• 中国出版政府奖提名奖

    中国百强科技报刊

    湖北出版政府奖

    中国高校百佳科技期刊

    中国最美期刊

    Volume 50 Issue 4
    Apr.  2025
    Turn off MathJax
    Article Contents
    Deng Xingbin, Huang Shen, Ren Kun, Huang Nanrui, He Guang, Huang Huiji, Zeng Jie, Cheng Ruirui, Pan Xiaodong, 2025. Hydrochemical and Isotopic Characteristics of Water in Mamian Pyrite Mining Area and Their Environmental Indication Significance. Earth Science, 50(4): 1531-1544. doi: 10.3799/dqkx.2024.064
    Citation: Deng Xingbin, Huang Shen, Ren Kun, Huang Nanrui, He Guang, Huang Huiji, Zeng Jie, Cheng Ruirui, Pan Xiaodong, 2025. Hydrochemical and Isotopic Characteristics of Water in Mamian Pyrite Mining Area and Their Environmental Indication Significance. Earth Science, 50(4): 1531-1544. doi: 10.3799/dqkx.2024.064

    Hydrochemical and Isotopic Characteristics of Water in Mamian Pyrite Mining Area and Their Environmental Indication Significance

    doi: 10.3799/dqkx.2024.064
    • Received Date: 2024-01-06
      Available Online: 2025-05-10
    • Publish Date: 2025-04-25
    • Acid mine drainage (AMD) can contribute to deterioration of the receiving water quality, accelerate the dissolution of carbonate rocks, leading to the release of CO2, which poses a wide range of hazards. Combined with the hydrogeological setting, hydrochemical and isotopic methods are employed to investigate the sources and migration mechanisms of pollutants in surface and groundwater of the Mamian mining area in Guilin, China. Results show that: (1) the chemical composition of surface water and groundwater mainly came from the weathering of carbonate and silicate rock, as well as the oxidation of sulfide, and Ca-HCO3 was the main water type in the study area, while some sites affected by AMD and domestic sewage wastewater changed to Ca-HCO3·SO4 and Ca·(K+Na)-HCO3 types; (2) sulfur and oxygen isotopes indicate that sulfide, rainwater and sewage were the three main SO42- sources for sampled surface-ground waters; and (3) changes in hydrochemical and isotopic composition indicate that the influence of AMD on surface water and groundwater gradually decreased along the flow directions, affecting to approximately 13.5 km and 1.5 km downstream, respectively. This study not only revealed the negative impact of AMD and human activities on the waters, provided basic data for the protection of water resources for the studied mine area. At the same time, the combination of isotope and water chemistry is proved to be an effective means to study the migration and transformation of pollutants in mining area, which provides a new idea for the study of pollutants in other mining areas.

       

