典型岩溶小流域水体中硝酸盐分布特征及成因:以普定后寨河流域为例

李耕; 韩志伟; 申春华; 曾祥颖

doi:10.3799/dqkx.2019.170

Volume 44 Issue 9

Sep. 2019

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Li Geng, Han Zhiwei, Shen Chunhua, Zeng Xiangying, 2019. Distribution Characteristics and Causes of Nitrate in Waters of Typical Small Karst Catchment: A Case of the Houzhai River Catchment. Earth Science, 44(9): 2899-2908. doi: 10.3799/dqkx.2019.170

Citation:

Li Geng, Han Zhiwei, Shen Chunhua, Zeng Xiangying, 2019. Distribution Characteristics and Causes of Nitrate in Waters of Typical Small Karst Catchment: A Case of the Houzhai River Catchment. Earth Science, 44(9): 2899-2908. doi: 10.3799/dqkx.2019.170

Citation:

Li Geng, Han Zhiwei, Shen Chunhua, Zeng Xiangying, 2019. Distribution Characteristics and Causes of Nitrate in Waters of Typical Small Karst Catchment: A Case of the Houzhai River Catchment. Earth Science, 44(9): 2899-2908. doi: 10.3799/dqkx.2019.170

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Distribution Characteristics and Causes of Nitrate in Waters of Typical Small Karst Catchment: A Case of the Houzhai River Catchment

doi: 10.3799/dqkx.2019.170

1.
Resource and Environmental Engineering College, Guizhou University, Guiyang 550025, China
2.
Key Laboratory of Karst Environment and Geohazard Prevention, Ministry of Natural Resources, Guiyang 550025, China

Received Date: 2019-06-15
Publish Date: 2019-09-15

Abstract

Abstract

The water environment of karst catchment is very susceptible to human activities. Nitrate pollution is a prominent and common problem in karst catchment. It is important to clarify the source, distribution characteristics and formation mechanism of nitrate in waters of karst catchment, which can facilitate the nitrate pollution prevention in karst catchment. The Houzhai River catchment of Puding of Guizhou was selected as the study area. 53 samples of groundwater and surface water were collected for measuring water chemical parameters in May 2017. Water chemical parameters were determined for analyzing the NO₃^- source. Combined with the land use type, the influence of the nitrate spatial distribution was discussed along the flow path. The results show that the order of ion concentration in waters was Ca²⁺ > Mg²⁺ > Na⁺ > K⁺, HCO₃^- > SO₄^2- > NO₃^- > Cl^- in the study area, respectively. The type of water chemistry was HCO₃-Ca. The main source of NO₃^- was the chemical fertilizer. Variations of NO₃^- concentration along the flow path were mainly controlled by the mixing process, and the impact of nitrification and denitrification was not obvious. Waters of 6 sampling sites were obviously polluted by nitrate. The concentration of NO₃^- in waters of the catchment was obviously affected by the land use pattern. NO₃^- concentration increased when waters flowed through farmland or villages, and decreased when they flowed through forest land.
- karst,
- nitrate,
- distribution characteristics,
- formation mechnism,
- land use,
- mixing process,
- hydrogeology

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References(54)

References

Altman, S. J., Parizek, R. R., 1995. Dilution of Nonpoint-Source Nitrate in Groundwater. Journal of Environment Quality, 24(4): 707-718. https://doi.org/10.2134/jeq1995.00472425002400040023x

Babiker, I.S., Mohamed, M.A., Terao, H., et al., 2004. Assessment of Groundwater Contamination by Nitrate Leaching from Intensive Vegetable Cultivation Using Geographical Information System. Environment International, 29(8): 1009-1017. https://doi.org/10.1016/s0160-4120(03)00095-3

Chen, F. J., Li, X. H., Jia, G. D., 2007. The Application of Nitrogen and Oxygen Isotopes in the Study of Nitrate in Rivers. Advances in Earth Science, 22(12): 1251-1257 (in Chinese with English abstract). http://cn.bing.com/academic/profile?id=d9d45d24d1ceaccec7b6f8ca085df8b0&encoded=0&v=paper_preview&mkt=zh-cn

Duan, S. H., Jang, Y. J., Zhang, Y. Z., et al., 2019. Sources of Nitrate in Groundwater and Its Environmental Effects in Karst Trough Valleys: A Case Study of an Underground River System in the Longfeng Trough Valley, Chongqing. Environmental Science, 40(4):1715-1725 (in Chinese with English abstract).

