渝东北下寒武统牛蹄塘组页岩微纳米孔隙结构特征

王朋飞; 姜振学; 李卓; 陈磊; 王国臻; 黄璞; 阴丽诗

doi:10.3799/dqkx.2017.093

Volume 42 Issue 7

Jul. 2017

Turn off MathJax

Article Contents

Article Navigation > Earth Science > 2017 > 42(7): 1147-1156

Wang Pengfei, Jiang Zhenxue, Li Zhuo, Chen Lei, Wang Guozhen, Huang Pu, Yin Lishi, 2017. Micro-Nano Pore Structure Characteristics in the Lower Cambrian Niutitang Shale, Northeast Chongqing. Earth Science, 42(7): 1147-1156. doi: 10.3799/dqkx.2017.093

Citation:

Wang Pengfei, Jiang Zhenxue, Li Zhuo, Chen Lei, Wang Guozhen, Huang Pu, Yin Lishi, 2017. Micro-Nano Pore Structure Characteristics in the Lower Cambrian Niutitang Shale, Northeast Chongqing. Earth Science, 42(7): 1147-1156. doi: 10.3799/dqkx.2017.093

Citation:

Wang Pengfei, Jiang Zhenxue, Li Zhuo, Chen Lei, Wang Guozhen, Huang Pu, Yin Lishi, 2017. Micro-Nano Pore Structure Characteristics in the Lower Cambrian Niutitang Shale, Northeast Chongqing. Earth Science, 42(7): 1147-1156. doi: 10.3799/dqkx.2017.093

PDF( 2876 KB)

Micro-Nano Pore Structure Characteristics in the Lower Cambrian Niutitang Shale, Northeast Chongqing

doi: 10.3799/dqkx.2017.093

Wang Pengfei^{1,2
,},
Jiang Zhenxue^{1,2
,
,},
Li Zhuo^1,2,
Chen Lei^1,2,
Wang Guozhen^1,2,
Huang Pu^1,2,
Yin Lishi^1,2

1.
State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum, Beijing 102249, China
2.
Unconventional Natural Gas Research Institute, China University of Petroleum, Beijing 102249, China

Received Date: 2016-10-23
Publish Date: 2017-07-15

Abstract

Abstract

Lower Cambrian Niututang Formation shale in south China is one of the main target zones for shale gas exploration. However, the exploration of shale in northeastern Chongqing is not satisfactory as the pore structure of the shale is unclear. This study examined pores in shale samples from the Niutitang Formation using focused ion-beam scanning electron microscopy, nano-CT, and gas adsorption analysis. Results show that pores in Niutitang shale are rare and have small diameters and poor connectivity. Most Niutitang-shale pores are inorganic pores, including intraparticle and intergranular pores. N₂ adsorption hysteresis loop of Niutitang shale belongs to type H4 corresponding to narrow slit pore. The average total pore volume of the Niutitang shale is 0.0317mL/g, and the average total surface area is 34.57m²/g. Over-high thermal evolution degree resulting small number of organic pores and poor connectivity of micro-nano pores in Niutitang shale. Mesopores contributed most of the pore volume and micropores contributed more pore surface area than that of mesopores.
- northeast Chongqing,
- lower Cambrian,
- the Niutitang shale,
- pore structure,
- petroleum geology

FullText(HTML)

References(52)

References

Chen, Y.Y., Wei, L., Mastalerz, M., et al., 2015.The Effect of Analytical Particle Size on Gas Adsorption Porosimetry of Shale.International Journal of Coal Geology, 138:103-112.doi: 10.1016/j.coal.2014.12.012

Clarkson, C.R., Solano, N., Bustin, R.M., et al., 2013.Pore Structure Characterization of North American Shale Gas Reservoirs Using USANS/SANS, Gas Adsorption, and Mercury Intrusion.Fuel, 103:606-616.doi: 10.1016/j.fuel.2012.06.119

Guo, X.J., Shen, Y.H., He, S.L., 2015.Quantitative Pore Characterization and the Relationship between Pore Distributions and Organic Matter in Shale Based on Nano-CT Image Analysis:A Case Study for a Lacustrine Shale Reservoir in the Triassic Chang 7 Member, Ordos Basin, China.Journal of Natural Gas Science and Engineering, 27:1630-1640.doi: 10.1016/j.jngse.2015.10.033

Han, S.B., Zhang, J.C., Horsfield, B., et al., 2013.Pore Types and Characteristics of Shale Gas Reservoir:A Case Study of Lower Paleozoic Shale in Southeast Chongqing.Earth Science Frontiers, 20(3):247-253 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DXQY201303030.htm

Hou, Y.G., He, S., Yi, J.Z., et al., 2014.Effect of Pore Structure on Methane Sorption Potential of Shales.Petroleum Exploration and Development, 41(2):248-256 (in Chinese with English abstract). http://www.sciencedirect.com/science/article/pii/S1876380414600331