    • loading
    • Bottrell, S., Tellam, J., Bartlett, R., et al., 2008. Isotopic Composition of Sulfate as a Tracer of Natural and Anthropogenic Influences on Groundwater Geochemistry in an Urban Sandstone Aquifer, Birmingham, UK. Applied Geochemistry, 23(8): 2382-2394. https://doi.org/10.1016/j.apgeochem.2008.03.012
      Cao, H. L., Li, W., Su, C. L., et al., 2023. Indication of Hydrochemistry and δ34S-SO42- on Sulfate Pollution of Groundwater in Daye Mining Area. Earth Science, 48(9): 3432-3443(in Chinese with English abstract).
      Chen, H., Cui, Y. H., Wang, H. M., et al., 2024. Advances in Mines Ecological Restoration and Carbon Sequestration Potential. Earth Science, 49(12): 4594-4607(in Chinese with English abstract).
      Cidu, R., Dadea, C., Desogus, P., et al., 2012. Assessment of Environmental Hazards at Abandoned Mining Sites: A Case Study in Sardinia, Italy. Applied Geochemistry, 27(9): 1795-1806. https://doi.org/10.1016/j.apgeochem.2012.02.014
      Feng, J., Zhou, C. L., Yang, Q., et al., 2023. Performance and Mechanisms of PropS-SH/Ce(dbp)3 Coatings in the Inhibition of Pyrite Oxidationtion for Acid Mine Drainage Control. Environmental Pollution, 322: 121162. https://doi.org/10.1016/j.envpol.2023.121162
      Gaillardet, J., Dupré, B., Louvat, P., et al., 1999. Global Silicate Weathering and CO2 Consumption Rates Deduced from the Chemistry of Large Rivers. Chemical Geology, 159(1-4): 3-30. https://doi.org/10.1016/S0009-2541(99)00031-5
      Gammons, C. H., Brown, A., Poulson, S. R., et al., 2013. Using Stable Isotopes (S, O) of Sulfate to Track Local Contamination of the Madison Karst Aquifer, Montana, from Abandoned Coal Mine Drainage. Applied Geochemistry, 31: 228-238. https://doi.org/10.1016/j.apgeochem.2013.01.008
      Gammons, C. H., Duaime, T. E., Parker, S. R., et al., 2010. Geochemistry and Stable Isotope Investigation of Acid Mine Drainage Associated with Abandoned Coal Mines in Central Montana, USA. Chemical Geology, 269(1/2): 100-112. https://doi.org/10.1016/j.chemgeo.2009.05.026
      Gibbs, R. J., 1970. Mechanisms Controlling World Water Chemistry. Science, 170(3962): 1088-1090. https://doi.org/10.1126/science.170.3962.1088
      Guo, Y. S., Yu, S., Li, Y. S., et al., 2016. Chemical Characteristics and Source of Acid Precipitation in Guilin. Environmental Science, 37(8): 2897-2905(in Chinese with English abstract).
      Hakkou, R., Benzaazoua, M., Bussière, B., 2008. Acid Mine Drainage at the Abandoned Kettara Mine (Morocco): 1. Environmental Characterization. Mine Water and the Environment, 27(3): 145-159. https://doi.org/10.1007/s10230-008-0036-6
      Horibe, Y., Shigehara, K., Takakuwa, Y., 1973. Isotope Separation Factor of Carbon Dioxide-Water System and Isotopic Composition of Atmospheric Oxygen. Journal of Geophysical Research, 78(15): 2625-2629. https://doi.org/10.1029/JC078i015p02625
      Huang, Q. B., Zou, S. Z., Qin, X. Q., et al., 2023. Study on Characteristics and Regulation Technology of Water Resources of Karst Wetland in Huixian, Guilin. Carsologica Sinica, 42(4): 722-732, 762(in Chinese with English abstract).
      Jeong, C. H., 2001. Effect of Land Use and Urbanization on Hydrochemistry and Contamination of Groundwater from Taejon Area, Korea. Journal of Hydrology, 253(1-4): 194-210. https://doi.org/10.1016/S0022-1694(01)00481-4
