- 中文版：
- EI 100%收录
- 英文版
- SCI 100%收录
中国出版政府奖提名奖
中国百强科技报刊
湖北出版政府奖
中国高校百佳科技期刊
中国最美期刊
中国出版政府奖提名奖
中国百强科技报刊
湖北出版政府奖
中国高校百佳科技期刊
中国最美期刊
| Citation: | Wang Lei, Wang Xiangdong, Hu Jun, Jin Xinbiao, Zhang Xiong, Tan Juanjuan, 2025. Superimposed Mineralization of Dabaoshan Polymetallic Deposit in Guangdong Province: Evidence from Sulfide Re-Os and Rb-Sr Dating and In-Situ Trace Element Analysis. Earth Science, 50(7): 2548-2565. doi: 10.3799/dqkx.2025.104
|
The Dabaoshan deposit is a large-sized polymetallic deposit within the Qin-Hang Metallogenic Belt, and it is still controversial whether there has been submarine exhalative sedimentation. In this study, we conducted isotopic dating and in-situ elemental analysis of various sulfides in the deposit, having obtained Re-Os isochron age of (366±33) Ma for pyrrhotites and Rb-Sr isochron age of (166.3±2.5) Ma for sphalerite, respectively. The pyrrhotite is characterized by low concentrations of Co and Te, and high concentrations of Ni and Se, with Co/Ni ratios predominantly below 1, indicating a sedimentary origin. Additionally, sphalerite is relatively enriched in elements such as Fe, Mn, Cd, Ga, In, and Sn, exhibiting relatively low Zn/Cd and Cd/Fe ratios, low Co content, and high Sn content, indicating a sedimentary exhalative origin. Generally, the Dabaoshan polymetallic deposit experienced mineralization through Devonian exhalative sedimentation mineralization, followed by Jurassic magmatic-hydrothermal superimposition. The Re-Os isotope system of sulfides remained stable at a mineralization temperature around 400 ℃, preserving the in-situ geochemical signatures of the initial sedimentary processes. The findings provide valuable insights into the genesis of massive sulfide deposits in South China.
|
Brenan, J. M., Cherniak, D. J., Rose, L. A., 2000. Diffusion of Osmium in Pyrrhotite and Pyrite: Implications for Closure of the Re-Os Isotopic System. Earth and Planetary Science Letters, 180: 399-413. https://doi.org/10.1016/S0012-821X(00)00165-5
|
|
Cai, J. H., Liu, J. Q., 1993. Research and Its Application on the Inclusions Characteristics in the Dabaoshan Polymetallic Deposit, Northern Guangdong. Journal of Mineralogy and Petrology, 13(1): 33-40 (in Chinese with English abstract). http://www.researchgate.net/publication/313672438_Research_and_its_application_on_the_inclusions_characteristics_in_the_Dabaoshan_polymetallic_deposit_Northern_Guangdong
|
|
Chen, L., Wang, Z. Q., Zhao, Y. Y., et al., 2013. Re-Os Isotopic Dating of Pyrrhotite in the Linghou Cu Deposit, Jiande, Zhejiang Province and Its Geological Significance. Acta Geologica Sinica, 87(12): 1864-1873 (in Chinese with English abstract).
|
|
Chu, X. K., Li, B., Shen, P., et al., 2022. Trace Elements in Sulfide Minerals from the Huangshaping Copper-Polymetallic Deposit, Hunan, China: Ore Genesis and Element Occurrence. Ore Geology Reviews, 144: 104867. https://doi.org/10.1016/j.oregeorev.2022.104867
|
|
Du, A. D., Wu, S. Q., Sun, D. Z., et al., 2004. Preparation and Certification of Re-Os Dating Reference Materials: Molybdenites HLP and JDC. Geostandards and Geoanalytical Research, 28(1): 41-52. https://doi.org/10.1111/j.1751-908X.2004.tb01042.x
|
|
Du, G. M., Mei, Y. P., Cai, H., et al., 2012. Geochronology Research and Its Significance for Mo-W Polymetallic Deposit of Dabao Mountain in Northern Guangdong Province. Geology and Mineral Resources of South China, 28(3): 226-231 (in Chinese with English abstract).
