地下水排泄河水过程中溶解态铁砷的协同迁移转化机制

邓茜予; 刘慧; 黄瑶

doi:10.3799/dqkx.2023.022

Volume 49 Issue 7

Jul. 2024

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Article Navigation > Earth Science > 2024 > 49(7): 2627-2636

Deng Xiyu, Liu Hui, Huang Yao, 2024. Co-Migration and Transformation Mechanism of Dissolved Iron and Arsenic during Groundwater Discharge into River Water. Earth Science, 49(7): 2627-2636. doi: 10.3799/dqkx.2023.022

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Deng Xiyu, Liu Hui, Huang Yao, 2024. Co-Migration and Transformation Mechanism of Dissolved Iron and Arsenic during Groundwater Discharge into River Water. Earth Science, 49(7): 2627-2636. doi: 10.3799/dqkx.2023.022

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Co-Migration and Transformation Mechanism of Dissolved Iron and Arsenic during Groundwater Discharge into River Water

doi: 10.3799/dqkx.2023.022

Deng Xiyu^{1
,
,},
Liu Hui^{1, 2
,
,},
Huang Yao¹

1.
School of Environmental Studies, China University of Geosciences, Wuhan 430078, China
2.
State Key Laboratory of Biogeology and Environmental Geology, Wuhan 430078, China

Received Date: 2022-11-01
Available Online: 2024-08-03
Publish Date: 2024-07-25

Abstract

Abstract

During groundwater discharge into the river, Fe²⁺ and As³⁺ in anoxic groundwater are brought into the oxygen-containing interaction zone. This study explores the co-migration and transformation mechanism of Fe²⁺ and As³⁺with groundwater in the natural sediment medium.The migration and transformation rules of Fe²⁺ and As³⁺during groundwater discharge into river water and the transformation rate of Fe²⁺ and As³⁺ to solid phase (solidification) in different regions of the interaction zone are studied by laboratory column experiment and batch experiment.The results show that the sediment strongly adsorbs Fe²⁺ and As³⁺, and As³⁺ accelerates the migration of Fe²⁺. The chemical oxidation and precipitation of Fe²⁺ occur, and Fe-As bounding minerals are formed when it flows through the interaction zone.The solidification rate of Fe²⁺ and As³⁺ is accelerated from the area far from the river to that near the river. In the whole interaction zone, Fe²⁺ significantly promotes the solidification of As³⁺, while As³⁺ slightly inhibits the solidification of Fe²⁺ near the river bank.In short, during groundwater discharge into river water, the synergistic chemical oxidation and adsorption fixation of Fe²⁺ and As³⁺in groundwater occur at different rates in different regions of the interaction zone, which seriously hinders their migration to river water.
- groundwater discharge,
- interaction zone,
- iron,
- arsenic,
- migration,
- hydrogeology

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References

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