大同盆地高砷地下水稀土元素特征及其指示意义

谢先军; 王焰新; 李俊霞; 苏春利; 吴亚; 余倩; 李梦娣

doi:10.3799/dqkx.2012.046

Volume 37 Issue 2

Mar. 2012

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Article Navigation > Earth Science > 2012 > 37(2): 381-390

XIE Xian-jun, WANG Yan-xin, LI Jun-xia, Su Chun-li, WU Ya, YU Qian, Li Meng-di, 2012. Characteristics and Implications of Rare Earth Elements in High Arsenic Groundwater from the Datong Basin. Earth Science, 37(2): 381-390. doi: 10.3799/dqkx.2012.046

Citation:

XIE Xian-jun, WANG Yan-xin, LI Jun-xia, Su Chun-li, WU Ya, YU Qian, Li Meng-di, 2012. Characteristics and Implications of Rare Earth Elements in High Arsenic Groundwater from the Datong Basin. Earth Science, 37(2): 381-390. doi: 10.3799/dqkx.2012.046

Citation:

XIE Xian-jun, WANG Yan-xin, LI Jun-xia, Su Chun-li, WU Ya, YU Qian, Li Meng-di, 2012. Characteristics and Implications of Rare Earth Elements in High Arsenic Groundwater from the Datong Basin. Earth Science, 37(2): 381-390. doi: 10.3799/dqkx.2012.046

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Characteristics and Implications of Rare Earth Elements in High Arsenic Groundwater from the Datong Basin

doi: 10.3799/dqkx.2012.046

XIE Xian-jun^{1, 2
,},
WANG Yan-xin^{1, 2},
LI Jun-xia^{1, 2},
Su Chun-li^{1, 2},
WU Ya^{1, 2},
YU Qian^{1, 2},
Li Meng-di^{1, 2}

1.
School of Environmental Studies, China University of Geosciences, Wuhan 430074, China
2.
State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Wuhan 430074, China

Received Date: 2010-08-12
Publish Date: 2012-03-15

Abstract

Abstract

In order to better understand the occurrence of high arsenic groundwater, rare earth elements (REEs) analyses were conducted for groundwater from the Datong basin. The results indicate that high arsenic groundwater usually has low ∑REE concentration and enriches in HREEs relative to LREEs. The low concentration of ∑REE in groundwater samples could be due to the scavenging of REEs onto the surface of solid phase Fe-Mn oxides/hydroxides within aquifer sediment. The enrichment of HREEs can be attributed to the combined result of complexation, and desorption and readsorption. The average up crust normalized REEs patterns clearly exhibit significant positive Ce and Eu anomalies in high arsenic groundwater. The observed good correlation between Ce/Ce^* values and Eu and Fe+Mn could be related to the reductive dissolution of Fe and Mn oxides/hydroxides. The relationship between As and Ce/Ce^* value and Eu suggests that Ce/Ce^* value and Eu concentration are useful indicators of arsenic mobilization in groundwater system.
- water pollution,
- arsenic,
- rare earth elements,
- redox reactions,
- hydrogeology,
- Datong basin

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References(40)

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