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    中国百强科技报刊

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    Volume 36 Issue 3
    May  2011
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    Article Contents
    WANG Min, LU Shuang-fang, XUE Hai-tao, WU Chao-dong, WANG Xue-fei, 2011. The Influence and Appraisement of Source Rock Heterogeneity on Kinetic Parameters of Hydrocarbon Generation from Organic Matter. Earth Science, 36(3): 530-540. doi: 10.3799/dqkx.2011.054
    Citation: WANG Min, LU Shuang-fang, XUE Hai-tao, WU Chao-dong, WANG Xue-fei, 2011. The Influence and Appraisement of Source Rock Heterogeneity on Kinetic Parameters of Hydrocarbon Generation from Organic Matter. Earth Science, 36(3): 530-540. doi: 10.3799/dqkx.2011.054

    The Influence and Appraisement of Source Rock Heterogeneity on Kinetic Parameters of Hydrocarbon Generation from Organic Matter

    doi: 10.3799/dqkx.2011.054
    • Received Date: 2010-11-12
    • Publish Date: 2011-05-01
    • The heterogeneity of source rock, the uncertainty of frequency factor and the simulation experiment conditions (such as being open or closed, adding water or not, heating rates and the reproducibility) all affect the kinetic parameters of hydrocarbon generation from organic matter, which in turn, affect the reliability of appraised hydrocarbon potential. To this point, eighteen organic matter (OM) samples were pyrolyzed by using the Rock-Eval equipment, and parallel first-order reaction models including the model with a single frequency factor and a discrete distribution of activation energies (SFF model) and the model with multiple frequency factors and a discrete distribution of activation energies (MFF model) are adopted to analyze kinetic characteristics of hydrocarbon generation of all samples and to contrast the results difference of geological extrapolation. The comparison and analysis shows that the MFF model can avoid miscalculating the hydrocarbon generation potential (reaction ratio) in the low and high evolution stages, which appears in SFF model. For comparing the discrepancy of hydrocarbon generation from different type of kerogens, the arithmetic mean and weighted mean methods with pyrolysis parameter S2 are employed to get averaged kinetic parameters, and then averaged kinetic parameters are extrapolated with a heating rate of 3.3 ℃/Ma. At last, the application of two kind kinetic models with the kinetic parameters of the weighted mean methods in Heiyupao Sag of Songliao basin shows that if taking the hydrocarbon transformation ratio of 10% as the onset of the hydrocarbon generation threshold, the threshold depth of hydrocarbon generation is about 1 700 m, which is consistent with the appraisement result by using other geochemical parameters. Therefore, it is recommended that the kinetic method with the MFF model and the weighted mean kinetic parameters is used to appraise the hydrocarbon resource potential.

       