|
|
Fu, X. M., Zhang, D. X., Dai, T. G., et al., 2018. Trace Element Record of Pyrite from Diverse Deposits-Examples from the Dabaoshan Polymetallic Deposit of Northern Guangdong, South China. Geotectonica et Metallogenia, 42(3): 505-519 (in Chinese with English abstract).
|
|
Ge, C. H., Han, F., 1986. Submarine Volcanic Hydrothermal Sedimentary Origin of the Dabaoshan Iron and Polymetallic Sulfide Deposit. Mineral Deposits, 5(1): 1-12 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-KCDZ198601000.htm
|
|
Ge, C. H., Han, F., 1987. Geological and Geochemical Characteristics of Exhalative-Sedimentary Mineralization of the Dabaoshan Deposit in Guangdong Province. Science and Technology of China Press, Beijing, 111 (in Chinese).
|
|
Gu, L. X., Zaw, K., Hu, W. X., et al., 2007. Distinctive Features of Late Palaeozoic Massive Sulphide Deposits in South China. Ore Geology Reviews, 31(1-4): 107-138. https://doi.org/10.1016/j.oregeorev.2005.01.002
|
|
Guo, W. M., Lu, J. J., Jiang, S. Y., et al., 2011. Re-Os Isotope Dating of Pyrite from the Footwall Mineralization Zone of the Xinqiao Deposit, Tongling, Anhui Province: Geochronological Evidence for Submarine Exhalative Sedimentation. Chinese Science Bulletin, 56: 3860-3865. https://doi.org/10.1007/s11434-011-4770-y
|
|
Huang, X. W., Qi, L., Gao, J. F., et al., 2016. Some Thoughts on Sulfide Re-Os Isotope Dating. Bulletin of Mineralogy, Petrology and Geochemistry, 35(3): 432-440 (in Chinese with English abstract).
|
|
Huang, X. W., Zhou, M. F., Qi, L., et al., 2013. Re-Os Isotopic Ages of Pyrite and Chemical Composition of Magnetite from the Cihai Magmatic-Hydrothermal Fe Deposit, NW China. Mineralium Deposita, 48(8): 925-946. https://doi.org/10.1007/s00126-013-0467-2
|
|
Hu, R. Z., Zhou, M. F., 2012. Multiple Mesozoic Mineralization Events in South China—An Introduction to the Thematic Issue. Mineralium Deposita, 47: 579-588. https://doi.org/10.1007/s00126-012-0431-6
|
|
Jiang, S. Y., Zhao, K. D., Jiang, Y. H., et al., 2008. Characteristics and Genesis of Mesozoic A-Type Granites and Associated Mineral Deposits in the Southern Hunan and Northern Guangxi Provinces along the Shi-Hang Belt, South China. Geological Journal of China Universities, 14(4): 496-509 (in Chinese with English abstract).
|
|
Li, C. Y., Zhang, H., Wang, F. Y., et al., 2012. The Formation of the Dabaoshan Porphyry Molybdenum Deposit Induced by Slab Rollback. Lithos, 150: 101-110. https://doi.org/10.1016/j.lithos.2012.04.001
|
|
Li, Y., Selby, D., Li, X. H., et al., 2018. Multisourced Metals Enriched by Magmatic-Hydrothermal Fluids in Stratabound Deposits of the Middle-Lower Yangtze River Metallogenic Belt, China. Geology, 46(5): 391-394. https://doi.org/10.1130/g39995.1
|
|
Li, Y. J., Ji, H., Xiong, J. J., et al., 2024. Micro-Textures, In-Situ Trace Elemental and Sulfur Isotopic Analyses for Pyrite and Pyrrhotite from the Xiasai Ag-Pb-Zn-Sn Deposit, Central Yidun Terrane (SW China): Implication for Ore Formation. Ore Geology Reviews, 165: 105913. https://doi.org/10.1016/j.oregeorev.2024.105913
|
|
Lin, D. Y., Wang, L., Wang, X. D., et al., 2024. Depositional Age and Provenance of Ore-Hosting Strata in the Dabaoshan Copper Polymetallic Deposit, Northern Guangdong Province: Implication on Ore Genesis. Geological Bulletin of China, 43(9): 1565-1594 (in Chinese with English abstract).
