玄武岩二氧化碳矿化封存（Ⅱ）：广东省雷州半岛的封存条件、选址和挑战

周蒂; 夏菖佑; 李鹏春; 梁希

doi:10.3799/dqkx.2024.103

Volume 50 Issue 2

Feb. 2025

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Zhou Di, Xia Changyou, Li Pengchun, Liang Xi, 2025. CO2 Mineralization Storage in Basalt (Ⅱ): Storage Conditions, Site Selections and Challenges on Leizhou Peninsula, Guangdong Province, South China. Earth Science, 50(2): 569-584. doi: 10.3799/dqkx.2024.103

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Zhou Di, Xia Changyou, Li Pengchun, Liang Xi, 2025. CO₂ Mineralization Storage in Basalt (Ⅱ): Storage Conditions, Site Selections and Challenges on Leizhou Peninsula, Guangdong Province, South China. Earth Science, 50(2): 569-584. doi: 10.3799/dqkx.2024.103

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CO₂ Mineralization Storage in Basalt (Ⅱ): Storage Conditions, Site Selections and Challenges on Leizhou Peninsula, Guangdong Province, South China

doi: 10.3799/dqkx.2024.103

Zhou Di^{1, 2
,
,},
Xia Changyou¹,
Li Pengchun^{1, 2},
Liang Xi^{1, 3}

1.
UK-China (Guangdong) CCUS Centre, Guangzhou 510440, China
2.
South China Sea Institute of Oceanology, Key Laboratory of Ocean and Marginal Sea Geology, Chinese Academy of Sciences, Guangzhou 510301, China
3.
University College London, London WC1E6BT, United Kingdom

Received Date: 2024-05-12
Available Online: 2025-02-26
Publish Date: 2025-02-25

Abstract

Abstract

CO₂ mineralization storage in basaltis a new CCUS technique that enables the sequestration of CO₂ in basaltic areas for carbon reduction. The Leizhou Peninsula in the Guangdong Province of South China boasts a vast area covered by basalt, exceeding 3 000 km².The basaltic formations on the Leizhou Peninsula consist primarily of tholeiite and alkali olivine basalts, making it a promising candidate for CO₂ mineralization storage. This paper analyzed the geological and hydrological conditions of the Leizhou Peninsular and pointed out that the Carbfix technology, which allows safe storage of CO₂ without caprocks, is applicable to the area, However, the basalts in the peninsular are mostly shallowly buried, and only volcanic crater basalts and deeply buried Tertiary basalts might meet the minimum depth requirements of the Carbfix technology. Currently, Xuwun County's Tianyang Quaternary caldera basalts and the Yongshi Farmland's Tertiary basalts have been identified as potential pilot project sites. The geological and hydrological conditions at these two sites are reviewed, and favorable and unfavorable factors and potential for CO₂ storage are analyzed. The primary challenges currently faced are to investigate the safety issues of large⁃quantity water injection into the caldera basalts, and to detect the deep basal interface and lateral extension of the basalts. Additionally, the potential impacts of injected CO₂⁃changed water on underground water resources need to be monitored and investigated. The article proposes to develop techniques of storing CO₂ in shallower (e.g. < 150 m) basalts, and suggests to conduct necessary experiments at a shore site to explore the feasibility and techniques of using seawater for basalt CO₂ storage. These actions will benefit not only expanding the potential of basalt mineralization storage on the Leizhou Peninsula, but also contributing to the study of utilizing global submarine basaltic carbon storage resources.
- CO₂ mineralization storage in basalt,
- carbon capture, use, and storage (CCUS),
- storage site selection,
- Carbfix technique,
- volcanics in Lei-Qiong areas,
- Leizhou Peninsular

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References

Aradóttir, E., Sonnenthal, E., Björnsson, G., et al., 2012. Multidimensional Reactive Transport Modeling of CO₂ Mineral Sequestration in Basalts at the Hellisheidi Geothermal Field, Iceland. International Journal of Greenhouse Gas Control, 9: 24-40. doi: 10.1016/j.ijggc.2012.02.006

Cao, X., Li, Q., Xu, L., Tan, Y., 2024a. Experiments of CO₂⁃Basalt⁃Fluid Interactions and Micromechanical Alterations: Implications for Carbon Mineralization. Energy & Fuels, 38(7): 6205-6214.