Hu, M.Y., Deng, Q.J., Hu, Z.G., 2014.Shale Gas Accumulation Conditions of the Lower Cambrian Niutitang Formation in Upper Yangtze Region.Oil & Gas Geology, 35(2):272-279 (in Chinese with English abstract). https://www.researchgate.net/publication/287676506_Shale_gas_accumulation_conditions_of_the_Lower_Cambrian_Niutitang_Formation_in_Upper_Yangtze_region

Ji, W.M., Song, Y., Jiang, Z.X, et al., 2016.Micro-Nano Pore Structure Characteristics and Its Control Factors of Shale in Longmaxi Formation, Southeastern Sichuan Basin.Acta Petrolei Sinica, 37(2):182-195 (in Chinese with English abstract).

Jia, C.Z., Zheng, M., Zhang, Y.F., 2012.Unconventional Hydrocarbon Resources in China and the Prospect of Exploration and Development.Petroleum Exploration and Development, 39(2):129-136 (in Chinese with English abstract). http://www.jstor.org/stable/3724534

Jiao, K., Yao, S.P., Liu, C., et al., 2014.The Characterization and Quantitative Analysis of Nanopores in Unconventional Gas Reservoirs Utilizing FESEM-FIB and Image Processing:An Example from the Lower Silurian Longmaxi Shale, Upper Yangtze Region, China.International Journal of Coal Geology, 128:1-11.doi: 10.1016/j.coal.2014.03.004

Jiao, S.J., Han, H., Weng, Q.P., et al., 2012.Scanning Electron Microscope Analysis of Porosity in Shale.Journal of Chinese Electron Microscopy Society, 31(5):432-436 (in Chinese with English abstract). http://trove.nla.gov.au/work/205288785

Lin, T., Zhang, J.C., Li, B., et al., 2014.Shale Gas Accumulation Conditions and Gas-Bearing Properties of the Lower Cambrian Niutitang Formation in Well Changye 1, Northwestern Hunan.Acta Petrolei Sinica, 35(5):839-846 (in Chinese with English abstract). https://www.researchgate.net/publication/287757398_Shale_gas_accumulation_conditions_and_gas-bearing_properties_of_the_Lower_Cambrian_Niutitang_Formation_in_Well_Changye_1_northwestern_Hunan?ev=auth_pub

Loucks, R.G., Reed, R.M., Ruppel, S.C., et al., 2009.Morphology, Genesis, and Distribution of Nanometer-Scale Pores in Siliceous Mudstones of the Mississippian Barnett Shale.Journal of Sedimentary Research, 79(12):848-861.doi: 10.2110/jsr.2009.092

Loucks, R.G., Reed, R.M., Ruppel, S.C., et al., 2012.Spectrum of Pore Types and Networks in Mudrocks and a Descriptive Classification for Matrix-Related Mudrock Pores.AAPG Bulletin, 96(6):1071-1098.doi: 10.1306/08171111061

Loucks, R.G., Ruppel, S.C., 2007.Mississippian Barnett Shale:Lithofacies and Depositional Setting of a Deep-Water Shale-Gas Succession in the Fort Worth Basin, Texas.AAPG Bulletin, 91(4):579-601.doi: 10.1306/11020606059

Milliken, K.L., Rudnicki, M., Awwiller, D.N., et al., 2013.Organic Matter-Hosted Pore System, Marcellus Formation (Devonian), Pennsylvania.AAPG Bulletin, 97(2):177-200.doi: 10.1306/07231212048

Slatt, R.M., O'Brien, N.R., 2011.Pore Types in the Barnett and Woodford Gas Shales:Contribution to Understanding Gas Storage and Migration Pathways in Fine-Grained Rocks.AAPG Bulletin, 95(12):2017-2030.doi: 10.1306/03301110145

Tan, J.Q., Horsfield, B., Mahlstedt, N., et al., 2015.Shale Gas Potential of the Major Marine Shale Formations in the Upper Yangtze Platform, South China, Part Ⅰ:Geological and Geochemical Characterization.International Geology Review, 57(3):1-22.doi: org/10.1080/00206814.2015.1004200.

