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    Volume 49 Issue 12
    Dec.  2024
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    Article Navigation >  Earth Science  > 2024  >  49(12): 4335-4350
    Xiao Changhao, Wei Changshan, Zhang Yu, Chen Zhengle, Le Xingwen, Yu Shuqing, 2024. Calcite U-Pb Dating and Micro-XRF Analysis Constraint on Formation of Bawang Zn-Fe-Sn Deposit in Danchi Metallogenic Belt, South China. Earth Science, 49(12): 4335-4350. doi: 10.3799/dqkx.2023.191
    Citation: Xiao Changhao, Wei Changshan, Zhang Yu, Chen Zhengle, Le Xingwen, Yu Shuqing, 2024. Calcite U-Pb Dating and Micro-XRF Analysis Constraint on Formation of Bawang Zn-Fe-Sn Deposit in Danchi Metallogenic Belt, South China. Earth Science, 49(12): 4335-4350. doi: 10.3799/dqkx.2023.191
    shu

    Calcite U-Pb Dating and Micro-XRF Analysis Constraint on Formation of Bawang Zn-Fe-Sn Deposit in Danchi Metallogenic Belt, South China

    doi: 10.3799/dqkx.2023.191
    • 1.

      Laboratory of Dynamic Diagenesis and Metallogenesis, Institute of Geomechanics, Chinese Academy of Geological Sciences, Beijing 100081, China

    • 2.

      Key Laboratory of Paleomagnetism and Tectonic Reconstruction, Ministry of Natural Resources, Beijing 100081, China

    • 3.

      Laboratory of Deep Earth Sciences and Technology of Ministry of National Resources, Beijing 100094, China

    • 4.

      School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China

    • 5.

      No.4 Geology Team of Guangxi Zhuang Autonomic Region, Nanning 530033, China

    • 6.

      Mineral Resources Reserve Evaluation Center of Guangxi Autonomous Region, Nanning 530029, China

    • Received Date: 2023-06-15
      Available Online: 2025-01-09
    • Publish Date: 2024-12-25
      Abstract
    • Danchi metallogenic belt is one of the most important nonferrous metal industry bases. It is to be the research focus owing to the large scale of Sn and Sb metal budget. The genesis of Sn-polymetallic mineralization during the Late Cretaceous and the relationship between Zn-Sn and Sb mineralization in the belt remain unclear. The Bawang deposit, a recently discovered paleokarst infilled type deposit, occurs in the west limb of the Wuxu anticline. Basing on the earlier study of structural analysis, mineralogy, and cassiterite U-Pb ages, in this study it presents element mapping of ores by micro-XRF (μ-XRF) analysis, and in situ U-Pb laser ablation-magnetic sectorfield-inductively coupled plasma mass spectrometer (LA-SF-ICP-MS) ages of calcite during the antimony mineralization stage. Micro-XRF analysis revealed that the sphalerite, cassiterite-quartz, and arsenopyrite mineralization have taken place in order in the Bawang deposit. Calcite U-Pb dating provides a lower intercept ages of 62.8±1.1 Ma (MSWD = 2.6; 2σ). Combined with previous ages of Zn-Sn mineralization, mineralogy, and μ-XRF analysis, the Zn-Sn mineralization is 30 Ma earlier than Sb mineralization. The pressure contrast existed between the fluid pressure at the site of ore deposition and the fluid pressure within the concealed intrusion is the key dynamics of fluid flow for the tin mineralization.

       

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