Galloway, J. N., Townsend, A. R., Erisman, J. W., et al., 2008. Transformation of the Nitrogen Cycle: Recent Trends, Questions, and Potential Solutions. Science, 320(5878): 889-892. https://doi.org/10.1126/science.1136674

Gillham, R. W., Cherry, J. A., 1978. Field Evidence of Denitrification in Shallow Groundwater Flow Systems. Water Quality Research Journal, 13(1): 53-72. https://doi.org/10.2166/wqrj.1978.006

Gulis, G., Czompolyova, M., Cerhan, J. R., 2002. An Ecologic Study of Nitrate in Municipal Drinking Water and Cancer Incidence in Trnava District, Slovakia. Environmental Research, 88(3): 182-187. https://doi.org/10.1006/enrs.2002.4331

Guo, Y. M., Ni, J., Liu, L. B., et al., 2018. Estimating Aboveground Biomass Using Pléiades Satellite Image in a Karst Watershed of Guizhou Province, Southwestern China. Journal of Mountain Science, 15(5): 1020-1034. https://doi.org/10.1007/s11629-017-4760-x

Han, Z. W., Tang, C. Y., Wu, P., et al., 2014. Using Stable Isotopes and Major Ions to Identify Hydrological Processes and Geochemical Characteristics in a Typical Karstic Basin, Guizhou, Southwest China. Isotopes in Environmental and Health Studies, 50(1): 62-73. https://doi.org/10.1080/10256016.2013.837904

Hu, X. J., Chen, B., Hu, X. H., et al., 2001. Study on the Model of Rational Land Use in the Karst Areas of the Houzhai River Basin. Carsologica Sinica, 20(4): 305-309 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-ZGYR200104014.htm

Itoh, M., Takemon, Y., Makabe, A., et al., 2011. Evaluation of Wastewater Nitrogen Transformation in a Natural Wetland (Ulaanbaatar, Mongolia) Using Dual-Isotope Analysis of Nitrate. Science of the Total Environment, 409(8): 1530-1538. https://doi.org/10.1016/j.scitotenv.2011.01.019

Ju, X. T., Xing, G. X., Chen, X. P., et al., 2009. Reducing Environmental Risk by Improving N Management in Intensive Chinese Agricultural Systems. Proceedings of the National Academy of Sciences, 106(9): 3041-3046. https://doi.org/10.1073/pnas.0813417106

Li, H., Wen, Z., Xie, X. J., et al., 2017. Hydrochemical Characteristics and Evolution of Karst Groundwater in Sanqiao District of Guiyang City. Earth Science, 42(5): 804-812 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dqkx201705016

Li, L., Ren, F. P., Wang, Z. G., et al., 2014. A Review on Identifying Agricultural NPS Pollution Sources by Using Stable N Isotope. Journal of Yangtze River Scientific Research Institute, 31(7): 21-28 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=cjkxyyb201407004

Li, S. L., Liu, C. Q., 2006. The Character and Application of δ¹⁸O-NO₃^- in the Groundwater of Guiyang. Carsologica Sinica, 25(2): 108-111 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgyr200602004

Liu, C.Q., Li, S.L., Lang, Y.C., et al., 2006.Using δ¹⁵N and δ¹⁸O Values to Identify Nitrate Sources in Karst Ground Water, Guiyang, Southwest China. Environmental Science & Technology, 40(22):6928-6933. https://doi.org/10.1021/es0610129

Lu, L., Cheng, H., Pu, X., et al., 2015.Nitrate Behaviors and Source Apportionment in an Aquatic System from a Watershed with Intensive Agricultural Activities. Environmental Science: Processes & Impacts, 17(1): 131-144. https://doi.org/10.1039/c4em00502c

Shen, S., Ma, T., Du, X., et al., 2017. Dynamic Variations of Nitrogen in Groundwater under Influence of Seasonal Hydrological Condition in Typical Area of Jianghan Plain. Earth Science, 42(5): 674-684 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dqkx201705003

Su, W. C., 1997. Appraisal Study on the Sensitivity of Eco Environment in Karst Region. Carsologica Sinina, 16(1): 57-65 (in Chinese with English abstract). http://en.cnki.com.cn/article_en/cjfdtotal-zgyr701.009.htm

