湖南水口山多金属矿区废石堆重金属污染评价及赋存形态分析

陈佳木; 吴志华; 刘文浩; 张晓军; 张晓平; 王琳玲; 周淼; 齐宇彤; 吴云辉

doi:10.3799/dqkx.2021.019

Volume 46 Issue 11

Nov. 2021

Turn off MathJax

Article Contents

Article Navigation > Earth Science > 2021 > 46(11): 4127-4139

Chen Jiamu, Wu Zhihua, Liu Wenhao, Zhang Xiaojun, Zhang Xiaoping, Wang Linling, Zhou Miao, Qi Yutong, Wu Yunhui, 2021. Heavy Metal Pollution Evaluation and Species Analysis of Waste Rock Piles in Shuikoushan, Hunan Province. Earth Science, 46(11): 4127-4139. doi: 10.3799/dqkx.2021.019

Citation:

Chen Jiamu, Wu Zhihua, Liu Wenhao, Zhang Xiaojun, Zhang Xiaoping, Wang Linling, Zhou Miao, Qi Yutong, Wu Yunhui, 2021. Heavy Metal Pollution Evaluation and Species Analysis of Waste Rock Piles in Shuikoushan, Hunan Province. Earth Science, 46(11): 4127-4139. doi: 10.3799/dqkx.2021.019

Citation:

Chen Jiamu, Wu Zhihua, Liu Wenhao, Zhang Xiaojun, Zhang Xiaoping, Wang Linling, Zhou Miao, Qi Yutong, Wu Yunhui, 2021. Heavy Metal Pollution Evaluation and Species Analysis of Waste Rock Piles in Shuikoushan, Hunan Province. Earth Science, 46(11): 4127-4139. doi: 10.3799/dqkx.2021.019

PDF( 3213 KB)

Heavy Metal Pollution Evaluation and Species Analysis of Waste Rock Piles in Shuikoushan, Hunan Province

doi: 10.3799/dqkx.2021.019

1.
School of Earth Resources, China University of Geosciences, Wuhan 430074, China
2.
The 417 Geological Team, Hunan Bureau of Geology and Mineral Exploration and Development, Hengyang 421001, China
3.
School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

Received Date: 2021-01-05
Available Online: 2021-12-04
Publish Date: 2021-11-30

Abstract

Abstract

The Shuikoushan area in Hunan Province is one of the seriously heavy metal pollution areas in Hunan Province. The Longwangshan gold deposit is an important gold deposit in this area. To investigate the pollution source characteristics, pollution pathways, heavy metal mobility, and potential hazards of the waste rock pile of this deposit, a 24 m shallow drilling system was conducted to evaluate the waste rock pile of FS17, and the acidic wastewater from the waste rock pile was collected to analyze the total amount of heavy metals. The single factor index and Nemerow comprehensive pollution index suggest that the FS17 contains large amounts of heavy metals (Cd, Cu, Pb, As, Zn, Ni, and Cr) with an unevenly vertical distribution; the natural leaching water samples have high heavy metal contents. The migration index implies that the FS17 has heavy metal potential migration order of Cd > Ni≈ Zn > Cu > Pb > As > Cr > Fe in shallow layer, and of Cd > Zn > Cu > Ni > Cr > Pb > As > Fe in deep layer. The mobility of heavy metal elements in the shallow layer is greater than that in the deep layer. Thus, in this paper it argues that the FS17 is the main pollution source of heavy metals in this area, and acidic wastewater is the main way to release pollution elements. The heavy metals of Cd, Cu, Zn, and Ni have stronger mobility and are main polluting elements for the surrounding environment. The mobility of Pb, Ni, As is significantly reduced in the deep layer, and its mobility can be weakened by deep burying, and Cr will not pollute the surrounding environment.
- heavy metal,
- chemical speciation,
- migration,
- pollution source,
- FS17 waste rock pile,
- Shuikoushan mining area,
- environmental geology

FullText(HTML)

References(50)

References

Bao, Z., Bain, J., Holland, S.P., et al., 2020. Faro Waste Rock Project: Characterizing Geochemical Heterogeneity in Sulfide- and Carbonate-Rich Waste Rock. Applied Geochemistry, 121: 104691. https://doi.org/10.1016/j.apgeochem.2020.104691

Chai, L., Li, H., Yang, Z., et al., 2017. Heavy Metals and Metalloids in the Surface Sediments of the Xiangjiang River, Hunan, China: Distribution, Contamination, and Ecological Risk Assessment. Environmental Science and Pollution Research, 24(1): 874-885. https://doi.org/10.1007/s11356-016-7872-x

Chen, H.M., 2010. Environmental Soil Science. Science Press, Beijing, 54-58 (in Chinese).

