福州寿山石矿床的流体包裹体和H-O同位素特征及其矿床成因意义

朱律运; 孟桅; 杨仲; 许文; 李玉娟; 詹旭焘; 陈润生

doi:10.3799/dqkx.2024.044

Volume 50 Issue 7

Jul. 2025

Turn off MathJax

Article Contents

Article Navigation > Earth Science > 2025 > 50(7): 2707-2719

Zhu Lyuyun, Meng Wei, Yang Zhong, Xu Wen, Li Yujuan, Zhan Xutao, Chen Runsheng, 2025. Fluid Inclusions and H-O Isotopic Characterization of Shoushan Stone Deposits in Fuzhou and Its Significance for Genesis of Deposits. Earth Science, 50(7): 2707-2719. doi: 10.3799/dqkx.2024.044

Citation:

Zhu Lyuyun, Meng Wei, Yang Zhong, Xu Wen, Li Yujuan, Zhan Xutao, Chen Runsheng, 2025. Fluid Inclusions and H-O Isotopic Characterization of Shoushan Stone Deposits in Fuzhou and Its Significance for Genesis of Deposits. Earth Science, 50(7): 2707-2719. doi: 10.3799/dqkx.2024.044

Citation:

Zhu Lyuyun, Meng Wei, Yang Zhong, Xu Wen, Li Yujuan, Zhan Xutao, Chen Runsheng, 2025. Fluid Inclusions and H-O Isotopic Characterization of Shoushan Stone Deposits in Fuzhou and Its Significance for Genesis of Deposits. Earth Science, 50(7): 2707-2719. doi: 10.3799/dqkx.2024.044

PDF( 12325 KB)

Fluid Inclusions and H-O Isotopic Characterization of Shoushan Stone Deposits in Fuzhou and Its Significance for Genesis of Deposits

doi: 10.3799/dqkx.2024.044

1.
Zijin School of Geology and Mining, Fuzhou University, Fuzhou 350108, China
2.
Fujian Institute of Geological Survey, Fuzhou 350013, China

Received Date: 2024-01-08
Available Online: 2025-07-29
Publish Date: 2025-07-25

Abstract

Abstract

As one of the four most famous carving stones in China, Shoushan stone is mainly produced in the Fuzhou volcanic basin and formed by alteration between acidic volcanic rocks and hydrothermal fluids. The characteristics of ore-forming fluid are the key to understanding the mineralization and exploration model. The hydrothermal quartz from Shoushan stone deposit was sampled for the experiment of fluid inclusions and H-O isotopes. The thermodynamic tool is also adopted to quantify the conditions for the formation of Shoushan stone containing kaolinite group minerals. All fluid inclusions in quartz consist of volatile-liquid phases. The homogenization temperatures are 197 ℃ and 211 ℃ for samples from Liuping sample, and 245 ℃ for that from Gaoshan. The δ¹⁸O_V-SMOW values of quartz are 8.3‰ and 8.4‰, and the δD_V-SMOW values of quartz are -61‰ and -83‰. Combined with the H-O isotope results of kaolinite from previous research, the H-O isotope of fluid is calculated theoretically under different temperatures (150 ℃, 200 ℃ and 250 ℃), which demonstrates that the ore-forming fluid is a mixture of magmatic and meteoric water. By the addition of meteoric water, the temperature, salinity and pH of magmatic-hydrothermal fluids, hydrothermal fluids are made more suitable for the formation of clay minerals. Then, the long-term water-rock reaction leads to the sufficient alternation of acidic volcanic rocks, forming a variety of Shoushan stones. This study improves the mineralization model of Shoushan stone and provides insights into the exploration of metallic and non-metallic deposits caused by epithermal hydrothermal alteration.
- Shoushan stone,
- fluid inclusion,
- H-O isotope,
- fluid source,
- mineralization condition,
- ore deposit

FullText(HTML)

References(58)

References

Al Ani, T., Sarapää, O., 2008. Clay and Clay Mineralogy. Report of Geographical Area GTK Espoo. Geological Survey of Finland, Espoo.

Bodnar, R. J., 1993. Revised Equation and Table for Determining the Freezing Point Depression of H₂O-Nacl Solutions. Geochimica et Cosmochimica Acta, 57(3): 683-684. https://doi.org/10.1016/0016-7037(93)90378-A

Chao, W. W., Xu, D. R., Li, Z. H., et al., 2024. Characteristics and Geological Implications of Mineral Chemistry and Fluid Inclusions in Huxu Au-Pb-Zn Ore Deposit, Jiangxi Province. Earth Science, 49(4): 1292-1306 (in Chinese with English abstract).

