• 中国出版政府奖提名奖

    中国百强科技报刊

    湖北出版政府奖

    中国高校百佳科技期刊

    中国最美期刊

    Volume 28 Issue 3
    May  2003
    Turn off MathJax
    Article Contents
    HUANG Hai-ping, YANG Jie, Larter S R, 2003. Biodegradation Effect on Distributions of Multiple Methylated Naphthalenes in Reservoir Extracts. Earth Science, 28(3): 281-288.
    Citation: HUANG Hai-ping, YANG Jie, Larter S R, 2003. Biodegradation Effect on Distributions of Multiple Methylated Naphthalenes in Reservoir Extracts. Earth Science, 28(3): 281-288.

    Biodegradation Effect on Distributions of Multiple Methylated Naphthalenes in Reservoir Extracts

    • Received Date: 2002-06-15
    • Publish Date: 2003-05-25
    • Detailed geochemical analysis has been carried out on reservoir extracts from the Es 3 reservoir of the Leng 43 block of the Lengdong oilfield, Liaohe basin. Bulk compositions and aliphatic biomarker parameters indicate that these residual oils from three different oil columns are biodegraded at varying degrees. The biodegradation degree increases from the top of oil columns to the bottom of oil columns with excellent gredient variations. Comparison of the distributions of trimethylnaphthalenes (TMNs), tetramethylnaphthalenes (TeMNs) and pentamethylnaphthalenes (PMNs) at various biodegradation levels indicate that biodegradation controls their occurrence and distribution. The susceptibility of individual isomer of TMNs, TeMNs and PMNs to biodegradation has been determined on its relative abundance variation during biodegradation. The results show that these thermal dynamic stable structures are more susceptible to bacterial attack than these thermal unstable structures, suggesting biodegradation completely differs from thermal dynamic process. This study reveals that after moderate biodegradation these maturity parameters based on thermal stability of isomers are invalid and the ratios between easily biodegraded and refractory structures, in turn, can be used as new geochemical indicators to assess the degree of biodegradation.

       

    • loading
    • [1]
      Van Aarssen B G K, Bastow T P, Alexander R, et al. Distributions of methylated naphthalenes in crude oils: indicators of maturity, biodegradation and mixing[J]. Organic Geochemistry, 1999, 30: 1213-1227. doi: 10.1016/S0146-6380(99)00097-2
      [2]
      Bastow T P, Alexander R, Sosrowidjojo I B, et al. Pentamethylnaphthalenes and related compounds in sedimentary organic matter[J]. Organic Geochemistry, 1998, 28: 585-595. doi: 10.1016/S0146-6380(98)00018-7
      [3]
      Bastow T P, Alexander R, Fisher S J, et al. Geosynthesis of organic compounds. Part V—methylation of alkylnaphthalenes[J]. Organic Geochemistry, 2000, 31(6): 523534.
      [4]
      Alexander R, Kagi R I, Rowland S J, et al. The effects of thermal maturity on distribution of dimethylnaphthalenes and trimethylnaphthalenes in some ancient sediments and petroleums[J]. Geochimica et Cosmochimica Acta, 1985, 49: 385-395. doi: 10.1016/0016-7037(85)90031-6
      [5]
      Radke M, Rullkotter J, Vriend S P. Distribution of naphthalenes in crude oils from Java Sea: source and maturation effects[J]. Geochimica et Cosmochimica Acta, 1994, 58: 3675-3689. doi: 10.1016/0016-7037(94)90158-9
      [6]
      Radke M, Willsch H, Welte D H. Maturity parameters based on aromatic hydrocarbons: influence of the organic matter type[J]. Organic Geochemistry, 1986, 10: 5163.
      [7]
      Strachan M G, Alexander R, Kagi R I. Trimethylnaphthalenes in crude oils and sediments: effects of source and maturity[J]. Geochimica et Cosmochimica Acta, 1988, 52: 1255-1264. doi: 10.1016/0016-7037(88)90279-7
      [8]
      Volkman J K, Alexander R, Kagi R I, et al. Biodegradation of aromatic hydrocarbons in crude oils from the Barrow sub-basin of western Australia[J]. Organic Geochemistry, 1984, 6: 619-632. doi: 10.1016/0146-6380(84)90084-6
      [9]
      Connan J. Biodegradation of crude oils in reservoirs[A]. In: Brooks J, Welte D H, eds. Advances in petroleum geochemistry[C]. London: Academic Press, 1984. 299335.
      [10]
      Fisher S J, Alexander R, Kagi R I. Biodegradation of alkylnaphthalenes in sediment adjacent to an offshore petroleum production platform[J]. Polycyclic Aromatic Compounds, 1996, 11: 35-42. doi: 10.1080/10406639608544647
      [11]
      Ahmed M, Smith J W, George S C. Effects of biodegradation on Australian Permian coals[J]. Organic Geochemistry, 1999, 30(10): 1311-1322. doi: 10.1016/S0146-6380(99)00104-7
      [12]
      Widdel F, Rabus R. Anaerobic biodegradation of saturated and aromatic hydrocarbons[J]. Current Opinions in Biotechnology, 2001, 12: 259-276. doi: 10.1016/S0958-1669(00)00209-3
      [13]
      Huang H, Ren F, Larter S R. Influence of biodegradation on benzocarbazole distributionsin reservoired oils[J]. Chinese Science Bulletin, 2002, 47: 1734-1739.
      [14]
      Bennett B, Larter S R. Quantitative separation of aliphatic and aromatic hydrocarbons using silver ion-silica solid-phase extraction[J]. Analytical Chemistry, 2000, 72: 1039-1044. doi: 10.1021/ac9910482
      [15]
      Peters K E, Moldowan J M. The biomarker guide: interpreting molecular fossils in petroleum and ancient sediments[M]. Englewood Cliffs, NJ: Prentice Hall, 1993.
    • 加载中

    Catalog

      通讯作者: 陈斌, bchen63@163.com
      • 1. 

        沈阳化工大学材料科学与工程学院 沈阳 110142

      1. 本站搜索
      2. 百度学术搜索
      3. 万方数据库搜索
      4. CNKI搜索

      Figures(5)  / Tables(2)

      Article views (3920) PDF downloads(11) Cited by()
      Proportional views

      /

      DownLoad:  Full-Size Img  PowerPoint
      Return
      Return