Chen, T.H., Feng, J.H., Xu, X. C., et al., 2002. Simulation Experiments on Weathering and Oxidation of Sulfide Minerals in Mine Tailings. Acta Petrologica et Mineralogica, (3): 298-302 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-YSKW200203012.htm

Fang, X., Peng, B., Wang, X., et al., 2019. Distribution, Contamination and Source Identification of Heavy Metals in Bed Sediments from the Lower Reaches of the Xiangjiang River in Hunan Province, China. Science of the Total Environment, 689: 557-570. https://doi.org/10.1016/j.scitotenv.2019.06.330

Gieré, R., Sidenko, N.V., Lazareva, E.V., 2003. The Role of Secondary Minerals in Controlling the Migration of Arsenic and Metals from High-Sulfide Wastes (Berikul Gold Mine, Siberia). Applied Geochemistry, 18(9): 1347-1359. https://doi.org/10.1016/S0883-2927(03)00055-6

Gong, X., Chen, Z., Luo, Z., 2014. Spatial Distribution, Temporal Variation, and Sources of Heavy Metal Pollution in Groundwater of a Century-Old Nonferrous Metal Mining and Smelting Area in China. Environmental Monitoring and Assessment, 186(12): 9101-9116. https://doi.org/10.1007/s10661-014-4069-y

Jallad, K. N., 2015. Heavy Metal Exposure from Ingesting Rice and Its Related Potential Hazardous Health Risks to Humans. Environmental Science and Pollution Research, 22(20): 15449-15458. https://doi.org/10.1007/s11356-015-4753-7

Kumar, S., Prasad, S., Yadav, K. K., et al., 2019. Hazardous Heavy Metals Contamination of Vegetables and Food Chain: Role of Sustainable Remediation Approaches-A Review. Environmental Research, 179: 108792. https://doi.org/10.1016/j.envres.2019.108792

Lei, L.Q., Luo, Y.H., Song, C.A., et al., 2013. Evaluation and Prediction of Combined Pollution of Heavy Metals from Sulfide Tailing in a Mining Area in Northern Guangxi. Earth Science, 38(5): 1107-1115 (in Chinese with English abstract).

Lei, L. Q., Mo, B.J., Fu, W., et al., 2014. Occurrence of Heavy Metals in Carbonate Sulfide Tailings in Bari. Earth and Environment, 42(5): 604-610 (in Chinese with English abstract).

Li, G., Tong, F.P., Liu, Z.H., 2012. Analysis of Heavy Metal Pollution in Shuikou Mountain Lead and Zinc Mine in Hengyang. Journal of Central South University of Forestry and Technology, 32(7): 105-109 (in Chinese with English abstract).

Li, G., Tong, F.P., Liu, Z.H., 2014. Study on Plant Investigate and Species Diversity of Shuikoushan Pb-Zn Mining Area in Hengyang. Chinese Agricultural Science Bulletin, 30(13): 66-70 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-ZNTB201413014.htm

Liu, B., Li, T.Y., Cai, Y.Y., 2018. A Brief Introduction of Current Situation, Harm and Repair Methods of "Cadmium Rice". Modern Food, (21): 86-89 (in Chinese with English abstract).

Lu, Y.J., 2020. The Study of Prospecting Direction and Ore-Controlling Factor of Longwangshan Gold Deposit in Hunan Province. Mineral Resources and Geology, 34(3): 408-414 (in Chinese with English abstract).

Lü, J.R., Wang, Z.W., Liu, Y. M., et al., 2019. Migration of Heavy Metals in Alkaline Saline Surface Soil during Wet-Dry Alternating Process. Journal of Tianjin Normal University (Natural Science Edition), 39(5): 57-63 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-TJSD201905010.htm

Nieva, N.E., Borgnino, L., García, M.G., 2018. Long Term Metal Release and Acid Generation in Abandoned Mine Wastes Containing Metal-Sulphides. Environmental Pollution, 242: 264-276. https://doi.org/10.1016/j.envpol.2018.06.067