Tan, J.Q., Weniger, P., Krooss, B., et al., 2014.Shale Gas Potential of the Major Marine Shale Formations in the Upper Yangtze Platform, South China, Part Ⅱ:Methane Sorption Capacity.Fuel, 129:204-218.doi: 10.1016/j.fuel.2014.03.064

Tian, H., Pan, L., Xiao, X.M., et al., 2013.A Preliminary Study on the Pore Characterization of Lower Silurian Black Shales in the Chuandong Thrust Fold Belt, Southwestern China Using Low Pressure N₂ Adsorption and FE-SEM Methods.Marine and Petroleum Geology, 48:8-19.doi:org/ 10.1016/j.marpetgeo.2013.07.008

Tian, H., Pan, L., Zhang, T.W., et al., 2015.Pore Characterization of Organic-Rich Lower Cambrian Shales in Qiannan Depression of Guizhou Province, Southwestern China.Marine and Petroleum Geology, 62:28-43.doi: 10.1016/j.marpetgeo.2015.01.004

Wang, P.F., Jiang, Z.X., Ji, W.M., et al., 2016.Heterogeneity of Intergranular, Intraparticle and Organic Pores in Longmaxi Shale in Sichuan Basin, South China:Evidence from SEM Digital Images and Fractal and Multifractal Geometries.Marine and Petroleum Geology, 72:122-138.doi: 10.1016/j.marpetgeo.2016.01.020

Wu, C.J., Zhang, M.F., Ma, W.Y., et al., 2014.Organic Matter Characteristic and Sedimentary Environment of the Lower Cambrian Niutitang Shale in Southeastern Chongqing.Nature Gas Geosciences, 25(8):1267-1274 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-TDKX201408019.htm

Wu, K., Ma, Q.F., Feng, Q.L., 2012.Middle Permian Pore Characteristics and Shale Gas Exploration Significance from the Gufeng Formation in Jianshi, Western Hubei.Earth Science, 37(Suppl.2):175-183 (in Chinese with English abstract).

Wu, S.T., Zou, C.N., Zhu, R.K., et al., 2015.Reservoir Quality Characterization of Upper Triassic Chang 7 Shale in Ordos Basin.Earth Science, 40(11):1810-1823 (in Chinese with English abstract).

Xiao, Z.H., Wang, C.H., Yang, R.F., et al., 2013.Reservoir Conditions of Shale Gas in the Lower Cambrian Niutitang Formation, Northwestern Hunan.Acta Geologica Sinica, 87(10):1612-1623 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DZXE201310010.htm

Yang, F., Ning, Z.F., Zhang, S.D., et al., 2013.Characterization of Pore Structures in Shales through Nitrogen Adsorption Experiment.Natural Gas Industry, 33(4):135-140 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-TRQG201304031.htm

Yang, X., Jiang, Z.X., Song, Y., et al., 2016.A Comparative Study on Whole-Aperture Pore Structure Characteristics between Niutitang and Longmaxi Formation of High-Matruity Marine Shales in Southeastern Chongqing.Geological Journal of China Universities, 22(2):368-377 (in Chinese with English abstract).

Yang, Y.F., Wang, C.C., Yao, J., et al., 2016.A New Method for Microscopic Pore Structure Analysis in Shale Matrix.Earth Science, 41(6):1067-1073 (in Chinese with English abstract).

Yu, B.S., 2013.Classification and Characterization of Gas Shale Pore System.Earth Science Frontiers, 20(4):211-220 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DXQY201304020.htm

Yuan, Y., Jiang, Z.H., Yu, C., et al., 2016.Reservoir Characteristics of High Abundance and Low Thermal Stage Lacustrine Shale:An Example from the Middle Jurassic Shale in the Northern Qaidam Basin.Acta Geologica Sinica, 90(3):541-552 (in Chinese with English abstract). http://www.en.cnki.com.cn/Article_en/CJFDTotal-DZXE201603011.htm

Zhang, H., Shao, L., Zhang, G.C., et al., 2015.Distribution and Petroleum Geologic Significance of Eocene Marine Strata in the South China Sea.Earth Science, 40(4):660-670 (in Chinese with English abstract). https://www.researchgate.net/publication/281993837_Distribution_and_petroleum_geologic_significance_of_eocene_Marine_strata_in_the_South_China_Sea

Zhang, L.Y., Li, J.Y., Li, Z., 2015.Development Characteristics and Formation Mechanism of Intra-Organic Reservoir Space in Acustrine Shales.Earth Science, 40 (11):1824-1833 (in Chinese with English abstract). https://www.researchgate.net/publication/288230302_Development_characteristics_and_formation_mechanism_of_intra-organic_reservoir_space_in_lacustrine_shales

Zheng, L.J., Guan, D.F., Guo, X.W., et al., 2015.Key Geological Conditions Affecting Pyrolysis Experiments of Marine Source Rocks for Hydrocarbon Generation.Earth Science, 40(5):909-917 (in Chinese with English abstract). https://www.researchgate.net/publication/281687728_Key_geological_conditions_affecting_pyrolysis_experiments_of_marine_source_rocks_for_hydrocarbon_generation

韩双彪, 张金川, Horsfield, B., 等, 2013.页岩气储层孔隙类型及特征研究:以渝东南下古生界为例.地学前缘, 20(3): 247-253. http://www.cnki.com.cn/Article/CJFDTOTAL-DXQY201303030.htm