|
|
Liu, G. Q., Yang, S. Y., Zhang, X. L., et al., 1985. A Preliminary Study on the Genesis of the Dabaoshan Polymetallic Deposit in Northern Guangdong. Acta Geologica Sinica, 59(1): 47-60 (in Chinese with English abstract).
|
|
Liu, S., Wang, C. L., Huang, W. T., et al., 2012. LA-ICP-MS Zircon U-Pb Age and Dynamic Background of the Dabaoshan Porphyry Associated with Mo-W Mineralization in Northern Guangdong Province. Geotectonica et Metallogenia, 36(3): 440-449 (in Chinese with English abstract). http://epub.cnki.net/grid2008/docdown/docdownload.aspx?filename=DGYK201203020&dbcode=CJFD&year=2012&dflag=pdfdown
|
|
Liu, W. S., Zhao, R. Y., Zhang, X., et al., 2019. The EPMA and LA-ICP-MS In-Situ Geochemical Features of Pyrrhotite and Pyrite in Dabaoshan Cu-Polymetallic Deposit, North Guangdong Province, and Their Constraint on Genetic Mechanism. Acta Geoscientica Sinica, 40(2): 291-306 (in Chinese with English abstract).
|
|
Liu, X. S., Zhou, S. Z., 1984. The Discovery of Sulfide Fossils in Strata-Bound Polymetalliferous Ore Deposit from Dabaoshan, Qujiang County, Guandong Province, with a Reference to Its Geological Significance. Journal of Nanjing University (Natural Sciences), 20(1): 139-143 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-NJDZ198401017.htm
|
|
Leng, C. B., 2017. Genesis of Hongshan Cu Polymetallic Large Deposit in the Zhongdian Area, NW Yunnan: Constraints from LAICPMS Trace Elements of Pyrite and Pyrrhotite. Earth Science Frontiers, 24(6): 162-175 (in Chinese with English abstract).
|
|
Lyu, C., Gao, J. F., Qi, L., et al., 2023. Analytical Methods and Application of Sulfide Re-Os Isotope Dating of Mineral Deposits: Research Progress and Problems. Earth Science, 48(12): 4387-4403 (in Chinese with English abstract).
|
|
Lyu, L. S., Mao, J. W., Li, H. B., et al., 2011. Pyrrhotite Re-Os and SHRIMP Zircon U-Pb Dating of the Hongqiling Ni-Cu Sulfide Deposits in Northeast China. Ore Geology Reviews, 43(1): 106-119. https://doi.org/10.1016/j.oregeorev.2011.02.003
|
|
Lyu, X. Q., Mao, Q. G., Guo, N. X., et al., 2020. Re-Os Isotopic Dating of Pyrrhotite from Yueyawan Cu-Ni Sulfide Deposit in Kalatage Area of East Tianshan Mountain and Its Geological Significance. Earth Science, 45(9): 3475-3486 (in Chinese with English abstract).
|
|
Mao, J. W., Cheng, Y. B., Chen, M. H., et al., 2013. Major Types and Time-Space Distribution of Mesozoic Ore Deposits in South China and Their Geodynamic Settings. Mineralium Deposita, 48(3): 267-294. https://doi: 10.1007/s00126-012-0446-z
|
|
Mao, J. W., Zheng, W., Xie, G. Q., et al., 2021. Recognition of a Middle-Late Jurassic Arc-Related Porphyry Copper Belt along the Southeast China Coast: Geological Characteristics and Metallogenic Implications. Geology, 49(5): 592-596. https://doi.org/10.1130/g48615.1
|
|
Mao, W., Li, X. F., Yang, F. C., 2013. Zircon LA-ICP-MS U-Pb Ages of Granites at Dabaoshan Polymetallic Deposit and Its Geological Significance, Guangdong, South China. Acta Petrologica Sinica, 29(12): 4104-4120 (in Chinese with English abstract).
