials, 418: 126299. https://doi.org/10.1016/j.jhazmat.2021.126299

Rubinos, D. A., Iglesias, L., Díaz⁃Fierros, F., et al., 2011. Interacting Effect of pH, Phosphate and Time on the Release of Arsenic from Polluted River Sediments (Anllóns River, Spain). Aquatic Geochemistry, 17(3): 281-306. https://doi.org/10.1007/s10498⁃011⁃9135⁃2

Sağ, Y., Aktay, Y., 2002. Kinetic Studies on Sorption of Cr(Ⅵ) and Cu(Ⅱ) Ions by Chitin, Chitosan and Rhizopus Arrhizus. Biochemical Engineering Journal, 12(2): 143-153. https://doi.org/10.1016/S1369⁃703X(02)00068⁃2

Salam, M. A., Al⁃Zhrani, G., Kosa, S. A., 2014. Removal of Heavy Metal Ions from Aqueous Solution by Multi⁃Walled Carbon Nanotubes Modified with 8⁃Hydroxyquinoline: Kinetic Study. Journal of Industrial and Engineering Chemistry, 20(2): 572-580. https://doi.org/10.1016/j.jiec.2013.05.016

Shen, Q. B., Wang, Z. Y., Yu, Q., et al., 2020. Removal of Tetracycline from an Aqueous Solution Using Manganese Dioxide Modified Biochar Derived from Chinese Herbal Medicine Residues. Environmental Research, 183: 109195. https://doi.org/10.1016/j.envres.2020.109195

Shen, Z. L., Guo, H. M., Xu, G., et al., 2010. Abnormal Groundwater Chemistry and Endemic Disease. Chinese Journal of Nature, 32(2): 83-89 (in Chinese with English abstract).

Su, Y., Cui, H., Li, Q., et al., 2013. Strong Adsorption of Phosphate by Amorphous Zirconium Oxide Nanoparticles. Water Research, 47(14): 5018-5026. https://doi.org/10.1016/j.watres.2013.05.044

Teng, H., Hsieh, C. T., 1999. Activation Energy for Oxygen Chemisorption on Carbon at Low Temperatures. Industrial & Engineering Chemistry Research, 38(1): 292-297. https://doi.org/10.1021/ie980107j

Tiwari, M. K., Bajpai, S., Dewangan, U. K., et al., 2015. Suitability of Leaching Test Methods for Fly Ash and Slag: A Review. Journal of Radiation Research and Applied Sciences, 8(4): 523-537. https://doi.org/10.1016/j.jrras.2015.06.003

Tournassat, C., Charlet, L., Bosbach, D., et al., 2002. Arsenic(Ⅲ) Oxidation by Birnessite and Precipitation of Manganese(Ⅱ) Arsenate. Environmental Science & Technology, 36(3): 493-500. https://doi.org/10.1021/es0109500

Wang, Y. L., Liu, H. P., Wang, S. F., et al., 2020. Simultaneous Removal and Oxidation of Arsenic from Water by δ⁃MnO₂ Modified Activated Carbon. Journal of Environmental Sciences, 94: 147-160. https://doi.org/10.1016/j.jes.2020.03.006

Wu, D. Y., Sui, Y. M., Chen, X. C., et al., 2008. Changes of Mineralogical⁃Chemical Composition, Cation Exchange Capacity, and Phosphate Immobilization Capacity during the Hydrothermal Conversion Process of Coal Fly Ash into Zeolite. Fuel, 87(10-11): 2194-2200. https://doi.org/10.1016/j.fuel.2007.10.028

Wu, K., Wang, M., Li, A. Z., et al., 2021. The Enhanced As(Ⅲ) Removal by Fe⁃Mn⁃Cu Ternary Oxide via Synergistic Oxidation: Performances and Mechanisms. Chemical Engineering Journal, 406: 126739. https://doi.org/10.1016/j.cej.2020.126739

Xie, X. J., Lu, C., Xu, R., et al., 2022. Arsenic Removal by Manganese⁃Doped Mesoporous Iron Oxides from Groundwater: Performance and Mechanism. Science of the Total Environment, 806: 150615. https://doi.org/10.1016/j.scitotenv.2021.150615

Xiyili, H., Çetintaş, S., Bingöl, D., 2017. Removal of Some Heavy Metals onto Mechanically Activated Fly Ash: Modeling Approach for Optimization, Isotherms, Kinetics and Thermodynamics. Process Safety and Environmental Protection, 109: 288-300. https://doi.org/10.1016/j.psep.2017.04.012

Zhang, G. S., Qu, J. H., Liu, H. J., et al., 2007. Removal Mechanism of As(Ⅲ) by a Novel Fe⁃Mn Binary Oxide Adsorbent: Oxidation and Sorption. Environmental Science & Technology, 41(13): 4613-4619. https://doi.org/10.1021/es063010u

Zhang, K. H., Zhang, D. X., Zhang, K., 2016. Arsenic Removal from Water Using a Novel Amorphous Adsorbent Developed from Coal Fly Ash. Water Science and Technology: A Journal of the International Association on Water Pollution Research, 73(8): 1954-1962. https://doi.org/10.2166/wst.2016.028

Zhao, X., Zhao, H. H., Huang, X. R., et al., 2021. Effect and Mechanisms of Synthesis Conditions on the Cadmium Adsorption Capacity of Modified Fly Ash. Ecotoxicology and Environmental Safety, 223: 112550. https://doi.org/10.1016/j.ecoenv.2021.112550

冯文丽, 吕学斌, 熊健, 等, 2021. 粉煤灰高附加值利用研究进展. 无机盐工业, 53(4): 25-31. https://www.cnki.com.cn/Article/CJFDTOTAL-WJYG202104005.htm

姜龙, 2020. 燃煤电厂粉煤灰综合利用现状及发展建议. 洁净煤技术, 26(4): 31-39. https://www.cnki.com.cn/Article/CJFDTOTAL-JJMS202004004.htm

蒋丽, 谌建宇, 李小明, 等, 2011. 粉煤灰陶粒对废水中磷酸盐的吸附试验研究. 环境科学学报, 31(7): 1413-1420. https://www.cnki.com.cn/Article/CJFDTOTAL-HJXX201107011.htm

沈照理, 郭华明, 徐刚, 等, 2010. 地下水化学异常与地方病. 自然杂志, 32(2): 83-89. https://www.cnki.com.cn/Article/CJFDTOTAL-ZRZZ201002006.htm

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Preparation of Fly Ash Modified with Manganese Dioxide to Enhance As(Ⅲ) and As(Ⅴ) Adsorption from Groundwater

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