Trudell, M. R., Gillham, R. W., Cherry, J. A., 1986. An In-Situ Study of the Occurrence and Rate of Denitrification in a Shallow Unconfined Sand Aquifer. Journal of Hydrology, 83(3-4): 251-268. https://doi.org/10.1016/0022-1694(86)90155-1

Vitousek, P. M., Naylor, R., Crews, T., et al., 2009. Nutrient Imbalances in Agricultural Development. Science, 324(5934): 1519-1520. https://doi.org/10.1126/science.1170261

Wan, H. T., Xie, C. J., Yang, Y., et al., 1999. The Hydrochemical Characteristics of Houzhai Small Karst Basin, Guizhou. Carsologica Sinica, 18(4): 329-336 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgyr199904005

Wang, J. Y., Wang, J. L., Jin, M. G., 2017. Hydrochemical Characteristics and Formation Causes of Karst Water in Jinan Spring Catchment. Earth Science, 42(5): 821-831 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dqkx201705018

Wang, K. R., Guo, F., Jiang, G. H., et al., 2014. Application of ¹⁵N and ¹⁸O to Nitrogen Pollution Source in Karst Water in Eastern Guilin. China Environmental Science, 34(9): 2223-2230 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zghjkx201409009

Wang, L. C, Xu, Y. P., Zhang, L. F., et al., 2000. The Characteristic Study of Karst Water at Houzhai Underground Basin in Puding County, Guizhou Province. Scientia Geographica Sinica, 20(6): 557-562 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dlkx200006012

Xu, Z. F., Liu, C. Q., 2010. Water Geochemistry of the Xijiang Basin Rivers, South China: Chemical Weathering and CO₂ Consumption. Applied Geochemistry, 25(10): 1603-1614. https://doi.org/10.1016/j.apgeochem.2010.08.012

Yan, Y. N., Ma, T., Zhang, J. W., et al., 2017. Experiment on Migration and Transformation of Nitrate under Interaction of Groundwater and Surface Water. Earth Science, 42(5): 783-792 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dqkx201705014

Yu, H. T., Ma, T., Deng, Y. M., et al., 2017. Hydrochemical Characteristics of Shallow Groundwater in Eastern Jianghan Plain. Earth Science, 42(5): 685-692 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dqkx201705004

Yu, J. B., Zhang, H. S., 1988. Karst Geomorphology in Puding, Guizhou Province. Carsologica Sinica, 7(2):163-172 (in Chinese with English abstract).

Yuan, D. X., 1996. On the Environmental and Geologic Problems of Karst Mountains and Rocks in the South-West China. World Sci-Tech R & D, 15(4):21-23 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=sjkjyjyfz199705009

Yue, F. J., Li, S. L., Liu, C. Q., et al., 2015. Sources and Transport of Nitrate Constrained by the Isotopic Technique in a Karst Catchment: An Example from Southwest China. Hydrological Processes, 29(8): 1883-1893. https://doi.org/10.1002/hyp.10302

Yue, F. J., Liu, C. Q., Li, S. L., et al., 2014. Analysis of δ¹⁵N and δ¹⁸O to Identify Nitrate Sources and Transformations in Songhua River, Northeast China. Journal of Hydrology, 519: 329-339. https://doi.org/10.1016/j.jhydrol.2014.07.026

Zhang, C., Yuan, D. X., 2004. Hydrochemical Variation of Typical Karst Subterranean Stream Basin and Its Relationship with Landuse Change——A Case Study of Houzhai Subterranean Stream Basin, Puding County, Guizhou Province. Journal of Soil Water Conservation, 18(5):134-137, 183 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-TRQS200405032.htm

Zhang, H. S., Shi, Y. L., Yu, J. B., 1987. A Simulation of Karst Runoff Process round Plateau Divide——A Case History of Southern Area of Puding, Guizhou. Carsologica Sinica, 6(4):263-274 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-ZGYR198704000.htm

Zhang, W. L., Wu, S. X., Ji, H. J., et al., 2004. Estimation of Agricultural Non-Point Source Pollution in China and the Alleviating Strategies Ⅰ. Estimation of Agricultural Non-Point Source Pollution in China in Early 21 Century. Scientia Agricultura Sinica, 37(7): 1008-1017 (in Chinese with English abstract). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgnykx200407012

陈法锦, 李学辉, 贾国东, 2007.氮氧同位素在河流硝酸盐研究中的应用.地球科学进展, 22(12):1251-1257. doi: 10.3321/j.issn:1001-8166.2007.12.005