|
|
Nakai, S., Halliday, A. N., Kesler, S. E., et al., 1993. Rb-Sr Dating of Sphalerites from Mississippi Valley-Type (MVT) Ore Deposits. Geochimica et Cosmochimica Acta, 57(2): 417-427. https://doi.org/10.1016/0016-7037(93)90440-8
|
|
Qu, H. Y., Chen, M. H., Yang, F. C., et al., 2014. Metallogenic Chronology of the Stratiform Cu Orebody in the Dabaoshan Cu Polymetallic Deposit, Northern Guangdong Province and Its Geological Significance. Acta Petrologica Sinica, 30(1): 152-162 (in Chinese with English abstract).
|
|
Qu, H. Y., Mao, J. W., Zhou, S. M., et al., 2020. Metallogenesis of Stratiform Cu Mineralization in the Dabaoshan Polymetallic Deposit, Northern Guangdong Province, South China. Journal of Geochemical Exploration, 210: 106448. https://doi.org/10.1016/j.gexplo.2019.106448
|
|
Shirey, S. B., Walker, R. J., 1995. Carius Tube Digestion for Low-Blank Rhenium-Osmium Analysis. Analytical Chemistry, 67: 2136-2141. https://doi.org/10.1021/ac00109a036
|
|
Sillitoe, R. H., 2010. Porphyry Copper Systems. Economic Geology, 105(1): 3-41. https://doi.org/10.2113/gsecongeo.105.1.3
|
|
Smoliar, H. J., Walker, R. J., Morgan, J. W., 1996. Re-Os Ages of Group IIA, IIIA, IVA, and IVB Iron Meteorites. Science, 271: 1099-1102. https://doi.org/10.1126/science.271.5252.109
|
|
Song, S. M., Hu, K., Jiang, S. Y., et al., 2007. The He-Ar-Pb-S Isotope Tracing on Ore-Forming Fluid in Dabao Hill Polymetallic Deposit, North Guangdong. Contributions to Geology and Mineral Resources Research, 22(2): 87-92 (in Chinese with English abstract).
|
|
Su, S. Q., Qin, K. Z., Li, G. M., et al., 2019. Geochronology and Geochemistry of Early Silurian Felsic Volcanic Rocks in the Dabaoshan Ore District, South China: Implications for the Petrogenesis and Geodynamic Setting. Geological Journal, 54(6): 3286-3303. https://doi.org/10.1002/gj.3328
|
|
Wang, L., Hu, M. G., Yang, Z., et al., 2011. U-Pb and Re-Os Geochronology and Geodynamic Setting of the Dabaoshan Polymetallic Deposit, Northern Guangdong Province, South China. Ore Geology Reviews, 43(1): 40-49. https://doi.org/10.1016/j.oregeorev.2011.06.008
|
|
Wang, L., Jin, X. B., Xu, D. M., et al., 2019. Geochronological, Geochemical, and Nd-Hf Isotopic Constraints on the Origin of Magmatism in the Dabaoshan Ore District of South China. Geological Journal, 54(3): 1518-1534. https://doi.org/10.1002/gj.3248
|
|
Wu, J., Wang, G. Q., Liang, H. Y., et al., 2014. Indentification of Caledonian Volcanic Rock in the Dabaoshan Ore-Field in Northern Guangdong Province and Its Geological Implication. Acta Petrologica Sinica, 30(4): 1145-1154 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-YSXB201404019.htm
|
|
Xiang, J. H., Liang, X. Q., Shan, Y. H., et al., 2018. Two Phases of Mineralization in the Dabaoshan Polymetallic Deposit, Guangdong Province: Constraints from Re-Os Geochronology of Black Carbonaceous Mudstone and Molybdenite. Geotectonica et Metallogenia, 42(4): 732-745 (in Chinese with English abstract).
|
|
Xu, K. Q., Wang, H. N., Zhou, J. P., et al., 1996. A Discussion on the Exhalative Sedimentary Massive Sulfide Deposits of South China. Geological Journal of China Universities, 2(3): 241-256 (in Chinese).
|
|
Yang, Z. K., Yang, Y., Zhang, Z. K., et al., 2022. Geochemistry of Pyrrhotite in the Jiama Deposit, Tibet and Its Relationship with Gold Enrichment and Precipitation. Geology in China, 49(4): 1198-1213 (in Chinese with English abstract).