侯宇光, 何生, 易积正, 等, 2014.页岩孔隙结构对甲烷吸附能力的影响.石油勘探与开发, 41(2): 248-256. doi: 10.11698/PED.2014.02.17

胡明毅, 邓庆杰, 胡忠贵, 2014.上扬子地区下寒武统牛蹄塘组页岩气成藏条件.石油与天然气地质, 35(2): 272-279. http://www.cnki.com.cn/Article/CJFDTOTAL-SYYT201402018.htm

纪文明, 宋岩, 姜振学, 等, 2016.四川盆地东南部龙马溪组页岩微-纳米孔隙结构特征及控制因素.石油学报, 37(02): 182-195. http://www.cnki.com.cn/Article/CJFDTOTAL-SYXB201602004.htm

贾承造, 郑民, 张永峰, 2012.中国非常规油气资源与勘探开发前景.石油勘探与开发, 39(2): 129-136. http://www.cnki.com.cn/Article/CJFDTOTAL-SKYK201202002.htm

焦淑静, 韩辉, 翁庆萍, 等, 2012.页岩孔隙结构扫描电镜分析方法研究.电子显微学报, 31(5): 432-436. http://www.cnki.com.cn/Article/CJFDTOTAL-SHJS201607150.htm

林拓, 张金川, 李博, 等, 2014.湘西北常页1井下寒武统牛蹄塘组页岩气聚集条件及含气特征.石油学报, 35(5): 839-846. doi: 10.7623/syxb201405003

吴陈君, 张明峰, 马万云, 等, 2014.渝东南牛蹄塘组页岩有机质特征及沉积环境研究.天然气地球科学, 25(8): 1267-1274. http://www.cnki.com.cn/Article/CJFDTOTAL-TDKX201408019.htm

吴勘, 马强分, 冯庆来, 2012.鄂西建始中二叠世孤峰组孔隙特征及页岩气勘探意义.地球科学, 37(增刊2): 175-183. http://www.cnki.com.cn/Article/CJFDTOTAL-DQKX2012S2024.htm

吴松涛, 邹才能, 朱如凯, 等, 2015.鄂尔多斯盆地上三叠统长7段泥页岩储集性能.地球科学, 40(11): 1810-1823. http://www.earth-science.net/WebPage/Article.aspx?id=3188

肖正辉, 王朝晖, 杨荣丰, 等, 2013.湘西北下寒武统牛蹄塘组页岩气储集条件研究.地质学报, 87(10): 1612-1623. http://www.cnki.com.cn/Article/CJFDTOTAL-DZXE201310010.htm

杨峰, 宁正福, 张世栋, 等, 2013.基于氮气吸附实验的页岩孔隙结构表征.天然气工业, 33(4): 135-140. doi: 10.3787/j.issn.1000-0976.2013.04.025

杨潇, 姜振学, 宋岩, 等, 2016.渝东南牛蹄塘组与龙马溪组高演化海相页岩全孔径孔隙结构特征对比研究.高校地质学报, 22(2): 368-377. http://www.cnki.com.cn/Article/CJFDTOTAL-GXDX201602017.htm

杨永飞, 王晨晨, 姚军, 等, 2016.页岩基质微观孔隙结构分析新方法.地球科学, 41(6): 1067-1073. doi: 10.11764/j.issn.1672-1926.2016.06.1067

于炳松, 2013.页岩气储层孔隙分类与表征.地学前缘, 20(4): 211-220. http://www.cnki.com.cn/Article/CJFDTOTAL-DXQY201304020.htm

原园, 姜振学, 喻宸, 等, 2016.高丰度低演化程度湖相页岩储层特征——以柴达木盆地北缘中侏罗统为例.地质学报, 90(3): 541-552. http://www.cnki.com.cn/Article/CJFDTOTAL-DZXE201603011.htm

张浩, 邵磊, 张功成, 等, 2015.海始新世海相地层分布及油气地质意义.地球科学, 40(4): 660-670. http://www.earth-science.net/WebPage/Article.aspx?id=3076

张林晔, 李钜源, 李政, 2015.湖相页岩有机储集空间发育特点与成因机制.地球科学, 40(11): 1824-1833. http://www.earth-science.net/WebPage/Article.aspx?id=3189

郑伦举, 关德范, 郭小文, 等, 2015.影响海相烃源岩热解生烃过程的地质条件.地球科学, 40(5): 909-917. http://www.earth-science.net/WebPage/Article.aspx?id=3091

Relative Articles

Supplements(0)

Cited By

Proportional views

Proportional views

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Figures(9) / Tables(2)

Get Citation

PDF

XML

Article views (5062) PDF downloads(50)

Micro-Nano Pore Structure Characteristics in the Lower Cambrian Niutitang Shale, Northeast Chongqing

doi: 10.3799/dqkx.2017.093

Abstract

References

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Proportional views

Export File

Citation

Format

Content