      Jia, X. C., Zhou, J. W., Zhu, H. H., et al., 2020. Characteristics of Sulfur Isotope in Water Bodies near the Zhaoyuan Gold Mine Area and Its Indicative Function of Pollution Sources. Hydrogeology & Engineering Geology, 47(5): 179-188(in Chinese with English abstract).
      Jiao, Y. N., Zhang, C. H., Su, P. D., et al., 2023. A Review of Acid Mine Drainage: Formation Mechanism, Treatment Technology, Typical Engineering Cases and Resource Utilization. Process Safety and Environmental Protection, 170: 1240-1260. https://doi.org/10.1016/j.psep.2022.12.083
      Li, X. Q., Zhou A. G., Gan, Y. Q., et al., 2011. Controls on the δ34S and δ18O of Dissolved Sulfate in the Quaternary Aquifers of the North China Plain. Journal of Hydrology, 400(3/4): 312-322(in Chinese).
      Li, Y., Cao, M. D., Jin, M. G., et al., 2020. Hydrochemical Characteristics and Tracing of Nitrate Sources in Quanshui River Catchment, Hubei Province. Earth Science, 45(3): 1061-1070(in Chinese with English abstract).
      Li, Y. Y., Luo, Z. J., Qi, S. H., 2024. Characteristics and Genesis of Acid Drainage Contamination from a Rock Tunneling Project Site. Journal of Earth Science, 35(1): 190-200. https://doi.org/10.1007/s12583-021-1551-7
      Liu, C. Q., Lang, Y. C., Satake, H., et al., 2008. Identification of Anthropogenic and Natural Inputs of Sulfate and Chloride into the Karstic Ground Water of Guiyang, SW China: Combined δ37Cl and δ34S Approach. Environmental Science & Technology, 42(15): 5421-5427. https://doi.org/10.1021/es800380w
      Migaszewski, Z. M., Gałuszka, A., Dołęgowska, S., 2019. Extreme Enrichment of Arsenic and Rare Earth Elements in Acid Mine Drainage: Case Study of Wiśniówka Mining Area (South-Central Poland). Environmental Pollution, 244: 898-906. https://doi.org/10.1016/j.envpol.2018.10.106
      Panno, S. V., Hackley, K. C., Hwang, H. H., et al., 2006a. Characterization and Identification of Na-Cl Sources in Ground Water. Groundwater, 44(2): 176-187. https://doi.org/10.1111/j.1745-6584.2005.00127.x
      Panno, S. V., Kelly, W. R., Martinsek, A. T., et al., 2006b. Estimating Background and Threshold Nitrate Concentrations Using Probability Graphs. Groundwater, 44(5): 697-709. https://doi.org/10.1111/j.1745-6584.2006.00240.x
      Phillips, D. L., 2001. Mixing Models in Analyses of Diet Using Multiple Stable Isotopes: A Critique. Oecologia, 127(2): 166-170. https://doi.org/10.1007/s004420000571
      Pu, T., He, Y. Q., Zhang, T., et al., 2013. Isotopic and Geochemical Evolution of Ground and River Waters in a Karst Dominated Geological Setting: A Case Study from Lijiang Basin, South-Asia Monsoon Region. Applied Geochemistry, 33: 199-212. https://doi.org/10.1016/j.apgeochem.2013.02.013
      Ren, K., Pan, X. D., Yuan, D. X., et al., 2022. Nitrate Sources and Nitrogen Dynamics in a Karst Aquifer with Mixed Nitrogen Inputs (Southwest China): Revealed by Multiple Stable Isotopic and Hydro-Chemical Proxies. Water Research, 210: 118000. https://doi.org/10.1016/j.watres.2021.118000
      Ren, K., Zeng, J., Liang, J. P., et al., 2021. Impacts of Acid Mine Drainage on Karst Aquifers: Evidence from Hydrogeochemistry, Stable Sulfur and Oxygen Isotopes. Science of the Total Environment, 761: 143223. https://doi.org/10.1016/j.scitotenv.2020.143223