Peng, B., Tang, X.Y., Yu, C.X., et al., 2011. Heavy Metal Contamination of Inlet Sediments of the Xiangjiang River and Pb Isotopic Geochemical Implication. Acta Geologica Sinica, 85(2): 282-299 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DZXE201102015.htm

Smuda, J., Dold, B., Friese, K., et al., 2007. Mineralogical and Geochemical Study of Element Mobility at the Sulfide-Rich Excelsior Waste Rock Dump from the Polymetallic Zn-Pb-(Ag-Bi-Cu) Deposit, Cerro de Pasco, Peru. Journal of Geochemical Exploration, 92(2-3): 97-110. https://doi.org/10.1016/j.gexplo.2006.08.001

St-Arnault, M., Vriens, B., Blaskovich, R., et al., 2020. Geochemical and Mineralogical Assessment of Reactivity in a Full-Scale Heterogeneous Waste-Rock Pile. Minerals Engineering, 145: 106089. https://doi.org/10.1016/j.mineng.2019.106089

Sun, X., Ning, P., Tang, X., et al., 2012. Heavy Metals Migration in Soil in Tailing Dam Region of Shuikoushan, Hunan Province, China. Procedia Environmental Sciences, 16: 758-763. https://doi.org/10.1016/j.proenv.2012.10.103

Vriens, B., Peterson, H., Laurenzi, L., et al., 2019. Long-Term Monitoring of Waste-Rock Weathering at the Antamina Mine, Peru. Chemosphere, 215: 858-869. https://doi.org/10.1016/j.chemosphere.2018.10.105

Wang, J.Y., Lai, J.Q., 2019. Geological Characteristics and Prospecting Criteria of Longwangshan Gold Deposit in Shuikou Mountain Orefield, Hunan Province. Southern Metals, (4): 8-13 (in Chinese with English abstract).

Wei, C.W., Wang, C., Yang, L.S., 2009. Characterizing Spatial Distribution and Sources of Heavy Metals in the Soils from Mining-Smelting Activities in Shuikoushan, Hunan Province, China. Journal of Environmental Science, 21(9): 1230-1236. https://doi.org/10.1016/s1001-0742(08)62409-2

Wei, F.S., Chen, J.S., Wu, Y.Y., et al., 1991. Research on the Background Value of Soil Environment in China. Environmental Science, 12(4): 12-19, 94 (in Chinese with English abstract).

Wen, D.G., Lin, L.J., Sun, J.C., et al., 2012. Groundwater Quality and Contamination Assessment in the Main Plains of Eastern China. Earth Science, 37(2): 220-228 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DQKX201202005.htm

Wu, K.Z., Gao, Z.G., Liu, J.L., 2009. Geological Characteristics and Prospecting Prediction of Longwangshan Gold Deposit. West-China Exploration Engineering, 21(9): 105-108 (in Chinese).

Yan, Y.Q., 2019. Analysis on the Status Quo of Water Pollution Control in Xiangjiang River Basin. China Resources Comprehensive Utilization, 37(12): 36-38 (in Chinese with English abstract).

Yang, H. J., Xu, Y. H., Liu, Y. B., et al., 2018. Environmental Health Risk Assessment of Shuikou Mountain Section of Hengyang in Xiangjiang River Basin. Environmental Chemistry, 37(9): 2060-2070 (in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-HJHX201809021.htm

Yin, J.Z., Wang, M.C., 1993. Geological Characteristics and Genesis of Longwangshan Gold Deposit in Shuikou Mountain Orefield, Hunan Province. Gold Geology, (3): 46-50 (in Chinese).

Zhang, L., Zhao, G., 1996. The Species and Geochemical Characteristics of Heavy Metals in the Sediments of Kangjiaxi River in the Shuikoushan Mine Area, China. Applied Geochemistry, 11(1): 217-222. https://doi.org/10.1016/0883-2927(95)00096-8

Zhu, Y. M., Feng, R. W., Wei, C.Y., 2012. The Effectiveness of Arsenic in Paddy Soil and Vegetable Soil of Shuikou Mountain. Journal of Ecology, 31(10): 2657-2661 (in Chinese with English abstract).

陈怀满, 2010. 环境土壤学. 北京: 科学出版社, 54-58.