|
|
Ye, L., Cook, N. J., Ciobanu, C. L., et al., 2011. Trace and Minor Elements in Sphalerite from Base Metal Deposits in South China: A LA-ICPMS Study. Ore Geology Reviews, 39(4): 188-217. https://doi.org/10.1016/j.oregeorev.2011.03.001
|
|
Ying, L. J., Wang, D. H., Li, C., et al., 2017. Re-Os Dating of Sulfides in the North Stratiform Ore Body in Dabaoshan, Guangdong Province and Its Indication. Earth Science Frontiers, 24(5): 31-38 (in Chinese with English abstract).
|
|
Yuan, J. H., Zhan, X. C., Hu, M. Y., et al., 2015. Characterization of Matrix Effects in Microanalysis of Sulfide Minerals by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Based on an Element Pair Method. Spectroscopy and Spectral Analysis, 35(2): 512-518 (in Chinese with English abstract).
|
|
Zhang, D. X., Liu, J. B., Wang, Z. L., et al., 2024. In Situ LA-ICP-MS Trace Elements in Sphalerite from the Fankou Pb-Zn Deposit, South China: Implications for Ore Genesis. Ore Geology Reviews, 164: 105812. https://doi.org/10.1016/j.oregeorev.2023.105812
|
|
Zhao, G. C., Cawood, P. A., 2012. Precambrian Geology of China. Precambrian Research, 222-223: 13-54. https://doi.org/10.1016/j.precamres.2012.09.017
|
|
Zhou, T. F., Zhang, L. J., Yuan, F., et al., 2010. LA-ICP-MS In Situ Trace Element Analysis of Pyrite from the Xinqiao Cu-Au-S Deposit in Tongling, Anhui, and Its Constraints on the Ore Genesis. Earth Science Frontiers, 17(2): 306-319 (in Chinese with English abstract).
|
|
Zu, B., Xue, C. J., Zhao, Y., et al., 2015. Late Cretaceous Metallogeny in the Zhongdian Area: Constraints from Re-Os Dating of Molybdenite and Pyrrhotite from the Hongshan Cu Deposit, Yunnan, China. Ore Geology Reviews, 64: 1-12. https://doi.org/10.1016/j.oregeorev.2014.06.009
|
|
Zuo, L. Y., Pei, R. F., Wang, H. F., 2019. Re-Os Age Report of Pyrrhotite in the Dhi Samir Amprophyre-Type Copper-Nickel Sulfide Deposit in Yemen. China Geology, 2(2): 239-240. https://doi.org/10.31035/cg2018107
|
|
蔡锦辉, 刘家齐, 1993. 粤北大宝山多金属矿床矿物包裹体特征研究及应用. 矿物岩石, 13(1): 33-40.
|
|
陈雷, 王宗起, 赵元艺, 等, 2013. 浙江建德岭后铜矿磁黄铁矿Re-Os年代学特征及成矿意义. 地质学报, 87(12): 1864-1873.
|
|
杜国民, 梅玉萍, 蔡红, 等, 2012. 粤北大宝山钼钨多金属矿床年代学研究及其意义. 华南地质与矿产, 28(3): 226-231.
|
|
傅晓明, 张德贤, 戴塔根, 等, 2018. 不同成因类型矿化中黄铁矿微量元素地球化学记录——以广东大宝山多金属矿床为例. 大地构造与成矿学, 42(3): 505-519.
|
|
葛朝华, 韩发, 1986. 大宝山铁‒多金属矿床的海相火山热液沉积成因特征. 矿床地质, 5(1): 1-12.
|
|
葛朝华, 韩发, 1987. 广东大宝山矿床喷气‒沉积成因地质地球化学特征. 北京: 中国科学技术出版社, 111.
|
|
黄小文, 漆亮, 高剑峰, 等, 2016. 关于硫化物Re-Os同位素定年的一些思考. 矿物岩石地球化学通报, 35(3): 432-440.
|
|
蒋少涌, 赵葵东, 姜耀辉, 等, 2008. 十杭带湘南‒桂北段中生代A型花岗岩带成岩成矿特征及成因讨论. 高校地质学报, 14(4): 496-509.
