• 中国出版政府奖提名奖

    中国百强科技报刊

    湖北出版政府奖

    中国高校百佳科技期刊

    中国最美期刊

    Volume 45 Issue 4
    Apr.  2020
    Turn off MathJax
    Article Contents
    Jiang Suhui, Wang Zhimin, Chen Renxu, Zheng Yongfei, Zhu Lin, 2020. Water of Garnet in Eclogite from Jinheqiao Area in the Dabie Orogen. Earth Science, 45(4): 1168-1186. doi: 10.3799/dqkx.2019.132
    Citation: Jiang Suhui, Wang Zhimin, Chen Renxu, Zheng Yongfei, Zhu Lin, 2020. Water of Garnet in Eclogite from Jinheqiao Area in the Dabie Orogen. Earth Science, 45(4): 1168-1186. doi: 10.3799/dqkx.2019.132

    Water of Garnet in Eclogite from Jinheqiao Area in the Dabie Orogen

    doi: 10.3799/dqkx.2019.132
    • Received Date: 2019-06-03
    • Publish Date: 2020-04-15
    • Nominally anhydrous minerals (NAMs) are major components of the subducted continental slab and thus regarded as important water reservoir in continental subduction zone. The water contents of NAMs are critical for understanding of fluid action and geodynamics of subduction zones. In this study,Fourier Transform Infrared Spectroscopy (FTIR) as well as major and trace element analyses were carried out on garnets in Jinheqiao eclogites from the Dabie orogen. The results demonstrate that garnet grains contain molecular water and hydroxyl (OH) with the contents of < 1×10-6 to 1 946×10-6 and < 1×10-6 to 1 347×10-6,respectively. Contents of hydroxyl are positively correlated with Ca,Na,Ti,Zr and Pr,but negatively correlated with Si for garnets in most samples,indicating that the incorporation of OH in garnet is dominated by hydrogarnet substitution. Molecular water is primary or transformed from hydroxyl during exhumation,implying molecular water an internal origin in eclogite. Garnet has total water contents varying from < 1×10-6 to 3 293×10-6,with the highest water content corresponding to the garnet's capacity for water storage under peak UHP metamorphism. Water can be saturated in peak metamorphic garnet. The variable water contents in garnet have been controlled by several factors including protolith nature,fluid availability,pressure and temperature,which however,have been dominated by decompression dehydration during exhumation. Garnets in the Jinheqiao eclogites have average total water contents ranging from 749×10-6 to 1 164×10-6,suggesting that they have similar capacity for water storage as omphacite and thus are important media for subducted slab to transport water into deep mantle.

       

    • loading
    • An, S.C., Li, S.G., Liu, Z., et al., 2018. Modification of the Sm-Nd Isotopic System in Garnet Induced by Retrogressive Fluids. Journal of Metamorphic Geology, 36(8): 1039-1048.https://doi.org/10.1111/jmg.12426
      Bell, D.R., Ihinger, P.D., Rossman, G.R., 1995. Quantitative Analysis of Trace OH in Garnet and Pyroxenes. American Mineralogist, 80(5-6): 465-474.https://doi.org/10.2138/am-1995-5-607
      Bell, D.R., Rossman, G.R., 1992a. The Distribution of Hydroxyl in Garnets from the Subcontinental Mantle of Southern Africa. Contributions to Mineralogy and Petrology, 111(2): 161-178.https://doi.org/10.1007/bf00348949
      Bell, D.R., Rossman, G.R., 1992b. Water in Earth's Mantle: The Role of Nominally Anhydrous Minerals. Science, 255(5050): 1391-1397.https://doi.org/10.1126/science.255.5050.1391
      Chen, R.X., Zheng, Y.F., Gong, B., 2011. Mineral Hydrogen Isotopes and Water Contents in Ultrahigh-Pressure Metabasite and Metagranite: Constraints on Fluid Flow during Continental Subduction-Zone Metamorphism. Chemical Geology, 281(1-2): 103-124.https://doi.org/10.1016/j.gca.2007.02.012
      Chen, Y.X., Zhou, K., Zheng, Y.F., et al., 2015. Garnet Geochemistry Records the Action of Metamorphic Fluids in Ultrahigh-Pressure Dioritic Gneiss from the Sulu Orogen. Chemical Geology, 398: 46-60. https://doi.org/10.1016/j.chemgeo.2015.01.021
      Demouchy, S., Bolfan-Casanova, N., 2016. Distribution and Transport of Hydrogen in the Lithospheric Mantle: A Review. Lithos, 240-243: 402-425.https://doi.org/10.1016/j.lithos.2015.11.012
      Gao, X.Y., Zheng, Y.F., Chen, Y.X., 2011. U-Pb Ages and Trace Elements in Metamorphic Zircon and Titanite from UHP Eclogite in the Dabie Orogen: Constraints on P-T-t Path. Journal of Metamorphic Geology, 29(7): 721-740.https://doi.org/10.1111/j.1525-1314.2011.00938.x
      Geiger, C.A., Stahl, A., Rossman, G.R., 2000. Single-Crystal IR- and UV/VIS-Spectroscopic Measurements on Transition-Metal-Bearing Pyrope: The Incorporation of Hydroxide in Garnet. European Journal of Mineralogy, 12(2): 259-271. https://doi.org/10.1127/0935-1221/2000/0012-0259
      Gose, J., Schmädicke, E., 2018. Water Incorporation in Garnet: Coesite versus Quartz Eclogite from Erzgebirge and Fichtelgebirge. Journal of Petrology, 59(2): 207-232.https://doi.org/10.1093/petrology/egy022
      Katayama, I., Nakashima, S., Yurimoto, H., 2006. Water Content in Natural Eclogite and Implication for Water Transport into the Deep Upper Mantle. Lithos, 86(3-4): 245-259.https://doi.org/10.1016/j.lithos.2005.06.006
      Koch-Müller, M., Matsyuk, S.S., Wirth, R., 2004. Hydroxyl in Omphacites and Omphacitic Clinopyroxenes of Upper Mantle to Lower Crustal Origin beneath the Siberian Platform. American Mineralogist, 89(7): 921-931. https://doi.org/10.2138/am-2004-0701
      Li, Q. L., Li, S. G., Zheng, Y.F., et al., 2003. A High Precision U-Pb Age of Metamorphic Rutile in Coesite-Bearing Eclogite from the Dabie Mountains in Central China: A New Constraint on the Cooling History. Chemical Geology, 200(3-4): 255-265. https://doi.org/10.1016/s0009-2541(03)00194-3
      Li, Q. L., Li, S. G., Zheng, Y. F., et al., 2003. O-Nd-Pb Isotopic Systems in Eclogite Minerals at Jinheqiao in Dabieshan and Constraints on Their Relative Diffusivity. Geological Journal of China Universities, 9(2):218-226 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=gxdzxb200302007
      Li, Z.H., Yang, S.T., Liu, M.Q., et al., 2019. Aqueous Fluid Activity and Its Effects in the Subduction Zones:A Systematic Numerical Modelling Study. Earth Science, 44(12):3984-3992(in Chinese with English abstract). https://www.sciencedirect.com/science/article/pii/S0264370711000664
      Lin, W., Shi, Y. H., Wang, Q. C., 2009. Exhumation Tectonics of the HP-UHP Orogenic Belt in Eastern China: New Structural-Petrological Insights from the Tongcheng Massif, Eastern Dabieshan. Lithos, 109(3-4): 285-303. https://doi.org/10.1016/j.lithos.2008.10.007
      Liu, F.L., Xu, Z.Q., Liou, J.G., 2004. Tracing the Boundary between UHP and HP Metamorphic Belts in the Southwestern Sulu Terrane, Eastern China: Evidence from Mineral Inclusions in Zircons from Metamorphic Rocks. International Geology Review, 46(5): 409-425. https://doi.org/10.2747/0020-6814.46.5.409
      Liu, X.W., Xie, Z.J., Wang, L., et al., 2016. Water Incorporation in Garnets from Ultrahigh Pressure Eclogites at Shuanghe, Dabieshan. Mineralogical Magazine, 80(6): 959-975.https://doi.org/10.1180/minmag.2016.080.034
      Liu, Y.S., Hu, Z.C., Gao, S., et al., 2008. In Situ Analysis of Major and Trace Elements of Anhydrous Minerals by LA-ICP-MS without Applying an Internal Standard. Chemical Geology, 257(1-2): 34-43.https://doi.org/10.1016/j.chemgeo.2008.08.004
      Lu, R., Keppler, H., 1997. Water Solubility in Pyrope to 100 kbar. Contributions to Mineralogy and Petrology, 129(1): 35-42.https://doi.org/10.1007/s004100050321
      Maldener, J., Hosch, A., Langer, K., et al., 2003. Hydrogen in Some Natural Garnets Studied by Nuclear Reaction Analysis and Vibrational Spectroscopy. Physics and Chemistry of Minerals, 30(6): 337-344.https://doi.org/10.1007/s00269-003-0321-7
      Matsyuk, S. S., Langer, K., Hösch, A., 1998. Hydroxyl Defects in Garnets from Mantle Xenoliths in Kimberlites of the Siberian Platform. Contributions to Mineralogy and Petrology, 132(2): 163-179. https://doi.org/10.1007/s004100050414
      Mookherjee, M., Karato, S. I., 2010. Solubility of Water in Pyrope-Rich Garnet at High Pressures and Temperature. Geophysical Research Letters, 37(3): L03310. https://doi.org/10.1029/2009gl041289
      Schmädicke, E., Gose, J., 2017. Water Transport by Subduction: Clues from Garnet of Erzgebirge UHP Eclogite. American Mineralogist, 102(5): 975-986. https://doi.org/10.2138/am-2017-5920
      Sheng, Y.M., Xia, Q.K., Dallai, L., et al., 2007. H2O Contents and D/H Ratios of Nominally Anhydrous Minerals from Ultrahigh-Pressure Eclogites of the Dabie Orogen, Eastern China. Geochimica et Cosmochimica Acta, 71(8): 2079-2103.https://doi.org/10.1016/j.gca.2007.01.018
      Shi, Y.H., Wang, Q.C., 2006. Variation in Peak P-T Conditions across the Upper Contact of the UHP Terrane, Dabieshan, China: Gradational or Abrupt?. Journal of Metamorphic Geology, 24(9): 803-822. https://doi.org/10.1111/j.1525-1314.2006.00670.x
      Su, W., You, Z. D., Cong, B. L., et al., 2002. Cluster of Water Molecules in Garnet from Ultrahigh-Pressure Eclogite. Geology, 30(7): 611-614. https://doi.org/10.1130/0091-7613(2002)030<0611:cowmig>2.0.co;2
      Sun, S. S., McDonough, W.F., 1989. Chemical and Isotopic Systematics of Oceanic Basalts: Implications for Mantle Composition and Processes. Geological Society, London, Special Publications, 42(1): 313-345. https://doi.org/10.1144/gsl.sp.1989.042.01.19
      Wang, L.P., Zhang, Y.X., Essene, E.J., 1996. Diffusion of the Hydrous Component in Pyrope. American Mineralogist, 81(5-6): 706-718. https://doi.org/10.2138/am-1996-5-618
      Wang, L., Wang, S.J., Brown, M., et al., 2017. On the Survival of Intergranular Coesite in UHP Eclogite. Journal of Metamorphic Geology, 36(2): 173-194.https://doi.org/10.1111/jmg.12288
      Wei, C.J., Qian, J.H., Tian, Z.L., 2013. Metamorphic Evolution of Medium-Temperature Ultra-High Pressure (MT-UHP) Eclogites from the South Dabie Orogen, Central China: An Insight from Phase Equilibria Modeling. Journal of Metamorphic Geology, 31(7): 755-774.https://doi.org/10.1111/jmg.12043
      Withers, A.C., Wood, B.J., Carroll, M.R., 1998. The OH Content of Pyrope at High Pressure. Chemical Geology, 147(1), 161-171.https://doi.org/10.1016/S0009-2541(97)00179-4
      Wu, Y.N., Wang, Y.F., 2018. An FTIR Study of Kyanite in the Maobei Kyanite-Bearing Eclogites from the Sulu Orogenic Belt, Eastern China. Journal of Earth Science, 29(1): 21-29.https://doi.org/10.1007/s12583-017-0774-0
      Xia, Q.K., Cheng, H., Liu, J., et al., 2017.The Distribution of the Early Cretaceous Hydrous Lithospheric Mantle in the North China Craton:Constraints from Water Content in Peridotites of Tietonggou.Earth Science, 42(6):853-861(in Chinese with English abstract). https://www.nature.com/articles/ncomms8700
      Xia, Q.K., Liu, J., Kovács, I., et al., 2019. Water in the Upper Mantle and Deep Crust of Eastern China:Concentration, Distribution and Implications. National Science Review, 6(1):125-144. doi: 10.1093/nsr/nwx016
      Xia, Q.K., Sheng, Y.M., Yang, X.Z., et al., 2005. Heterogeneity of Water in Garnets from UHP Eclogites, Eastern Dabieshan, China. Chemical Geology, 224(4): 237-246. https://doi.org/10.1016/j.chemgeo.2005.08.003
      Xiao, Y. L., Hoefs, J., van den Kerkhof, A.M., et al., 2000. Fluid History of UHP Metamorphism in Dabie Shan, China: A Fluid Inclusion and Oxygen Isotope Study on the Coesite-Bearing Eclogite from Bixiling. Contributions to Mineralogy and Petrology, 139(1): 1-16.https://doi.org/10.1007/s004100050570
      Zheng, Y.F., 2009. Fluid Regime in Continental Subduction Zones: Petrological Insights from Ultrahigh-Pressure Metamorphic Rocks. Journal of the Geological Society, 166(4): 763-782.https://doi.org/10.1144/0016-76492008-016r
      Zheng, Y.F., Chen, R.X., Xu, Z., et al., 2016. The Transport of Water in Subduction Zones. Science China:Earth Sciences, 46(3):253-286(in Chinese). http://d.old.wanfangdata.com.cn/OAPaper/oai_pubmedcentral.nih.gov_3637742
      Zheng, Y.F., Chen, R. X., Zhao, Z. F., 2009. Chemical Geodynamics of Continental Subduction-Zone Metamorphism: Insights from Studies of the Chinese Continental Scientific Drilling (CCSD) Core Samples. Tectonophysics, 475(2): 327-358.https://doi.org/10.1016/j.tecto.2008.09.014
      Zheng, Y.F., Chen, Y.X., 2019. Crust-Mantle Interaction in Continental Subduction Zones. Earth Science, 44(12):3961-3983 (in Chinese with English abstract). http://d.old.wanfangdata.com.cn/Periodical/dqkx201912001
      Zheng, Y.F., Fu, B., Gong, B., et al., 2003. Stable Isotope Geochemistry of Ultrahigh Pressure Metamorphic Rocks from the Dabie-Sulu Orogen in China: Implications for Geodynamics and Fluid Regime. Earth-Science Reviews, 62(1-2): 105-161.https://doi.org/10.1016/s0012-8252(02)00133-2
      Zheng, Y.F., Hermann, J., 2014. Geochemistry of Continental Subduction-Zone Fluids. Earth, Planets and Space, 66(1): 93.https://doi.org/10.1186/1880-5981-66-93
      李秋立, 李曙光, 郑永飞, 等, 2003.大别山金河桥榴辉岩矿物O-Nd-Pb同位素体系及其对扩散速率的制约.高校地质学报, 9(2):218-226. doi: 10.3969/j.issn.1006-7493.2003.02.007
      李忠海, 杨舒婷, 刘明启, 等, 2019.板块俯冲水流体活动及其效应的定量化数值模拟.地球科学, 44(12):3984-3992. doi: 10.3799/dqkx.2019.232?viewType=HTML
      夏群科, 程徽, 刘佳, 等, 2017.山东铁铜沟橄榄岩的水含量:华北克拉通早白垩世富水岩石圈的分布.地球科学, 42(6):853-861. http://d.old.wanfangdata.com.cn/Periodical/dqkx201706001
      郑永飞, 陈仁旭, 徐峥, 等, 2016.俯冲带中的水迁移.中国科学:地球科学, 46(3):253-286. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgkx-cd201603001
      郑永飞, 陈伊翔, 2019.大陆俯冲带壳幔相互作用.地球科学, 44(12):3961-3983. http://d.old.wanfangdata.com.cn/Periodical/dqkx201912001
    • dqkx-45-4-1168-Table1-2.pdf
    • 加载中

    Catalog

      通讯作者: 陈斌, bchen63@163.com
      • 1. 

        沈阳化工大学材料科学与工程学院 沈阳 110142

      1. 本站搜索
      2. 百度学术搜索
      3. 万方数据库搜索
      4. CNKI搜索

      Figures(12)  / Tables(2)

      Article views (2461) PDF downloads(65) Cited by()
      Proportional views

      /

      DownLoad:  Full-Size Img  PowerPoint
      Return
      Return