陈天虎, 冯军会, 徐晓春, 等, 2002. 尾矿中硫化物风化氧化模拟实验研究. 岩石矿物学杂志, 21(3): 298-302. doi: 10.3969/j.issn.1000-6524.2002.03.013

雷良奇, 罗远红, 宋慈安, 等, 2013. 桂北某矿区硫化物尾矿重金属复合污染评价预测. 地球科学, 38(5): 1107-1115. doi: 10.3799/dqkx.2013.109

雷良奇, 莫斌吉, 付伟, 等, 2014. 巴里富碳酸盐硫化物尾矿中重金属的赋存状态. 地球与环境, 42(5): 604-610. https://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ201405004.htm

李贵, 童方平, 刘振华, 2012. 衡阳水口山铅锌矿区重金属污染现状的分析. 中南林业科技大学学报, 32(7): 105-109. https://www.cnki.com.cn/Article/CJFDTOTAL-ZNLB201207023.htm

李贵, 童方平, 刘振华, 等, 2014. 衡阳水口山铅锌矿区植被调查及物种多样性分析. 中国农学通报, 30(13): 66-70. https://www.cnki.com.cn/Article/CJFDTOTAL-ZNTB201413014.htm

刘斌, 黎天勇, 蔡扬尧, 2018. "镉大米"的现状、危害及修复方法简述. 现代食品, (21): 86-89. https://www.cnki.com.cn/Article/CJFDTOTAL-SPXD201821031.htm

卢玉杰, 2020. 湖南龙王山金矿床控矿因素及找矿方向探讨. 矿产与地质, 34(3): 408-414. https://www.cnki.com.cn/Article/CJFDTOTAL-KCYD202003002.htm

吕佳芮, 王祖伟, 刘雅明, 等, 2019. 干湿交替过程中重金属在碱性盐化表层土壤中的迁移特征. 天津师范大学学报(自然科学版), 39(5): 57-63. https://www.cnki.com.cn/Article/CJFDTOTAL-TJSD201905010.htm

彭渤, 唐晓燕, 余昌训, 等, 2011. 湘江入湖河段沉积物重金属污染及其Pb同位素地球化学示踪. 地质学报, 85(2): 282-299. https://www.cnki.com.cn/Article/CJFDTOTAL-DZXE201102015.htm

王金艳, 赖健清, 2019. 湖南省水口山矿田龙王山金矿床地质特征及找矿标志. 南方金属, (4): 8-13. https://www.cnki.com.cn/Article/CJFDTOTAL-NFGT201904004.htm

魏复盛, 陈静生, 吴燕玉, 等, 1991. 中国土壤环境背景值研究. 环境科学, 12(4): 12-19, 94. https://www.cnki.com.cn/Article/CJFDTOTAL-HJKZ199104006.htm

文冬光, 林良俊, 孙继朝, 等, 2012. 中国东部主要平原地下水质量与污染评价. 地球科学, 37(2): 220-228. doi: 10.3799/dqkx.2012.022

吴康忠, 高中贵, 柳佳良, 2009. 龙王山金矿床地质特征及找矿预测. 西部探矿工程, 21(9): 105-108. https://www.cnki.com.cn/Article/CJFDTOTAL-XBTK200909044.htm

严艺琪, 2019. 浅析湘江流域水污染的治理现状. 中国资源综合利用, 37(12): 36-38. https://www.cnki.com.cn/Article/CJFDTOTAL-ZWZS201912010.htm

杨海君, 许云海, 刘亚宾, 等, 2018. 湘江流域衡阳水口山段水环境健康风险评估. 环境化学, 37(9): 2060-2070. https://www.cnki.com.cn/Article/CJFDTOTAL-HJHX201809021.htm

银剑钊, 王敏初, 1993. 湖南省水口山矿田龙王山金矿床地质特征及成因. 黄金地质科技, (3): 46-50. https://www.cnki.com.cn/Article/CJFDTOTAL-HJDZ199303008.htm

朱雁鸣, 冯人伟, 韦朝阳, 2012. 水口山水稻土与菜地土中砷的有效性. 生态学杂志, 31(10): 2657-2661. https://www.cnki.com.cn/Article/CJFDTOTAL-STXZ201210036.htm

Relative Articles

Supplements(0)

Cited By

Proportional views

Proportional views

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Figures(3) / Tables(5)

Get Citation

PDF

XML

Article views (1180) PDF downloads(84)

Heavy Metal Pollution Evaluation and Species Analysis of Waste Rock Piles in Shuikoushan, Hunan Province

doi: 10.3799/dqkx.2021.019

Abstract

References

Proportional views

Catalog

通讯作者: 陈斌, bchen63@163.com

Proportional views

Export File

Citation

Format

Content