段世辉, 蒋勇军, 张远瞩, 等, 2019.岩溶槽谷区地下河硝酸盐来源及其环境效应:以重庆龙凤槽谷地下河系统为例.环境科学, 40(4):1715-1725. doi: 10.3969/j.issn.1000-6923.2019.04.045

胡绪江, 陈波, 胡兴华, 等, 2001.后寨河喀斯特流域土地资源合理利用模式研究.中国岩溶, 20(4):305-309. doi: 10.3969/j.issn.1001-4810.2001.04.011

李华, 文章, 谢先军, 等, 2017.贵阳市三桥地区岩溶地下水水化学特征及其演化规律.地球科学, 42(5):804-812. http://d.old.wanfangdata.com.cn/Periodical/dqkx201705016

李力, 任斐鹏, 王志刚, 等, 2014.利用氮稳定同位素识别农业面源污染源的研究进展.长江科学院院报, 31(7):21-28. doi: 10.3969/j.issn.1001-5485.2014.07.004

李思亮, 刘丛强, 2006.贵阳地下水硝酸盐氧同位素特征及应用.中国岩溶, 25(2):108-111. doi: 10.3969/j.issn.1001-4810.2006.02.004

沈帅, 马腾, 杜尧, 等, 2017.江汉平原典型地区季节性水文条件影响下氮的动态变化规律.地球科学, 42(5):674-684. http://d.old.wanfangdata.com.cn/Periodical/dqkx201705003

苏维词, 1997.岩溶地区生态环境敏感度评价研究——以乌江流域为例.中国岩溶, 16(1):57-65. http://www.cnki.com.cn/Article/CJFDTotal-ZGYR701.009.htm

万洪涛, 谢传节, 杨勇, 等, 1999.贵州后寨河喀斯特小流域水化学特征.中国岩溶, 18(4):329-336. doi: 10.3969/j.issn.1001-4810.1999.04.005

王珺瑜, 王家乐, 靳孟贵, 2017.济南泉域岩溶水水化学特征及其成因.地球科学, 42(5):821-831. http://d.old.wanfangdata.com.cn/Periodical/dqkx201705018

王开然, 郭芳, 姜光辉, 等, 2014.¹⁵N和¹⁸O在桂林岩溶水氮污染源示踪中的应用.中国环境科学, 34(9):2223-2230. http://d.old.wanfangdata.com.cn/Periodical/zghjkx201409009

王腊春, 许有鹏, 张立峰, 等, 2000.贵州普定后寨地下河流域岩溶水特征研究.地理科学, 20(6):557-562. doi: 10.3969/j.issn.1000-0690.2000.06.012

闫雅妮, 马腾, 张俊文, 等, 2017.地下水与地表水相互作用下硝态氮的迁移转化实验.地球科学, 42(5):783-792. http://d.old.wanfangdata.com.cn/Periodical/dqkx201705014

於昊天, 马腾, 邓娅敏, 等, 2017.江汉平原东部地区浅层地下水水化学特征.地球科学, 42(5):685-692. http://d.old.wanfangdata.com.cn/Periodical/dqkx201705004

俞锦标, 章海生, 1988.贵州普定岩溶地貌.中国岩溶, 7(2):163-172. http://www.cnki.com.cn/Article/CJFDTotal-ZGYR198802015.htm

袁道先, 1996.我国西南岩溶石山的环境地质问题.世界科技研究与发展, 15(4):21-23. doi: 10.1111-j.1748-3743.2009.00179.x/

章程, 袁道先, 2004.典型岩溶地下河流域水质变化与土地利用的关系——以贵州普定后寨地下河流域为例.水土保持学报, 18(5):134-137, 183. doi: 10.3321/j.issn:1009-2242.2004.05.033

章海生, 史运良, 俞锦标, 1987.高原分水岭型喀斯特径流过程模拟——以贵州普定县南部地区为例.中国岩溶, 6(4):263-274. http://www.cnki.com.cn/Article/CJFDTotal-ZGYR198704000.htm

张维理, 武淑霞, 冀宏杰, 等, 2004.中国农业面源污染形势估计及控制对策Ⅰ.21世纪初期中国农业面源污染的形势估计.中国农业科学, 37(7):1008-1017. doi: 10.3321/j.issn:0578-1752.2004.07.012

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Distribution Characteristics and Causes of Nitrate in Waters of Typical Small Karst Catchment: A Case of the Houzhai River Catchment

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