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    Volume 51 Issue 2
    Feb.  2026
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    Zeng Xi, Fan Hongrui, Zou Xinyu, Zhu Yusheng, Huang Yongshu, Lan Jun, Li Xiaochun, 2026. Significance of Volatiles for Rare-Earth Mineralization: Insights from the Weishan and Xuezhuang Alkaline(-Carbonatite) Complexes, Shandong Province. Earth Science, 51(2): 462-476. doi: 10.3799/dqkx.2025.220
    Citation: Zeng Xi, Fan Hongrui, Zou Xinyu, Zhu Yusheng, Huang Yongshu, Lan Jun, Li Xiaochun, 2026. Significance of Volatiles for Rare-Earth Mineralization: Insights from the Weishan and Xuezhuang Alkaline(-Carbonatite) Complexes, Shandong Province. Earth Science, 51(2): 462-476. doi: 10.3799/dqkx.2025.220

    Significance of Volatiles for Rare-Earth Mineralization: Insights from the Weishan and Xuezhuang Alkaline(-Carbonatite) Complexes, Shandong Province

    doi: 10.3799/dqkx.2025.220
    • Received Date: 2025-04-23
    • Publish Date: 2026-02-25
    • Alkaline-carbonatite complexes host more than half of the world's rare-earth element (REE) resources. However, the key factors controlling REE fertility remain uncertain. In this study, we present petrography, whole-rock geochemistry, feldspar and apatite compositions, and Sr-Nd isotopes for the coeval Weishan and Xuezhuang alkaline (-carbonatite) complexes along the southeastern margin of the North China Craton. The Weishan complex is REE-mineralized, whereas the Xuezhuang complex is barren. Syenites from the two complexes show similar isotopic compositions, with (87Sr/86Sr)t = 0.707 297~0.709 173 and εNd(t)~+8.4, suggesting derivation from a common enriched lithospheric mantle source. In contrast, the Weishan complex contains more volatile-bearing minerals (fluorite, barite, apatite, and calcite) and displays distinct geochemical features, including lower CaO and P2O5 contents but higher Sr, Ba, Th, and U relative to Xuezhuang. Feldspar from Weishan shows lower Ca contents (lower anorthite component), and apatite has higher F contents. These mineralogical and geochemical differences indicate a higher volatile budget in the Weishan magma system, which promoted more advanced magmatic differentiation and ultimately facilitated REE mineralization.

       

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