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    • Allred, V.D., 1966. Kinetics of oil shale pyrolysis. Chemical Engineering Progress, (62): 55-60.
      Behar, F., Lorant, F., Lewan, M., 2008. Role of NSO compounds during primary cracking of a Type II kerogen and a Type III lignite. Organic Geochemistry, (39): 1-22. doi: 10.1016/j.orggeochem.2007.10.007
      Behar, F.S., Kressmann, J.L., Rudkiewicz, et al., 1992. Experimental simulation in a confined system and kinetic modelling of kerogen and oil cracking. Organic Geochemistry, (19): 173-189. doi: 10.1016/0146-6380(92)90035-V
      Braun, R.L., Burnham, A.K., 1992. PMOD: a flexible model of oil and gas generation, cracking, and expulsion. Organic Geochemistry, 19(1-3): 161-172. doi:10. 1016/0146-6380(92)90034-U
      Burnham, A.K., Braun, R.L., Samou, A.M., 1988. Further comparison of methods for measuring kerogen pyrolysis rates and fitting kinetic parameters. Organic Geochemistry, 13(4-6): 839-845. doi: 10.1016/0146-6380(88)90236-7
      Burnham, A.K., Schmidt, J., Braun, R.L., 1995. A test of the parallel reaction model using kinetic measurements on hydrous pyrolysis residues. Organic Geochemistry, 23(10): 931-939. doi: 10.1016/0146-6380(95)00069-0
      Dieckmann, V., 2005. Modelling petroleum formation from heterogeneous source rocks: the influence of frequency factors on activation energy distribution and geological prediction. Marine and Petroleum Geology, (22): 375-390. doi:10.1016/j.marpetgeo. 2004.11.002
      Dieckmann, V., Keym, M., 2006. A new approach to bridge the effect of organofacies variations on kinetic modelling and geological extrapolations. Organic Geochemistry, (37): 728-739. doi: 10.1016/j.orggeochem.2005.12.008
      Friedman, H.L., 1963. Kinetics of thermal degradation of char-forming plastics from thermogravimetry: application to a phenolic plastic. Journal of Polymer Science(Part C), 6: 183-195. doi: 10.1002/polc.5070060121
      Huang, D.F., Li, J.C., Zhou, Z.H., et al., 1984. The evolution and hydrocarbon generating mechanism of terrestrial facies organic matter. Petroleum Industry Press, Beijing, 165-180 (in Chinese).
      Jarvie, D.M., 1991. Factors affecting rock-eval derived kinetic parameters. Chemical Geology, (93): 79-99. doi: 10.1016/0009-2541(91)90065-Y
      Jin, Q., Qian, J.L., Huang, X.H., 1986. Study on thermal degradation kinetics of source rock kerogen and quantitative estimation of hydrocarbon transformation. Acta Petrolei Sinica, 7(3): 11-19 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-SYXB198603001.htm
      Keym, M., Dieckman, V., Horsfield, B., et al., 2006. Source rock heterogeneity of the Upper Jurassic Draupne Formation, North Viking Graben, and its relevance to petroleum generation studies. Organic Geochemistry, (37): 220-243. doi: 10.1016/j.orggeochem.2005.08.023
      Klomp, U.C., Wright, P.A., 1990. A new method for the measurement of kinetic parameters of hydrocarbon generation from source rocks. Organic Geochemistry, 116(1-3): 49-60. doi: 10.1016/0146-6380(90)90025-U
      Lu, S.F., 1996. Kinetics theory of hydrocarbon generation from organic matter and its application. Petroleum Industry Press, Beijing (in Chinese).
      Lu, S.F., Li, J.N., Liu, S.J., et al., 2009. Oil generation threshold depth of Songliao basin: revision and its significanc. Petroleum Exploration and Development, 36(2): 166-173 (in Chinese with English abstract). doi: 10.1016/S1876-3804(09)60117-8
      Lu, S.F., Wang, Z.W., Huang, D.F., et al., 1995. Coal macerals of hydrocarbon generation kinetics. Science in China (Ser. B), 25(1): 101-107 (in Chinese). http://www.researchgate.net/publication/292432354_Coal_macerals_of_hydrocarbon_generation_kinetics