Cao, X., Li, Q., Xu, L. and Tan, Y., 2024b. A Review of in situ Carbon Mineralization in Basalt. Journal of Rock Mechanics and Geotechnical Engineering, 16(4): 1467-1485. https://doi.org/10.1016/j.jrmge.2023.11.010

Chen, J. R., 1990. Quaternary Geology of Tianyang Volcanic Lake in Guangdong Province. Geological Publishing House, Beijing(in Chinese)

Chen, M. X., Xia, S. G., Yang, S. Z., 1991. Local Geothermal Anomalies and Their Formation Mechanisms on Leizhou Peninsula, South China. Chinese Journal of Geology, 26(4): 369-383(in Chinese with English abstract).

Flaathen, T. K., Gislason, S. R., Oelkers, E. H. et al., 2009. Chemical Evolution of the Mt. Hekla, Iceland, Groundwaters: A Natural Analogue for CO₂ Sequestration in Basaltic Rocks. App. Geochem, 24: 463-474.

Gao, Z. H., Xia, C. Y., Liao, S. L., et al., 2023. Progress of Methods for Assessing CO₂ Mineralization Storage Potential in Basalt. Geological Journal of China Universities, 29(1): 66-75(in Chinese with English abstract).

Gislason, S. R., Oelkers, E. H., 2014. Carbon Storage in Basalt. Science, 344(6182): 373-374. https://doi.org/10.1126/science.1250828

Goldberg, D. S., Takahashi, T., Slagle, A. L., 2008. Carbon Dioxide Sequestration in Deep⁃Sea Basalt. Proceedings of the National Academy of Sciences of the United States of America, 105(29): 9920-9925. https://doi.org/10.1073/pnas.0804397105

Guangdong Geological Bureau, 1996. Stratigraphy(lithostratic) of Guangdong Province. China University of Geosciences Press, Wuhan(in Chinese).

Han, J. W., Xiong, X. L., Zhu, Z. Y., 2009. Geochemistry of Late⁃Cenozoic Basalts from Leiqiong area; The Origin of EM2 and the Contribution from Sub⁃Continental Lithosphere Mantle. Acta Petrologica Sinica, 25(12): 3208-3220(in Chinese with English abstract).

Ho, H. J., Iizuka, A., 2023. Mineral Carbonation Using Seawater for CO₂ Sequestration and Utilization: A Review. Separation and Purification Technology, 307: 122855. doi: 10.1016/j.seppur.2022.122855

Huang, Z. G., Cai, F. X., Han, Z. Y., 1993. Quaternary Volcano in Lei Qiong. Science Press, Beijing(in Chinese).

IEAGHG, 2011. Geological Storage of CO₂ in Basalts. 2011/TR2. IEA Greenhouse Gas R & D Programme, 18.

IEAGHG, 2017. Review of CO₂ Storage in Basalts. 2017-TR2. IEA Greenhouse Gas R & D Programme, 27.

Kong, Z. H., 2004. Hydrogeological Property and Laws of Water Abundance of the Volcanic Rocks in Leizhou Peninsula. Tropical Geography, 24(2): 136-139(in Chinese with English abstract). doi: 10.3969/j.issn.1001-5221.2004.02.009

Li, C., Li, Y., Zhu, W. H., et al., 2023. Carbon Dioxide Cured Building Materials as an Approach to Decarbonizing the Calcium Carbide Related Industry. Renewable and Sustainable Energy Reviews, 186: 113688. https://doi.org/10.1016/j.rser.2023.113688

Li, P. C., Jiang, J. L., Cheng, J. H., et al., 2023. Assessment of Carbon Dioxide Mineralization Sequestration Potential of Volcanic Rocks in Leizhou Peninsula, Guangdong Province, China. Geological Journal of China Universities, 29(1): 76-84(in Chinese with English abstract).

Li, W. L., Chen, J., Jia, L. X., et al., 2022a. Research Progress of CO₂ Geological Sequestration in Basalts. Geological Review, 68(2): 648-657(in Chinese with English abstract).

Li, W. L., Xu, J. J., Jia, L. X., et al., 2022b. Research Progress on Key Technologies of CO₂ Storage in Basalts. Hydrogeology & Engineering Geology, 49(3): 164-173(in Chinese with English abstract).

