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    Volume 51 Issue 6
    Jun.  2026
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    Article Contents
    Pan Tianshuo, Huang Xin, Chen Xi, Ping Xue, Sun Ronglin, 2026. Simulation of Nitrate Hydrologic Residence Time in a Hierarchical Groundwater Flow System of Sandy Basin and Implications from Management. Earth Science, 51(6): 2187-2200. doi: 10.3799/dqkx.2026.096
    Citation: Pan Tianshuo, Huang Xin, Chen Xi, Ping Xue, Sun Ronglin, 2026. Simulation of Nitrate Hydrologic Residence Time in a Hierarchical Groundwater Flow System of Sandy Basin and Implications from Management. Earth Science, 51(6): 2187-2200. doi: 10.3799/dqkx.2026.096

    Simulation of Nitrate Hydrologic Residence Time in a Hierarchical Groundwater Flow System of Sandy Basin and Implications from Management

    doi: 10.3799/dqkx.2026.096
    • Received Date: 2025-12-12
    • Publish Date: 2026-06-25
    • This study investigates the nitrate hydrologic residence time (NHRT) in a sandy, hierarchical groundwater flow system based on a 2D Tóth basin. Results show that with increasing groundwater recharge intensity, groundwater flow system evolves from a single regional system to nested systems, and finally to a single local flow system. The mean NHRT within the basin decreases across five distinct flow system patterns, but the proportion of longer-duration NHRT (250-500 a) remains dominant. Nitrate concentrations in discharge zones were primarily governed by adjacent local flow systems. A greater development depth of the local system prolongs NHRT in the discharge zone. Under nitrate input control scenarios, the baseline simulation (no input reduction) shows that concentrations in discharge zones stabilized within 2-8 years and then failed to decline. Compared to a gradual cessation, an immediate cessation of nitrate input accelerates recovery to background levels by only 4-6 years. The findings suggest that effective control of groundwater nitrate pollution requires either prioritizing input reduction in recharge areas of adjacent local flow systems or altering their development depth by regulating recharge intensity. Nevertheless, rapid cuts in nitrate loading do not substantially mitigate the inherent time lag of water quality response to remediation measures.

       

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    • Allard, M., World Health Organization, 1992. GEMS/WATER Operational Guide. Report GEMS/W. 92.1. National Water Research Institute, Burlington.
      Chen, D. J., Hu, M. P., Dahlgren, R. A., 2014. A Dynamic Watershed Model for Determining the Effects of Transient Storage on Nitrogen Export to Rivers. Water Resources Research, 50(10): 7714-7730. https://doi.org/10.1002/2014wr015852
      Chen, D. J., Shen, H., Hu, M. P., et al., 2018. Legacy Nutrient Dynamics at the Watershed Scale: Principles, Modeling, and Implications. Advances in Agronomy. Elsevier, Amsterdam, 237-313. https://doi.org/10.1016/bs.agron.2018.01.005
      Domenico, P. A., Schwartz, F. W., 1997. Physical and Chemical Hydrogeology. John Wiley Sons, New York.
      Erler, D. V., Shepherd, B. O., Linsley, B. K., et al., 2018. Coral Skeletons Record Increasing Agriculture-Related Groundwater Nitrogen Inputs to a South Pacific Reef over the Past Century. Geophysical Research Letters, 45(16): 8370-8378. https://doi.org/10.1029/2018gl078656
      Gao, J. B., Wang, S. M., Li, Z. Q., et al., 2021. High Nitrate Accumulation in the Vadose Zone after Land-Use Change from Croplands to Orchards. Environmental Science Technology, 55(9): 5782-5790. https://doi.org/10.1021/acs.est.0c06730
      Gelhar, L. W., Welty, C., Rehfeldt, K. R., 1992. A Critical Review of Data on Field-Scale Dispersion in Aquifers. Water Resources Research, 28(7): 1955-1974. https://doi.org/10.1029/92wr00607
      Goode, D. J., 1996. Direct Simulation of Groundwater Age. Water Resources Research, 32(2): 289-296. https://doi.org/10.1029/95wr03401
      Green, C. T., Jurgens, B. C., Zhang, Y., et al., 2016. Regional Oxygen Reduction and Denitrification Rates in Groundwater from Multi-Model Residence Time Distributions, San Joaquin Valley, USA. Journal of Hydrology, 543: 155-166. https://doi.org/10.1016/j.jhydrol.2016.05.018
      Gu, B. J., Ge, Y., Chang, S. X., et al., 2013. Nitrate in Groundwater of China: Sources and Driving Forces. Global Environmental Change, 23(5): 1112-1121. https://doi.org/10.1016/j.gloenvcha.2013.05.004
      Hu, M. P., 2019. Quantitative Study on Lag Effect of Watershed Non-Point Source Nitrogen Pollution (Disserattion). Zhejiang University, Hangzhou (in Chinese with English abstract).
