多重环境因素对Fe<sup>2+</sup>作用下化学反硝化去除亚硝的影响

李林鑫; 蒋宏忱; 黄柳琴

doi:10.3799/dqkx.2023.060

Volume 49 Issue 8

Aug. 2024

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Article Navigation > Earth Science > 2024 > 49(8): 2891-2900

Li Linxin, Jiang Hongchen, Huang Liuqin, 2024. Multiple Environmental Factors Affect the Nitrite Removal Efficiency of Chemo-Denitrification by Fe2+. Earth Science, 49(8): 2891-2900. doi: 10.3799/dqkx.2023.060

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Li Linxin, Jiang Hongchen, Huang Liuqin, 2024. Multiple Environmental Factors Affect the Nitrite Removal Efficiency of Chemo-Denitrification by Fe²⁺. Earth Science, 49(8): 2891-2900. doi: 10.3799/dqkx.2023.060

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Multiple Environmental Factors Affect the Nitrite Removal Efficiency of Chemo-Denitrification by Fe²⁺

doi: 10.3799/dqkx.2023.060

State Key Laboratory of Biogeology and Environmental Geology, China University of Geosciences, Wuhan 430074, China

Received Date: 2023-03-15
Available Online: 2024-08-27
Publish Date: 2024-08-25

Abstract

Abstract

To improve the efficiency of the NO₂^- removal process using Fe²⁺ as a reducing agent in practical applications, this research designed three environmental factors of exogenous anions, Fe²⁺ concentration, and reaction temperature to investigate their effects on the chemical reduction of NO₂^- by Fe²⁺. The results showed that although increasing the Fe²⁺ concentration could significantly promote the removal rate of NO₂^-, it also reduced the utilization rate of Fe²⁺. In addition, raising the temperature and adding HCO₃^-/CO₃^2- could both increase the removal rate and extent of NO₂^-. The type of by-product formed by iron oxidation was also regulated by temperature and HCO₃^-. At temperatures below 55 ℃ (such as 30 ℃ and 40 ℃), the by-product of iron oxidation was mainly goethite and magnetite. At temperatures above 55 ℃, Magnetite was the only by-product. But magnetite can be formed at a lower temperature (40 ℃) with HCO₃^-. These results provide experimental references for improving the application mode and by-product secondary treatment utilization of Fe²⁺-based Chemo-denitrification and provide theoretical basis in actual engineering.
- nitrite pollution,
- iron oxidation,
- Chemo-denitrification,
- high temperature,
- magnetite

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References(44)

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Multiple Environmental Factors Affect the Nitrite Removal Efficiency of Chemo-Denitrification by Fe2+

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Multiple Environmental Factors Affect the Nitrite Removal Efficiency of Chemo-Denitrification by Fe²⁺