Li, X. Y., Chang, C., Yu, Q. C., 2013. Model of Basalt Dissolution Rate under CO₂ Mineral Sequestration Conditions. Geoscience, 27(6): 1477-1483(in Chinese with English abstract). doi: 10.3969/j.issn.1000-8527.2013.06.028

Luo, S. W., 1998. Volcanic Activity in Southern Leizhou Peninsula and Its Tectonic Setting. Guangdong Geology, (3): 20-24(in Chinese).

Marieni, C., Voigt, M., Clark, D. E., et al., 2021. Mineralization Potential of Water⁃Dissolved CO₂ and H₂S Injected into Basalts as Function of Temperature: Freshwater Versus Seawater. International Journal of Greenhouse Gas Control, 109: 103357. https://doi.org/10.1016/j.ijggc.2021.103357

Matter, J. M., Kelemen, P. B., 2009. Permanent Storage of Carbon Dioxide in Geological Reservoirs by Mineral Carbonation. Nature Geoscience, 2: 837-841. https://doi.org/10.1038/ngeo683

Matter, J. M., Stute, M., Snæbjörnsdottir, S. Ó., et al., 2016. Rapid Carbon Mineralization for Permanent Disposal of Anthropogenic Carbon Dioxide Emissions. Science, 352(6291): 1312-1314. https://doi.org/10.1126/science.aad8132

McGrail, B. P., Schaef, H. T., Ho, A. M., et al., 2006. Potential for Carbon Dioxide Sequestration in Flood Basalts. Journal of Geophysical Research: Solid Earth, 111(B12): 1-15.

McGrail, B. P., Spane, F. A., Amonette, J. E., et al., 2014. Injection and Monitoring at the Wallula Basalt Pilot Project. Energy Procedia, 63: 2939-2948. https://doi.org/10.1016/j.egypro.2014.11.316

Oelkers, E. H., Gislason, S. R., Matter, J., 2008. Mineral Carbonation of CO₂. Elements, 4(5): 333-337. doi: 10.2113/gselements.4.5.333

Olsson, J., Stipp, S. L. S., Makovicky, E., et al., 2014. Metal Scavenging by Calcium Carbonate at the Eyjafjallajökull Volcano: a Carbon Capture and Storage Analogue. Chemical Geology, 384: 135-148. https://doi.org/10.1016/j.chemgeo.2014.06.025

Pan, S. Y., Chung, T. C., Ho, C. C., et al., 2017. CO₂ Mineralization and Utilization Using Steel Slag for Establishing a Waste⁃to⁃Resource Supply Chain. Scientific Reports, 7(1): 17227. https://doi.org/10.1038/s41598⁃017⁃17648⁃9

Power, I. M., Dipple, G. M., Bradshaw, P. M. D., et al., 2020. Prospects for CO₂ Mineralization and Enhanced Weathering of Ultramafic Mine Tailings from the Baptiste Nickel Deposit in British Columbia, Canada. International Journal of Greenhouse Gas Control, 94: 102895. https://doi.org/10.1016/j.ijggc.2019.102895

Snæbjörnsdóttir, S. Ó., Sigfússon, B., Marieni, C., et al., 2020. Carbon Dioxide Storage through Mineral Carbonation. Nature Reviews Earth & Environment, 1: 90-102. https://doi.org/10.1038/s43017⁃019⁃0011⁃8

Snæbjörnsdóttir, S. Ó., Wiese, F., Fridriksson, T., et al., 2014. CO₂ Storage Potential of Basaltic Rocks in Iceland and the Oceanic Ridges. Energy Procedia, 63: 4585-4600. https://doi.org/10.1016/j.egypro.2014.11.491

Sui, S. Z., Wang, W. Y., 2003. The Discussion of the Bottom Age of TY2 Core from Paleo⁃Maar⁃Lake Tianyang, Guangdong Province. Quaternary Sciences, 23(2): 232(in Chinese with English abstract). doi: 10.3321/j.issn:1001-7410.2003.02.015

Sun, J. S., 1991. Cenozoic Volcanic Activity in the Northern South China Sea and Guangdong Coastal Area. Marine Geology & Quaternary Geology, 11(3): 45-67, 125-130(in Chinese with English abstract).

Wang, M., Lu, H. Y., 2019. Age, Geochemical Composition and Their Paleoclimatic Implications of the Basalt in Leizhou Peninsula, Southern China. Quaternary Sciences, 39(5): 1071-1082(in Chinese with English abstract).

Wen, H. H., 2013. Study on groundwater circulation law and rational development and utilization in Leizhou Peninsula(Dissertation). China University of Geosciences, Wuhan, 167(in Chinese with English abstract).

White, S. K., Spane, F. A., Todd Schaef, H., et al., 2020. Quantification of CO₂ Mineralization at the Wallula Basalt Pilot Project. Environmental Science & Technology, 54(22): 14609-14616. https://doi.org/10.1021/acs.est. 0c05142 doi: 10.1021/acs.est.0c05142

Wiese, F., Fridriksson, T., Ármannsson, H., 2008. CO₂ Fixation by Calcite in High⁃Temperature Geothermal Systems in Iceland, Iceland Geosurvey.

Wolff⁃Boenisch, D., 2011. On the Buffer Capacity of CO₂ ⁃Charged Seawater Used for Carbonation and Subsequent Mineral Sequestration. Energy Procedia, 4(C): 3738-3745

Wu, E. N., Chen, Q., Wang, S. W., et al., 2017. Study on CO₂ Storage Potential of Basalt Reservoir in Jiyang Depression. West⁃China Exploration Engineering, 29(12): 98-100(in Chinese with English abstract).

Wu, E. N., Wu, C. Z., Ji, J. F., et al., 2012. Potential Capacity and Feasibility of CO₂ Sequestration in Petroleum Reservoirs of Basaltic Rocks: Example from Basaltic Hydrocarbon Reservoir in the Xujiaweizi Fault Depression the Songliao Basin, East China. Geological Journal of China Universities, 18(2): 239-247(in Chinese with English abstract). doi: 10.3969/j.issn.1006-7493.2012.02.006

Yao, J. M., Zhou, X., Li, J., et al., 2007. Hydrogeochemical Characteristics and Evolution Simulation of Groundwater in Basalts on the Leizhou Peninsula, Guangdong, China. Geological Bulletin of China, 26(3): 327-334(in Chinese with English abstract). doi: 10.3969/j.issn.1671-2552.2007.03.010

Zhang, G. M., 1993. Characteristics and Enrichment Law of Volcanic Groundwater in Leizhou Peninsula. Guangdong Geology, (2): 1-13(in Chinese).

Zhang, L., Wen, R., Li, F., et al., 2023. Assessment of CO₂ Mineral Storage Potential in the Terrestrial Basalts of China. Fuel, 348: 128602. doi: 10.1016/j.fuel.2023.128602

Zhang, L., Wen, R. H., Geng, S. H., et al., 2022. Mineral Trapping of CO₂ in Basalt Rock: Progress and Key Issues. Journal of Chemical Engineering of Chinese Universities, 36(4): 473-480(in Chinese with English abstract). doi: 10.3969/j.issn.1003-9015.2022.04.002

Zhang, S. H., 2016. Conjunctive Use of Surface Water and Groundwater on Leizhou Peninsula. Guangxi Water Resources & Hydropower Engineering, (1): 1-5(in Chinese with English abstract). doi: 10.3969/j.issn.1003-1510.2016.01.001

Zhang, Z., Zhang, H. F., 2012. Carbonation of Mafic⁃Ultramafic Rocks: a New Approach to Carbon Dioxide Geological Sequestration. Earth Science, 37(1): 156-162(in Chinese with English abstract).

Zhou, D., Xia, C. Y., Li, PC., et al., 2024. CO₂ Mineral Storage in Basalt (Ⅰ): Technology and Application Conditions. Chinese Journal of Environmental Engineering, 18(10): 2708-2718(in Chinese with English abstract).

Zhou, Y. Q., 1990. Geological Characteristics and Development Prospect of Diatomite Deposit in Leizhou Peninsula. Guangdong Geology, (2): 22-27(in Chinese).

陈俊仁, 黄成彦, 林茂福, 等, 1990. 广东田洋火山湖第四纪地质. 北京: 地质出版社, 197.