Chen, H. N., Wu, Q. H., He, J. R., et al., 1988. Basic Characteristics of Mesozoic Volcanic Genesis Non- Metallic Mineral Deposits in Zhejiang, Fujian, and Jiangxi Regions. Geological Publishing House, Beijing, 488 (in Chinese).

Chen, R. B., Wei, X., 2017. Geological Conditions of Shoushan Stone Mineralization and Prediction of Prospective Target Areas. Academic Symposium on the Geological Genesis and Characteristics of Beryl Stones in Shoushan Stone, Fujian Province. Geological Society of Fujian, Fuzhou (in Chinese).

Chen, R. S., Li, Y. J., 2017. The Study of Geological Conditions and Genesis of Shoushan Stone Mineralization: Issues and Challenges. Academic Symposium on the Geological Genesis and Characteristics of Beryl Stones in Shoushan Stone, Fujian Province. Geological Society of Fujian, Fuzhou (in Chinese).

Chen, T., Tang, L. L., Lu, W., et al., 2008. Study on Colour Causing of Peach Blossom Stone from Gao Mountain, Shoushan County, Fujian Province. Journal of Gems & Gemmology, 10(3): 1-3 (in Chinese with English abstract).

Dong, J. K., 2008. Mineralogical Study and Genetic Analysis of the Shoushan Stone Deposit in Fujian (Dissertation). China University of Geosciences, Beijing (in Chinese with English abstract).

Gan, Y. X., 2001. The Mineralogy, Geochemistry, and Genesis of Shoushan Stone Deposits (Dissertation). Peking University, Beijing (in Chinese with English abstract).

Gao, T. J., Zhang, Z. L., Liu, Z. X., 1997. The Minerogenic Conditions and Prospects for Mineral Exploration of the Shoushan Stone (Agalmatolite) in Fujian Province. Geology of Fujian, 16(3): 110-131 (in Chinese with English abstract).

Hedenquist, J. W., Arribas, A., 2022. Exploration Implications of Multiple Formation Environments of Advanced Argillic Minerals. Economic Geology, 117(3): 609-643. https://doi.org/10.5382/econgeo.4880

Johnson, J. W., Oelkers, E. H., Helgeson, H. C., 1992. SUPCRT92: A Software Package for Calculating the Standard Molal Thermodynamic Properties of Minerals, Gases, Aqueous Species, and Reactions from 1 to 5 000 Bar and 0 to 1 000 ℃. Computers & Geosciences, 18(7): 899-947. https://doi.org/10.1016/0098-3004(92)90029-Q

Li, Y. J., 2005. On the Mineral Constituent and Characteristics of Shoushan Stone. Geology of Fujian, 24(2): 79-89 (in Chinese with English abstract).

Li, Y. J., 2018. Comparison for Metallogenic Geological Condition of Four Type Chinese Stamp Stones. Geology of Fujian, 37(1): 1-12 (in Chinese with English abstract).

Li, Y. J., Chen, R. S., Yang, Z., et al., 2022. Alunite ⁴⁰Ar/³⁹Ar Dating of Gaoshan Deposit, Fujian Province and Its Limitation of the Mineralization Age of Shoushan Stone. Journal of Gems & Gemmology, 24(5): 44-54 (in Chinese with English abstract).

Li, Y. J., Zhu, L. Y., Xu, W., et al., 2022. Stratigraphic Section and Geochronological Studies of the Shoushan Basin, Fujian Province, South China, and Its Implications for the Mineralization of Shoushan Stone. Minerals, 12(12): 1542. https://doi.org/10.3390/min12121542

Lin, M., 2011. New Progress on the Study of Stratum Sequence, Rock Association and Epoch of the Xiaoxi Formation in Fujian Province. Geology and Exploration, 47(4): 555-565 (in Chinese with English abstract).

Lin, M., 2017. Study on the Characteristics of Volcanism of Volcanic Eruptive Basins and the Relation to Pyrophyllite Ore in Shoushan Area, Fujian Province. Geology of Fujian, 36(4): 251-261 (in Chinese with English abstract).

Liu, B., Duan, G. X., 1987. The Density and Isochoric Formulae for NaCl-H₂O Fluid Inclusions (Salinity≤ 25 wt%) and Their Applications. Acta Mineralogica Sinica, 7(4): 345-352 (in Chinese with English abstract).