|
|
蔺东永, 王磊, 王祥东, 等, 2024. 粤北大宝山铜多金属矿区赋矿地层时代及对矿床成因的指示. 地质通报, 43(9): 1565-1594.
|
|
刘姤群, 杨世义, 张秀兰, 等, 1985. 粤北大宝山多金属矿床成因的初步探讨. 地质学报, 59(1): 47-60.
|
|
刘莎, 王春龙, 黄文婷, 等, 2012. 粤北大宝山斑岩钼钨矿床赋矿岩体锆石LA-ICP-MS U-Pb年龄与矿床形成动力学背景分析. 大地构造与成矿学, 36(3): 440-449.
|
|
刘孝善, 周顺之, 1984. 广东大宝山层控多金属矿床中首次发现硫化物化石及其地质意义. 南京大学学报(自然科学版), 20(1): 139-143.
|
|
刘武生, 赵如意, 张熊, 等, 2019. 粤北大宝山铜多金属矿区黄铁矿与磁黄铁矿EPMA和LA-ICP-MS原位微区组分特征及其对矿床成因机制约束. 地球学报, 40(2): 291-306.
|
|
冷成彪, 2017. 滇西北红山铜多金属矿床的成因类型: 黄铁矿和磁黄铁矿LA-ICPMS微量元素制约. 地学前缘, 24(6): 162-175.
|
|
吕串, 高剑峰, 漆亮, 等, 2023. 硫化物Re-Os同位素定年分析方法及其在矿床年代学中的应用: 研究现状及存在问题. 地球科学, 48(12): 4387-4403. doi: 10.3799/dqkx.2023.061
|
|
吕晓强, 毛启贵, 郭娜欣, 等, 2020. 东天山卡拉塔格地区月牙湾铜镍硫化物矿床磁黄铁矿Re-Os同位素测定及其地质意义. 地球科学, 45(9): 3475-3486.
|
|
毛伟, 李晓峰, 杨富初, 2013. 广东大宝山多金属矿床花岗岩锆石LA-ICP-MS U-Pb定年及其地质意义. 岩石学报, 29(12): 4104-4120.
|
|
瞿泓滢, 陈懋弘, 杨富初, 等, 2014. 粤北大宝山铜多金属矿床中层状铜矿体的成矿时代及其成因意义. 岩石学报, 30(1): 152-162.
|
|
宋世明, 胡凯, 蒋少涌, 等, 2007. 粤北大宝山多金属矿床成矿流体的He-Ar-Pb-S同位素示踪. 地质找矿论丛, 22(2): 87-92.
|
|
伍静, 王广强, 梁华英, 等, 2014. 粤北大宝山矿区加里东期火山岩的厘定及其地质意义. 岩石学报, 30(4): 1145-1154.
|
|
向建华, 梁新权, 单业华, 等, 2018. 广东大宝山多金属矿床两期成矿: 来自黑色炭质泥岩和辉钼矿Re-Os同位素定年的证据. 大地构造与成矿学, 42(4): 732-745.
|
|
徐克勤, 王鹤年, 周建平, 等, 1996. 论华南喷流‒沉积块状硫化物矿床. 高校地质学报, 2(3): 241-256.
|
|
杨征坤, 杨阳, 张忠坤, 等, 2022. 西藏甲玛矿床磁黄铁矿微量元素特征及其与金富集沉淀的耦合机制. 中国地质, 49(4): 1198-1213.
|
|
应立娟, 王登红, 李超, 等, 2017. 广东大宝山北部层状矿体硫化物Re-Os测年及指示. 地学前缘, 24(5): 31-38.
|
|
袁继海, 詹秀春, 胡明月, 等, 2015. 基于元素对研究激光剥蚀‒电感耦合等离子体质谱分析硫化物矿物的基体效应. 光谱学与光谱分析, 35(2): 512-518.
|
|
周涛发, 张乐骏, 袁峰, 等, 2010. 安徽铜陵新桥Cu-Au-S矿床黄铁矿微量元素LA-ICP-MS原位测定及其对矿床成因的制约. 地学前缘, 17(2): 306-319.
|
Figures(12) / Tables(4)
DownLoad:
