炼油污染场地地下水DOM三维荧光指纹特征及指示意义

李小倩; 刘鋆; 何宁洁; 宋晓东; 邢新丽; 刘运德

doi:10.3799/dqkx.2022.473

Volume 49 Issue 6

Jun. 2024

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Article Navigation > Earth Science > 2024 > 49(6): 2199-2212

Li Xiaoqian, Liu Yun, He Ningjie, Song Xiaodong, Xing Xinli, Liu Yunde, 2024. Fluorescence Excitation-Emission Matrix Characteristics and Implication of Dissolved Organic Matter in Groundwater at a Typical Refinery-Polluted Site. Earth Science, 49(6): 2199-2212. doi: 10.3799/dqkx.2022.473

Citation:

Li Xiaoqian, Liu Yun, He Ningjie, Song Xiaodong, Xing Xinli, Liu Yunde, 2024. Fluorescence Excitation-Emission Matrix Characteristics and Implication of Dissolved Organic Matter in Groundwater at a Typical Refinery-Polluted Site. Earth Science, 49(6): 2199-2212. doi: 10.3799/dqkx.2022.473

Citation:

Li Xiaoqian, Liu Yun, He Ningjie, Song Xiaodong, Xing Xinli, Liu Yunde, 2024. Fluorescence Excitation-Emission Matrix Characteristics and Implication of Dissolved Organic Matter in Groundwater at a Typical Refinery-Polluted Site. Earth Science, 49(6): 2199-2212. doi: 10.3799/dqkx.2022.473

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Fluorescence Excitation-Emission Matrix Characteristics and Implication of Dissolved Organic Matter in Groundwater at a Typical Refinery-Polluted Site

doi: 10.3799/dqkx.2022.473

Li Xiaoqian^{1, 2, 3
,
,},
Liu Yun⁴,
He Ningjie¹,
Song Xiaodong¹,
Xing Xinli^{1, 3},
Liu Yunde^{1, 2, 3}

1.
School of Environmental Studies, China University of Geosciences, Wuhan 430078, China
2.
State Key Laboratory of Water Pollution Traceability and Control for Environmental Protection, Wuhan 430078, China
3.
State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Wuhan 430078, China
4.
Institute of Geological Survey, China University of Geosciences, Wuhan 430074, China

Received Date: 2022-08-22
Available Online: 2024-07-11
Publish Date: 2024-06-25

Abstract

Abstract

The excitation-emission matrix (EEMs) fluorescence spectroscopy of dissolved organic matter (DOM) has been widely used in monitoring and warning of water pollution. To clarify the indicator of EEMs fluorescence fingerprint on groundwater organic pollution at refinery sites, the EEMs characteristics of DOM and spatial distribution of organic pollution in groundwater was studied at a typical refinery-polluted site by EEMs regional integration, correlation analysis and hierarchical clustering. The EEMs results show that DOM in groundwater of the polluted site had significant fluorescence spectral fingerprint as oil contaminants. The constituents of DOM in the polluted groundwater were quantified by EMMs regional integration based on fluorescence of model compounds. The normalized volumetric integration of regions Ⅰ and Ⅱ representing benzene series and petroleum hydrocarbons accounts for 55%-88% of the total volumetric integration of all regions, which is consistent with GC-MS results of organic compositions. The hierarchical clustering on the similarity of EEMs can effectively distinguish the types of groundwater organic pollution and their spatial distribution in the polluted site. The correlation analyses between normalized volumetric integration of EEMs regions and organic components, spectra parameters and water chemistry further suggest that the fluorescence EEMs fingerprint of DOM can effectively reveal organic pollution and effect on geochemistry of groundwater at the refinery site, indicating as an effective tracer to monitor and warn groundwater organic pollution.

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