超高压榴辉岩金红石中高场强元素变化的控制因素及其地球动力学意义

高长贵; 刘勇胜; 宗克清; 陈海红; 胡兆初

Volume 33 Issue 4

Jul. 2008

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Article Navigation > Earth Science > 2008 > 33(4): 487-503

GAO Zhang-gui, LIU Yong-sheng, ZONG Ke-qing, CHEN Hai-hong, HU Zhao-chu, 2008. Distributions and Geodynamic Implications of High Field Strength Elements in Rutile from Ultrahigh Pressure Eclogites. Earth Science, 33(4): 487-503.

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Distributions and Geodynamic Implications of High Field Strength Elements in Rutile from Ultrahigh Pressure Eclogites

State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, China

Received Date: 2007-10-29
Publish Date: 2008-07-25

Abstract

Abstract

Trace element compositions of rutiles in eclogites from the Chinese Continental Scientific Drilling (CCSD) main hole were analyzed using LA-ICP-MS.The results indicate that Nb and Ta contents of rutiles are significantly controlled by whole rock compositions, while Zr and Hf show no obvious dependence on the whole rock compositions.Coupled with enrichments of Pb and Sr at the rim of the interstitial rutiles, Zr contents decrease from the core to the rim.Nb/Ta ratios of rutiles are much higher than those of the parent eclogites.Moreover, Nb/Ta ratios of rutile show no correlation with Nb and Ta concentrations and Nb/Ta ratios of the parent eclogites, while Nb/Ta ratios of eclogites correlate negatively with the TiO₂ contents.These observations suggest that rutiles were metamorphic products of the Triassic ultrahigh pressure (UHP) metamorphism, rather than formed by crystallization in equilibrium with melt.The partially decoupling between rutiles and parent eclogites in terms of Nb/Ta ratios implies that although rutiles are the dominant carriers of Nb and Ta in eclogites, they might not completely reflect the Nb/Ta ratios of the parent eclogites, especially for low-Ti eclogites (TiO₂ < 0.5%).Nb/Ta ratios of rutiles are dominated by the combination of Nb, Ta and TiO₂ contents of the parent eclogites.The positive correlations between temperatures recorded by Zr contents and the size of rutile indicate that Zr in rutile was not immediately closed after rutile formation.On the other hand, the enrichments of Pb and Sr at the rim of the interstitial rutiles suggest influence of subsequent fluids on the compositions of rutiles, which could have affected Zr of the rutiles as well.This study provides the evidence for the Zr diffusion at a high temperature and fluid activity that could have contributed to the lower temperatures (598-827℃) recorded by Zr-in-rutile for the eclogites from the Dabie-Sulu UHP terrane.
- CCSD-MH,
- eclogite,
- rutile,
- trace element,
- Nb/Ta ratio

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References(105)

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沈阳化工大学材料科学与工程学院沈阳 110142

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Distributions and Geodynamic Implications of High Field Strength Elements in Rutile from Ultrahigh Pressure Eclogites

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