Pan, J. Y., Ni, P., Chi, Z., et al., 2019. Alunite ⁴⁰Ar/³⁹Ar and Zircon U-Pb Constraints on the Magmatic- Hydrothermal History of the Zijinshan High-Sulfidation Epithermal Cu-Au Deposit and the Adjacent Luoboling Porphyry Cu-Mo Deposit, South China: Implications for Their Genetic Association. Economic Geology, 114(4): 667-695. https://doi.org/10.5382/econgeo.4658

Simmons, S. F., Browne, P. R. L., 2000. Hydrothermal Minerals and Precious Metals in the Broadlands-Ohaaki Geothermal System: Implications for Understanding Low-Sulfidation Epithermal Environments. Economic Geology, 95(5): 971-999. https://doi.org/10.2113/gsecongeo.95.5.971

Tang, D. P., Wu, L. W., Zheng, Z. T., et al., 2012. An Explanation for the Provincial Standard of Larderite. Journal of Gems & Gemmology, 14(3): 48-52 (in Chinese with English abstract).

Tang, D. P., Zheng, Z. T., 1999. Mineralogy and Gemmology of Shoushan Stone. Journal of Gems & Gemmology, 1(4): 28-36 (in Chinese with English abstract).

Taylor, H. P., 1997. Oxygen and Hydrogen Isotope Relationships in Hydrothermal Mineral Deposits. In: Barnes, H. L., ed., Geochemistry of Hydrothermal Deposits. John Wiley and Sons, New York.

Wu, X. F., Cui, W. Y., 1999. A Mineralogical and Petrographical Study of Shoushan Stone (Agalmatolite). Acta Petrrologica et Mineralogica, 18(2): 186-192 (in Chinese with English abstract).

Xiao, F., Fan, F. P., Xing, G. F., et al., 2022. Late Jurassic Epithermal Mineralization of Shitouban Au Deposit, Dehua-Youxi Area, Southeast China: Quartz Rb Sr Dating, Fluid Inclusions, and H-O-S-Pb-Sr Isotope Analyses. Journal of Geochemical Exploration, 236: 106964. https://doi.org/10.1016/j.gexplo.2022.106964

Xu, B. T., 1991. Hydrogen and Oxygen Isotopic Compositions of Dickite Clay and Their Forming Condition in Zhejiang Province. Bulletin of Science and Technology, 7(6): 306-309 (in Chinese with English abstract).

Yang, X. Z., Huang, G. Z., Li, P. Y., et al., 1993. Polytypes and Transformation of Pyrophyllite from the Shoushan Pyrophyllite Deposit. Geology of Fujian, 12(3): 172-181 (in Chinese with English abstract).

Ye, K. K., 2019. Distribution and Types of Pyrophyllite Deposits in Fujian Province. Metallurgy and Materials, 11(6): 181, 183 (in Chinese with English abstract).

Ye, Z. F., Ye, F., Miao, R. G., et al., 2022. Ore Genesis of Pyrophyllite Deposit in Zhejiang-Fujian Area. Mineral Deposits, 41(6): 1258-1273 (in Chinese with English abstract).

Yu, M. G., Hong, W. T., Yang, Z. L., et al., 2021. Classification of Yanshanian Volcanic Cycle and the Related Mineralization in the Coast Area of Southeastern China. Geological Bulletin of China, 40(6): 845-863 (in Chinese with English abstract).

Zhang, S. Y., Zhang, H. F., 2020. Genesis of the Baiyun Pyrophyllite Deposit in the Central Taihang Mountain, China: Implications for Gold Mineralization in Wall Rocks. Ore Geology Reviews, 120: 103313. https://doi.org/10.1016/j.oregeorev.2020.103313

Zheng, Y., 2022. Large-Scaled Structure-Alteration-Mineralization Mapping of the Hydrothermal Deposits: Basic Principle and Precautions. Earth Science, 47(10): 3603-3615 (in Chinese with English abstract).

