冷冻条件下天然包裹体中流体水分子氢键的拉曼光谱特征

张振亮; 吕新彪; 黄智龙; 董福辰; 高永伟

doi:10.3799/dqkx.2013.035

Volume 38 Issue 2

Mar. 2013

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Article Navigation > Earth Science > 2013 > 38(2): 362-366

ZHANG Zhen-liang, LV Xin-biao, HUANG Zhi-long, DONG Fu-chen, GAO Yong-wei, 2013. Raman Spectroscopic Study on Hydrogen Bond of Water Molecules in Natural Inclusions under the Conditions of Freezing. Earth Science, 38(2): 362-366. doi: 10.3799/dqkx.2013.035

Citation:

ZHANG Zhen-liang, LV Xin-biao, HUANG Zhi-long, DONG Fu-chen, GAO Yong-wei, 2013. Raman Spectroscopic Study on Hydrogen Bond of Water Molecules in Natural Inclusions under the Conditions of Freezing. Earth Science, 38(2): 362-366. doi: 10.3799/dqkx.2013.035

Citation:

ZHANG Zhen-liang, LV Xin-biao, HUANG Zhi-long, DONG Fu-chen, GAO Yong-wei, 2013. Raman Spectroscopic Study on Hydrogen Bond of Water Molecules in Natural Inclusions under the Conditions of Freezing. Earth Science, 38(2): 362-366. doi: 10.3799/dqkx.2013.035

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Raman Spectroscopic Study on Hydrogen Bond of Water Molecules in Natural Inclusions under the Conditions of Freezing

doi: 10.3799/dqkx.2013.035

1.
Xi'an Institute of Geology and Minerals Resources, CGS, Xi'an710054, China
2.
Faculty of Resources, China University of Geosciences, Wuhan430074, China
3.
State key Laboratory of Ore Deposit Geochemistry, Chinese Academy of Sciences, Guiyang550002, China

Received Date: 2012-04-15
Publish Date: 2013-03-01

Abstract

Abstract

The Raman spectroscopy of water is combined by O-H stretching vibration peaks with hydrogen bond and O-H stretching vibration peaks with no hydrogen bond in 3 100-3 700 cm^-1, which all include symmetric and anti-symmetric stretching fundamentals. So the intensity of hydrogen bonding of H₂O molecules in fluid can be obtained by studying on the Raman spectroscopy of water. The hydrogen bonding of water in natural fluid inclusions under the condition of freezing is studied by in-site analysis with a Renishaw MK1-1000 type laser Raman microprobe. The results show that the stretching vibration with hydrogen bond between different H₂O molecules is the main movement of H₂O molecules below 0 ℃, and the weak stretching vibration with no hydrogen bond in the same molecules is also found in the meantime. The hydrogen bonding of water become stronger with the descent of temperature, and the property of fluid might be discontinuous at -130 to -180 ℃.
- condition of freezing,
- fluid inclusion,
- hydrogen bonding,
- Raman spectroscopy,
- homogeneous fluid,
- geochemistry

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References(27)

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