长江干流丰水期河水硫酸盐同位素组成特征及其来源解析

李小倩; 刘运德; 周爱国; 张彬

doi:10.3799/dqkx.2014.147

Volume 39 Issue 11

Nov. 2014

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Article Navigation > Earth Science > 2014 > 39(11): 1547-1554,1592

Li Xiaoqian, Liu Yunde, Zhou Aiguo, Zhang Bin, 2014. Sulfur and Oxygen Isotope Compositions of Dissolved Sulfate in the Yangtze River during High Water Period and Its Sulfate Source Tracing. Earth Science, 39(11): 1547-1554,1592. doi: 10.3799/dqkx.2014.147

Citation:

Li Xiaoqian, Liu Yunde, Zhou Aiguo, Zhang Bin, 2014. Sulfur and Oxygen Isotope Compositions of Dissolved Sulfate in the Yangtze River during High Water Period and Its Sulfate Source Tracing. Earth Science, 39(11): 1547-1554,1592. doi: 10.3799/dqkx.2014.147

Citation:

Li Xiaoqian, Liu Yunde, Zhou Aiguo, Zhang Bin, 2014. Sulfur and Oxygen Isotope Compositions of Dissolved Sulfate in the Yangtze River during High Water Period and Its Sulfate Source Tracing. Earth Science, 39(11): 1547-1554,1592. doi: 10.3799/dqkx.2014.147

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Sulfur and Oxygen Isotope Compositions of Dissolved Sulfate in the Yangtze River during High Water Period and Its Sulfate Source Tracing

doi: 10.3799/dqkx.2014.147

Li Xiaoqian^{1, 2
,},
Liu Yunde²,
Zhou Aiguo^{1, 2
,
,},
Zhang Bin¹

1.
School of Environmental Studies, China University of Geosciences, Wuhan 430074, China
2.
State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Wuhan 430074, China

Received Date: 2014-04-29
Publish Date: 2014-11-01

Abstract

Abstract

Crustal weathering by sulfuric acid and its relationship with carbon cycling is a subject of greatest concern in the domain of global carbon cycling, with its key issue of the identification of riverine sulfate sources. In this study, stable sulfur and oxygen isotope compositions of riverine sulfate in the mainstream of the Yangtze River during rainy season are determined to trace the riverine sulfate sources and controlling factors. The SO₄^2-concentration keeps increasing with ever-increasing annual growth rate. The isotope compositions of dissolved sulfate in the Yangze River range from -3.5‰ to 5.6‰ for δ³⁴S_SO4 and from 3.7‰ to 9.2‰ for δ¹⁸O_SO4, showing a significantly negative linear correlation between δ³⁴S_SO4 and δ¹⁸O_SO4. The tendency of increased δ¹⁸O_SO4 values from upstream to downstream is controlled by δ¹⁸O_H2O values of the Yangtze River water. It is indicated that atmospheric acid deposition and sulfide oxidation are dominant sources of dissolved sulfate in the Yangze River. This study offers theoretical basis which facilitates further environmental explorations for chemical weathering of carbonate and carbon cycling.
- sulfur isotope,
- oxygen isotope,
- sulfate source,
- the Yangtze River,
- geochemistry

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References(41)

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Sulfur and Oxygen Isotope Compositions of Dissolved Sulfate in the Yangtze River during High Water Period and Its Sulfate Source Tracing

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