      Lu, S.F., Zhong, N.N., Xue, H.T., et al., 2007. Chemical kinetics study of hydrocarbon regeneration from organic matter in carbonate source rocks and its significance. Science in China (Ser. D), 50(4): 536-543. doi: 10.1007/s11430-007-2058-5
      Pepper, A.S., Corvit, P.J., 1995. Simple kinetic models of petroleum formation: part I, oil and gas generation from kerogen. Marine and Petroleum Geology, 12(3): 291-319. doi:10. 1016/0264-8172(95)98381-E
      Peters, K.E., Walters, C.C., Mankiewicz, P.J., 2006. Evaluation of kinetic uncertainty in numerical models of petroleum generation. American Association of Petroleum Geologists Bulletin, 90(3): 387-403. doi: 10.1306/10140505122
      Pitt, G.J., 1962. The kinetics of evolution of volatile products from coal. Fuel, (41): 267- 274. http://www.researchgate.net/publication/264739462_The_Kinetics_of_the_Evolution_of_Volatile_Products_From_Coal
      Quigley, T.M., Mackenzie, A.S., 1988. The temperatures of oil and gas formation in the sub-surface. Nature, 333(6173): 549-552. doi: 10.1038/333549a0
      Schaefer, R.G., Schenk, H.J., Hardelauf, H., et al., 1990. Determination of gross kinetic parameters for petroleum formation from jurassic source rocks of different maturity levels by means of laboratory experiments. Organic Geochemistry, 16(1-3): 115-120. doi: 10.1016/0146-6380(90)90031-T
      Schenk, H.J., Dieckmann, V., 2004. Prediction of petroleum formation: the influence of laboratory heating rates on kinetic parameters and geological extrapolations. Marine and Petroleum Geology, 21(1): 79-95. doi: 10.1016/j.marpetgeo.2003.11.004
      Schenk, H.J., Horsfield, B., 1993. Kinetics of petroleum generation by programmed-temperature closed-versus open-system pyrolysis. Geochimica et Cosmochimica Acta, 57(3): 623-630. doi: 10.1016/0016-7037(93)90373-5
      Tissot, B.P., Pelet, R., Ungerer, P., 1987. Thermal history of sedimentary basins, maturation indices, and kinetics of oil and gas generation. AAPG Bulletin, 71(12): 1445-1466. doi: 10.1306/703C80E7-1707-11D7-8645000102C1865D
      Tissot, B.P., Welte, D.H., 1984. Petroleum formation and occurrence. Springer-verlag, Berlin.
      Ungerer, P., 1990. State of the art of research in kinetic modelling of oil formation and expulsion. Organic Geochemistry, 16(1-3): 1-25. doi: 10.1016/0146-6380(90)90022-R
      Ungerer, P., Pelet, R., 1987. Extrapolation of the kinetics of oil and gas formation from laboratory experiments to sedimentary basins. Nature, 327: 52-54. doi: 10.1038/327052a0
      Wang, J.Q., Wu, L.Y., Qian, J.L., 1984. Kinetic study of hydrocarbon-forming pyrolysis of source rock by using rock evaluation apparatus. Journal of China University of Petroleum, 8(1): 1-9 (in Chinese with English abstract). http://www.cnki.com.cn/Article/CJFDTotal-SYDX198401003.htm
      Wang, M., Lu, S.F., Xue, H.T., et al., 2011. Study of hydrocarbon generation kinetic characteristics from different types of organic matter. Acta Geologica Sinica (English Edition), 85 (in press). http://d.wanfangdata.com.cn/Periodical/dzxb-e201103020
      黄第藩, 李晋超, 周翥红, 等, 1984. 陆相有机质演化和成烃机理. 北京: 石油工业出版社, 165-180.
      金强, 钱家麟, 黄醒汉, 1986. 生油岩干酪根热降解动力学研究及其在油气生成量计算中的应用. 石油学报, 7(3): 11-19. https://www.cnki.com.cn/Article/CJFDTOTAL-SYXB198603001.htm
      卢双舫, 1996. 有机质成烃动力学理论及其应用. 北京: 石油工业出版社.
      卢双舫, 李娇娜, 刘绍军, 等, 2009. 松辽盆地生油门限重新厘定及其意义. 石油勘探与开发, 36(2): 166-173. https://www.cnki.com.cn/Article/CJFDTOTAL-SKYK200902004.htm
      卢双舫, 王子文, 黄第藩, 等, 1995. 煤岩显微组分的成烃动力学. 中国科学(B辑), 25(1): 101-107. https://www.cnki.com.cn/Article/CJFDTOTAL-JBXK199501015.htm
      王剑秋, 乌立言, 钱家麟, 1984. 应用岩石评价仪进行生油岩热解生烃动力学研究. 华东石油学院学报, 8(1): 1-9. https://www.cnki.com.cn/Article/CJFDTOTAL-SYDX198401003.htm
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