      Jiang, X. W., Wan, L., Wang, X. S., et al., 2012. Distribution of Groundwater Age in Drainage Basins. Hydrogeology Engineering Geology, 39(4): 1-6(in Chinese with English abstract).
      Jiang, X. W., Wang, X. S., Wan, L., et al., 2011. An Analytical Study on Stagnation Points in Nested Flow Systems in Basins with Depth-Decaying Hydraulic Conductivity. Water Resources Research, 47: 2010WR009346. https://doi.org/10.1029/2010wr009346
      Kolbe, T., de Dreuzy, J. R., Abbott, B. W., et al., 2019. Stratification of Reactivity Determines Nitrate Removal in Groundwater. Proceedings of the National Academy of Sciences of the United States of America, 116(7): 2494-2499. https://doi.org/10.1073/pnas.1816892116
      Korom, S. F., 1992. Natural Denitrification in the Saturated Zone: A Review. Water Resources Research, 28(6): 1657-1668. https://doi.org/10.1029/92wr00252
      Liang, X., Quan, D. J., Jin, M. G., et al., 2013. Numerical Simulation of Groundwater Flow Patterns Using Flux as Upper Boundary. Hydrological Processes, 27(24): 3475-3483. https://doi.org/10.1002/hyp.9477
      Liu, C., Gong, X. L., Liang, Y., et al., 2025. Characteristics of Seasonal Changes in Organic Matter of Groundwater in Binhai, Jiangsu Province and Its Impact on Nitrogen Transport and Transformation. Earth Science, 50(6): 2400-2415(in Chinese with English abstract).
      Liu, H. W., Luan, H. A., Zhang, Y. T., et al., 2024. Research Progress on the Occurrence Characteristics of Nitrogen and Phosphorus Leaching in Dryland Farmland. Chinese Journal of Eco-Agriculture, 32(9): 1520-1533 (in Chinese with English abstract)
      Liu, Y. Y., Liu, C. X., Nelson, W. C., et al., 2017. Effect of Water Chemistry and Hydrodynamics on Nitrogen Transformation Activity and Microbial Community Functional Potential in Hyporheic Zone Sediment Columns. Environmental Science Technology, 51(9): 4877-4886. https://doi.org/10.1021/acs.est.6b05018
      McMahon, P. B., Böhlke, J. K., Kauffman, L. J., et al., 2008. Source and Transport Controls on the Movement of Nitrate to Public Supply Wells in Selected Principal Aquifers of the United States. Water Resources Research, 44(4): 2007WR006252. https://doi.org/10.1029/2007wr006252.
      Nian, G. Q., Chen, Z. H., Zhang, L. F., et al., 2020. Treatment of Two Boundary Conditions for Rainfall Infiltration in Slope and Its Application. Rock and Soil Mechanics, 41(12): 4105-4115 (in Chinese with English abstract).
      Peterson, M. E., Curtin, D., Thomas, S., et al., 2013. Denitrification in Vadose Zone Material Amended with Dissolved Organic Matter from Topsoil and Subsoil. Soil Biology and Biochemistry, 61: 96-104. https://doi.org/10.1016/j.soilbio.2013.02.010.
      Puckett, L. J., Tesoriero, A. J., Dubrovsky, N. M., 2011. Nitrogen Contamination of Surficial Aquifers—A Growing Legacy. Environmental Science Technology, 45(3): 839-844. https://doi.org/10.1021/es1038358.
      Quan, D. J., 2012. Analysis of Two-Dimension Groundwater Flow Patterns and Transformation Rules (Dissertation). China University of Geosciences (Wuhan), Wuhan(in Chinese with English abstract).
      Spalding, R. F., Exner, M. E., 1993. Occurrence of Nitrate in Groundwater: A Review. Journal of Environmental Quality, 22(3): 392-402. https://doi.org/10.2134/jeq1993.00472425002200030002x.
      Sun, R., 2018. Numerical Simulation of Coastal Nutrient Input Processes Using Transport-Reaction Numerical Model (Dissertation). China University of Geosciences (Beijing), Beijing (in Chinese with English abstract).
      Tang, J. H., 2023. Effects of Nitrogen Reduction Combined with Urease/Nitrification Inhibitors on Nitrogen Loss and Nitrogen Use Efficiency in Purple Soil-Wheat System (Dissertation). Sichuan Agricultural University, Chengdu (in Chinese with English abstract).