陈墨香, 夏斯高, 杨淑贞, 1991. 雷州半岛局部地热异常及其形成机制. 地质科学, 26(4): 369-383.

高志豪, 夏菖佑, 廖松林, 等, 2023. 玄武岩CO₂矿化封存潜力评估方法研究现状及展望. 高校地质学报, 29(1): 66-75.

广东省地质矿产局, 1996. 广东省岩石地层. 武汉: 中国地质大学出版社, 171.

韩江伟, 熊小林, 朱照宇, 2009. 雷琼地区晚新生代玄武岩地球化学: EM2成分来源及大陆岩石圈地幔的贡献. 岩石学报, 25(12): 3208-3220.

黄镇国, 蔡福详, 韩中元, 等, 1993. 雷琼第四纪火山. 北京: 科学出版社, 281.

孔中恒, 2004. 雷州半岛火山岩的水文地质特征与富水规律. 热带地理, 24(2): 136-139.

李鹏春, 江静练, 程锦辉, 等, 2023. 广东雷州半岛火山岩二氧化碳矿化封存潜力评估. 高校地质学报, 29(1): 76-84.

李万伦, 陈晶, 贾凌霄, 等, 2022a. 玄武岩CO₂地质封存研究进展. 地质论评, 68(2): 648-657.

李万伦, 徐佳佳, 贾凌霄, 等, 2022b. 玄武岩封存CO₂技术方法及其进展. 水文地质工程地质, 49(3): 164-173.

李晓媛, 常春, 于青春, 2013. CO₂矿化封存条件下玄武岩溶解反应速率模型. 现代地质, 27(6): 1477-1483.

罗树文, 1998. 雷州半岛南部火山活动及其构造背景. 广东地质, 13(3): 20-24.

隋淑珍, 王文远, 2003. 广东田洋古玛珥湖TY2孔基底岩芯的年龄探讨. 第四纪研究, 23(2): 232.

孙嘉诗, 1991. 南海北部及广东沿海新生代火山活动. 海洋地质与第四纪地质, 11(3): 45-67, 125-130.

汪苗, 鹿化煜, 2019. 雷州半岛玛珥湖区玄武岩的年代、地球化学特征及其意义. 第四纪研究, 39(5): 1071-1082.

温汉辉, 2013. 雷州半岛地下水循环规律及合理开发利用研究(博士毕业论文). 武汉: 中国地质大学.

吾尔娜, 陈琦, 王世伟, 等, 2017. 济阳坳陷玄武岩油气藏储层的CO_2封存潜力研究. 西部探矿工程, 29(12): 98-100.

吾尔娜, 吴昌志, 季峻峰, 等, 2012. 松辽盆地徐家围子断陷玄武岩气藏储层的CO₂封存潜力研究. 高校地质学报, 18(2): 239-247.

姚锦梅, 周训, 李娟, 等, 2007. 广东雷州半岛玄武岩地下水水文地球化学特征及演化模拟. 地质通报, 26(3): 327-334.

张国梅, 1993. 雷州半岛火山岩地下水特征及其富集规律. 广东地质, (2): 1-13.

张亮, 温荣华, 耿松鹤, 等, 2022. CO₂在玄武岩中矿物封存研究进展及关键问题. 高校化学工程学报, 36(4): 473-480.

张胜华, 2016. 雷州半岛地表水与地下水联合利用浅析. 广西水利水电(1): 1-5.

张一驰, 2023. 腾讯启动碳寻计划, 投入过亿聚焦CCUS生态共建.

张舟, 张宏福, 2012. 基性、超基性岩: 二氧化碳地质封存的新途径. 地球科学, 37(1): 156-162. doi: 10.3799/dqkx.2012.015

周蒂, 夏菖佑, 李鹏春, 等, 2024. 玄武岩二氧化碳矿化封存(Ⅰ): 技术特点及适用条件. 环境工程学报, 18(10): 2708-2718

周永清, 1990. 雷州半岛硅藻土矿床地质特征和开发前景. 广东地质, 5(2): 22-27.

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CO2 Mineralization Storage in Basalt (Ⅱ): Storage Conditions, Site Selections and Challenges on Leizhou Peninsula, Guangdong Province, South China

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