Zhou, X. M., Li, W. X., 2000. Origin of Late Mesozoic Igneous Rocks in Southeastern China: Implications for Lithosphere Subduction and Underplating of Mafic Magmas. Tectonophysics, 326(3-4): 269-287. https://doi.org/10.1016/S0040-1951(00)00120-7

Zhu, L. Y., Jiang, S. Y., Chen, R. S., et al., 2019. Origin of the Shangfang Tungsten Deposit in the Fujian Province of Southeast China: Evidence from Scheelite Sm-Nd Geochronology, H-O Isotopes and Fluid Inclusions Studies. Minerals, 9(11): 713. https://doi.org/10.3390/min9110713

抄尉尉, 许德如, 李增华, 等, 2024. 江西虎圩金铅锌矿床矿物化学、流体包裹体特征及地质意义. 地球科学, 49(4): 1292-1306. doi: 10.3799/dqkx.2022.305

陈鹤年, 巫全淮, 贺菊瑞, 等, 1988. 浙闽赣地区中生代火山成因非金属矿床基本特征. 北京: 地质出版社, 488.

陈仁表, 魏鑫. 2017. 寿山石成矿地质条件及找矿靶区预测. 福建省寿山石地质成因及宝玉石特性学术研讨会. 福建省地质学会, 福州.

陈润生, 李玉娟. 2017. 寿山石成矿地质条件及成因研究: 问题与难点. 福建省寿山石地质成因及宝玉石特性学术研讨会. 福建省地质学会, 福州.

陈涛, 唐亮亮, 鲁纬, 等, 2008. 福建寿山高山桃花石的颜色成因研究. 宝石和宝石学杂志, 10(3): 1-3.

董晋琨, 2008. 福建寿山石矿床的矿物学研究和成因分析(硕士学位论文). 北京: 中国地质大学.

甘怡绚. 2001. 寿山石矿床矿物学、地球化学及其成因(博士学位论文). 北京: 北京大学.

高天钧, 张智亮, 刘志逊, 1997. 寿山石成矿地质条件及找矿前景. 福建地质, 16(3): 110-131.

李玉娟, 2005. 寿山石的矿物组分和特征. 福建地质, 24(2): 79-89.

李玉娟, 2018. 我国四大图章石成矿地质条件比较研究. 福建地质, 37(1): 1-12.

李玉娟, 陈润生, 杨仲, 等, 2022. 福建高山矿区明矾石⁴⁰Ar/³⁹Ar定年及其对寿山石成矿时代的限定. 宝石和宝石学杂志(中英文), 24(5): 44-54.

林敏, 2011. 福建小溪组地层层序、岩石组合及时代研究新进展. 地质与勘探, 47(4): 555-565.

林敏, 2017. 福建寿山火山喷发盆地火山作用特征及与叶蜡石成矿关系探讨. 福建地质, 36(4): 251-261.

刘斌, 段光贤, 1987. NaCl-H₂O溶液包裹体的密度式和等容式及其应用. 矿物学报, 7(4): 345-352.

汤德平, 吴立旺, 郑宗坦, 等, 2012. 寿山石新地方标准解析. 宝石和宝石学杂志, 14(3): 48-52.

汤德平, 郑宗坦, 1999. 寿山石的矿物组成与宝石学研究. 宝石和宝石学杂志, 1(4): 28-36.

武新逢, 崔文元, 1999. 寿山石的矿物学研究. 岩石矿物学杂志, 18(2): 186-192.

徐步台, 1991. 浙江地开石粘土的氢、氧同位素组成及其形成条件. 科技通报, 7(6): 306-309.

杨献忠, 黄光昭, 李佩玉, 等, 1993. 寿山叶蜡石矿床中叶蜡石的多型及其转变. 福建地质, 12(3): 172-181.

叶孔凯, 2019. 福建省叶蜡石矿床分布及其类型. 冶金与材料, 11(6): 181, 183.

叶泽富, 叶帆, 缪仁谷, 等, 2022. 浙闽地区叶蜡石矿床成矿规律研究. 矿床地质, 41(6): 1258-1273.

余明刚, 洪文涛, 杨祝良, 等, 2021. 东南沿海燕山期火山活动旋回划分及其成矿规律. 地质通报, 40(6): 845-863.

郑义, 2022. 热液矿床超大比例尺构造‒蚀变‒矿化填图: 基本原理与注意事项. 地球科学, 47(10): 3603-3615. doi: 10.3799/dqkx.2022.295

Relative Articles

Supplements(0)

Cited By

Proportional views

Proportional views

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Figures(9) / Tables(3)

Get Citation

PDF

XML

Article views (79) PDF downloads(14)

Fluid Inclusions and H-O Isotopic Characterization of Shoushan Stone Deposits in Fuzhou and Its Significance for Genesis of Deposits

doi: 10.3799/dqkx.2024.044

Abstract

References

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Proportional views

Export File

Citation

Format

Content