      Tóth, J., 1963. A Theoretical Analysis of Groundwater Flow in Small Drainage Basins. Journal of Geophysical Research, 68(16): 4795-4812. https://doi.org/10.1029/jz068i016p04795.
      Van Meter, K. J., Basu, N. B., 2017. Time Lags in Watershed-Scale Nutrient Transport: An Exploration of Dominant Controls. Environmental Research Letters, 12(8): 084017. https://doi.org/10.1088/1748-9326/aa7bf4
      Wang, J. L., Jin, M. G., Jia, B. J., et al., 2022. Numerical Investigation of Residence Time Distribution for the Characterization of Groundwater Flow System in Three Dimensions. Journal of Earth Science, 33(6): 1583-1600. https://doi.org/10.1007/s12583-022-1623-3
      Wang, J. Q., Ma, R., Sun, Z. Y., 2019. Reactive Transport and Model of Nitrogen Pollutants in the Surface Water-Ground Water Interaction Zones: A Review. Geological Science and Technology Information, 38(4): 270-280 (in Chinese with English abstract).
      Wang, J. Z., 2015. A Methodological Study on the Identification of Hierarchically Nested Groundwater Flow Systems in Drainage Basins (Dissertation). China University of Geosciences (Beijing), Beijing(in Chinese with English abstract).
      Wang, Y. A., Zhao, R. C., Ding, L., et al., 2025. Karst Trough Control of Solute Transport Processes at Two Karst Groundwater Flow Systems, Western Hubei, Central China. Journal of Earth Science, 36(4): 1731-1741. https://doi.org/10.1007/s12583-022-1665-6
      Wei, R. C., Tang, S. M., Wu, C. S., et al., 2020. Redox Zoning of Shallow Groundwater in Dongting Lake Region. China Environmental Science, 40(4): 1715-1722 (in Chinese with English abstract)
      Wentworth, C. K., 1922. A Scale of Grade and Class Terms for Clastic Sediments. The Journal of Geology, 30(5): 377-392. https://doi.org/10.1086/622910.
      Zhang, J., 2021. Hierarchically Nested Groundwater Flow System and Hydrological and Ecological Effects in the Northern Ordos Basin (Dissertation). Chang'an University, Xi'an(in Chinese with English abstract).
      Zhang, X. L., Jiao, J. J., 2023. Numerical Modelling Study on Non-Steady-State Groundwater Flow Systems in Response to Changing Rainfall. Bulletin of Geological Science and Technology, 42(4): 154-161, 169 (in Chinese with English abstract).
      胡敏鹏, 2019. 流域非点源氮污染的滞后效应定量研究(博士学位论文). 杭州: 浙江大学.
      蒋小伟, 万力, 王旭升, 等, 2012. 盆地地下水年龄空间分布规律. 水文地质工程地质, 39(4): 1-6.
      刘晨, 龚绪龙, 梁莹, 等, 2025. 江苏滨海地下水有机质季节变化特征及对氮迁移转化影响. 地球科学, 50(6): 2400-2415. doi: 10.3799/dqkx.2025.053
      刘瀚文, 栾好安, 张亦涛, 等, 2024. 旱地农田氮磷淋溶发生特征研究进展. 中国生态农业学报(中英文), 32(9): 1520-1533.
      年庚乾, 陈忠辉, 张凌凡, 等, 2020. 边坡降雨入渗问题中两种边界条件的处理及应用. 岩土力学, 41(12): 4105-4115.
      权董杰, 2012. 二维盆地地下水流模式与转化规律分析(硕士学位论文). 武汉: 中国地质大学(武汉).
      孙锐, 2018. 利用运移—反应数值模型模拟海岸带营养盐输入过程(硕士学位论文). 北京: 中国地质大学(北京).
      唐俊辉, 2023. 氮肥减量配施脲酶/硝化抑制剂对紫色土—小麦系统氮损失及利用效率的影响研究(硕士学位论文). 成都: 四川农业大学.
      王佳琪, 马瑞, 孙自永, 2019. 地表水与地下水相互作用带中氮素污染物的反应迁移机理及模型研究进展. 地质科技情报, 38(4): 270-280.
      王俊智, 2015. 盆地多级次地下水流系统识别方法研究(博士学位论文). 北京: 中国地质大学(北京).
      危润初, 唐仕明, 吴长山, 等, 2020. 洞庭湖区浅层地下水氧化还原分带规律. 中国环境科学, 40(4): 1715-1722.
      张俊, 2021. 鄂尔多斯高原多级嵌套地下水流系统形成演化及水文生态效应(博士学位论文). 西安: 长安大学.
      张萧琅, 焦赳赳, 2023. 非稳态地下水流系统响应降雨变化的数值模型研究. 地质科技通报, 42(4): 154-161, 169.
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