绿泥石对CO<sub>2</sub>-水-岩石相互作用的影响

杨国栋; 李义连; 马鑫; 董建兴

doi:10.3799/dqkx.2014.044

Volume 39 Issue 4

Apr. 2014

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Article Navigation > Earth Science > 2014 > 39(4): 462-472

Yang Guodong, Li Yilian, Ma Xin, Dong Jianxing, 2014. Effect of Chlorite on CO2-Water-Rock Interaction. Earth Science, 39(4): 462-472. doi: 10.3799/dqkx.2014.044

Citation:

Yang Guodong, Li Yilian, Ma Xin, Dong Jianxing, 2014. Effect of Chlorite on CO₂-Water-Rock Interaction. Earth Science, 39(4): 462-472. doi: 10.3799/dqkx.2014.044

Yang Guodong, Li Yilian, Ma Xin, Dong Jianxing, 2014. Effect of Chlorite on CO2-Water-Rock Interaction. Earth Science, 39(4): 462-472. doi: 10.3799/dqkx.2014.044

Citation:

Yang Guodong, Li Yilian, Ma Xin, Dong Jianxing, 2014. Effect of Chlorite on CO₂-Water-Rock Interaction. Earth Science, 39(4): 462-472. doi: 10.3799/dqkx.2014.044

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Effect of Chlorite on CO₂-Water-Rock Interaction

doi: 10.3799/dqkx.2014.044

1.
School of Environmental Studies, China University of Geosciences, Wuhan 430074, China
2.
Center for Hydrogeology and Environmental Geology Survey, China Geological Survey, Baoding 071051, China

Received Date: 2013-08-19
Publish Date: 2014-04-15

Abstract

Abstract

In order to understand the geochemical processes of key minerals in the supercritical CO₂ -water-rock system, we establish a one-dimensional vertical model to study the effect of chlorite contents in cap rock of 3%, 9% and 15% on CO₂ -water-rock interaction by numerical simulation software of TOUGHREACT based on the basic geological conditions of deep saline aquifer in Ordos basin, China. It is found that the mineral composition and permeability of the caprock change greatly after CO₂ broke into the caprock. It is not favorable for CO₂ storage when chlorite volume fraction is 3% because of the increasing permeability in 5 000 years. The permeability of caprock increases first and then decreases when chlorite volume fraction is 9% and 15%, resulting in self-sealing which facilitates the sequestration of CO₂. The results show that the dissolution of chlorite provides Mg²⁺, Fe²⁺ and AlO₂^- for precipitation of calcium montmorillonite, ankerite, dawsonite, and magnesite. The higher the chlorite content, the greater the amount of CO₂ mineralization capture, and the more obvious the effect of caprock self-sealing with the maximum caprock permeability decrease of 10%. This study provides a theoretical basis for long-term geological storage of CO₂ and its stability evaluation.
- chlorite,
- caprock,
- CO₂-water-rock interaction,
- self-sealing,
- permeability,
- numerical simulation,
- environmental geology

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References(44)

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Effect of Chlorite on CO2-Water-Rock Interaction

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Effect of Chlorite on CO₂-Water-Rock Interaction