      Ren, M. M., Huang, F., Hu, X. N., et al., 2020. Characteristics and Sources of Dissolved Inorganic Carbon and Nitrate in Lijiang River Basin. Earth Science, 45(5): 1830-1843(in Chinese with English abstract).
      Shi, W. Z., Zhao, C. H., Liang, Y. P., et al., 2022. Genetic Mechanism Analysis of Low Ca/Mg Value of Acid Goaf Water in Coal Mine Drainage. Carsologica Sinica, 41(4): 511-521(in Chinese with English abstract).
      Singh, K. P., Gupta, S., Mohan, D., 2014. Evaluating Influences of Seasonal Variations and Anthropogenic Activities on Alluvial Groundwater Hydrochemistry Using Ensemble Learning Approaches. Journal of Hydrology, 511: 254-266. https://doi.org/10.1016/j.jhydrol.2014.01.004
      Skousen, J., Zipper, C. E., Rose, A., et al., 2017. Review of Passive Systems for Acid Mine Drainage Treatment. Mine Water and the Environment, 36(1): 133-153. https://doi.org/10.1007/s10230-016-0417-1
      Sun, J., Kobayashi, T., Strosnider, W. H. J., et al., 2017. Stable Sulfur and Oxygen Isotopes as Geochemical Tracers of Sulfate in Karst Waters. Journal of Hydrology, 551: 245-252. https://doi.org/10.1016/j.jhydrol.2017.06.006
      Tabelin, C. B., Silwamba, M., Paglinawan, F. C., et al., 2020. Solid-Phase Partitioning and Release-Retention Mechanisms of Copper, Lead, Zinc and Arsenic in Soils Impacted by Artisanal and Small-Scale Gold Mining (ASGM) Activities. Chemosphere, 260: 127574. https://doi.org/10.1016/j.chemosphere.2020.127574
      Taylor, B. E., Wheeler, M. C., 1993. Sulfur- and Oxygen-Isotope Geochemistry of Acid Mine Drainage in the Western United States: Field and Experimental Studies Revisited. ACS Symposium Series. Washington, DC: American Chemical Society: 481-514. https://doi.org/10.1021/bk-1994-0550.ch030
      Zhang, Y., Kelly, W. R., Panno, S. V., et al., 2014. Tracing Fecal Pollution Sources in Karst Groundwater by Bacteroidales Genetic Biomarkers, Bacterial Indicators, and Environmental Variables. Science of the Total Environment, 490: 1082-1090. https://doi.org/10.1016/j.scitotenv.2014.05.086
      Zhao, Y., Zou, S. Z., Shen, H. Y., et al., 2021. Dynamic Characteristics and Equilibrium of Water Level of the Karst Groundwater System beneath the Huixian Wetland. Carsologica Sinica, 40(2): 325-333 (in Chinese with English abstract).
      曹慧丽, 李伟, 苏春利, 等, 2023. 水化学及硫同位素对大冶矿区地下水硫酸盐污染的指示. 地球科学, 48(9): 3432-3443. doi: 10.3799/dqkx.2022.119
      陈珲, 崔一涵, 汪海明, 等, 2024. 矿山生态修复及其固碳潜力研究进展. 地球科学, 49(12): 4594-4607. doi: 10.3799/dqkx.2024.081
      郭雅思, 于奭, 黎泳珊, 等, 2016. 桂林市酸雨变化特征及来源分析. 环境科学, 37(8): 2897-2905.
      黄奇波, 邹胜章, 覃小群, 等, 2023. 桂林市会仙岩溶湿地水资源特征及有效调控. 中国岩溶, 42(4): 722-732, 762.
      贾晓岑, 周建伟, 朱恒华, 等, 2020. 招远金矿区水体中硫同位素特征及其对污染来源的指示. 水文地质工程地质, 47(5): 179-188.
      李严, 曹明达, 靳孟贵, 等, 2020. 湖北泉水河流域水化学特征和硝酸盐来源示踪. 地球科学, 45(3): 1061-1070. doi: 10.3799/dqkx.2019.060
      任梦梦, 黄芬, 胡晓农, 等, 2020. 漓江流域碳氮同位素组成特征及其来源初探. 地球科学, 45(5): 1830-1843. doi: 10.3799/dqkx.2019.206
      石维芝, 赵春红, 梁永平, 等, 2022. 煤矿酸性"老窑水"低Ca/Mg成因机制. 中国岩溶, 41(4): 511-521.
      赵一, 邹胜章, 申豪勇, 等, 2021. 会仙湿地岩溶地下水系统水位动态特征与均衡分析. 中国岩溶, 40(2): 325-333.
    • 加载中

    Catalog

      通讯作者: 陈斌, bchen63@163.com
      • 1. 

        沈阳化工大学材料科学与工程学院 沈阳 110142

      1. 本站搜索
      2. 百度学术搜索
      3. 万方数据库搜索
      4. CNKI搜索

      Figures(9)  / Tables(1)

      Article views (75) PDF downloads(12) Cited by()
      Proportional views

      /

      DownLoad:  Full-Size Img  PowerPoint
      Return
      Return