Zn3（PhCH=CHCOO）6（phen）2·H2O的纳米晶结构计算及环境属性

陈洪; 胡波; 宫斯宁; 陈敬中; 王长娟; 潘会; 吴秀玲

Volume 34 Issue 4

Jul. 2009

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Article Navigation > Earth Science > 2009 > 34(4): 629-634

CHEN Hong, HU Bo, GONG Si-ning, CHEN Jing-zhong, WANG Zhang-juan, PAN Hui, WU Xiu-ling, 2009. Nano-Crystal Calculation and Environmental Significance of the Complex Zn3(PhCH=CHCOO)6(phen)2·H2O. Earth Science, 34(4): 629-634.

Citation:

CHEN Hong, HU Bo, GONG Si-ning, CHEN Jing-zhong, WANG Zhang-juan, PAN Hui, WU Xiu-ling, 2009. Nano-Crystal Calculation and Environmental Significance of the Complex Zn₃(PhCH=CHCOO)₆(phen)₂·H₂O. Earth Science, 34(4): 629-634.

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Nano-Crystal Calculation and Environmental Significance of the Complex Zn₃(PhCH=CHCOO)₆(phen)₂·H₂O

Engineering Research Center o f Nano-Geomaterials of the Ministry of Education, Faculty o f Materials Science and Chemical Engineering, China University of Geosciences, W uhan 430074, China

Received Date: 2008-08-12
Publish Date: 2009-07-25

Abstract

Abstract

The complex Zn₃ (PhCH=CHCOO) ₆ (phen) ₂·H₂O is a new environmental mineral.Its micro-structure is similar to that of manganese oxide and manganese hydroxide.The formation environment and micro-crystal structure have obvious environmental attribute.In order to investigate the nano-crystal structure, the optimum dimension, and the environment significance, we used the nano-crystal calculation method on the basis of the crystal structure of the title compound to discuss the crystal cell numbers, the atomicity, the surface layer atomicity and its proportion.By comparing the structure of manganese oxide and manganese hydroxide with the compound, we discuss its environmental attribute.It is found that the activity of the compound and surface effects are closely related with the particle size, and its inherence structure has obvious environmental attribute.Finally, we theoretically carry on the computation discussion to turning compounds into nanometer particle.The optimum dimension of its nano-particle is theoretically determined to be about 138 nm.
- Zn₃(PhCH=CHCOO)₆(phen)₂·H₂O,
- crystal structure,
- nanocrystals,
- nanocrystalline materials,
- chemical activity and stability,
- environmental significance.

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References(25)

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Nano-Crystal Calculation and Environmental Significance of the Complex Zn3(PhCH=CHCOO)6(phen)2·H2O

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Nano-Crystal Calculation and Environmental Significance of the Complex Zn₃(PhCH=CHCOO)₆(phen)₂·H₂O