豫北山前平原深层地下水硫酸盐来源与污染途径的同位素示踪

邹霜; 张东; 李小倩; 吴洋洋; 李玉红; 朱双双; 刘运涛; 段慧真; 郭文静

doi:10.3799/dqkx.2021.043

Volume 47 Issue 2

Feb. 2022

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Article Navigation > Earth Science > 2022 > 47(2): 700-716

Zou Shuang, Zhang Dong, Li Xiaoqian, Wu Yangyang, Li Yuhong, Zhu Shuangshuang, Liu Yuntao, Duan Huizhen, Guo Wenjing, 2022. Sources and Pollution Pathways of Deep Groundwater Sulfate Underneath the Piedmont Plain in the North Henan Province. Earth Science, 47(2): 700-716. doi: 10.3799/dqkx.2021.043

Citation:

Zou Shuang, Zhang Dong, Li Xiaoqian, Wu Yangyang, Li Yuhong, Zhu Shuangshuang, Liu Yuntao, Duan Huizhen, Guo Wenjing, 2022. Sources and Pollution Pathways of Deep Groundwater Sulfate Underneath the Piedmont Plain in the North Henan Province. Earth Science, 47(2): 700-716. doi: 10.3799/dqkx.2021.043

Citation:

Zou Shuang, Zhang Dong, Li Xiaoqian, Wu Yangyang, Li Yuhong, Zhu Shuangshuang, Liu Yuntao, Duan Huizhen, Guo Wenjing, 2022. Sources and Pollution Pathways of Deep Groundwater Sulfate Underneath the Piedmont Plain in the North Henan Province. Earth Science, 47(2): 700-716. doi: 10.3799/dqkx.2021.043

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Sources and Pollution Pathways of Deep Groundwater Sulfate Underneath the Piedmont Plain in the North Henan Province

doi: 10.3799/dqkx.2021.043

1.
School of Resource and Environment, Henan Polytechnic University, Jiaozuo 454000, China
2.
School of Environmental Studies, China University of Geosciences, Wuhan 430074, China
3.
The Fifth Institute of Geo-Exploration, Henan Bureau of Geo-Exploration & Mineral Development, Zhengzhou 450001, China
4.
Henan Province Research Center on Applied Engineering Technology of Hydrogeology, Zhengzhou 450001, China

Received Date: 2021-04-19
Publish Date: 2022-02-25

Abstract

Abstract

Deep groundwater sulfate in the piedmont alluvial plain in Jiaozuo had been increasing, however, the mechanism is still unclear. To illustrate the pollution mechanism of deep groundwater, deep groundwater in different hosting conditions was sampled to compare, and hydro-chemical compositions, hydrogen and oxygen isotopes (δD_H2O and δ¹⁸O_H2O), sulfate sulfur and oxygen isotopes (δ³⁴S_SO4 and δ¹⁸O_SO4) were determined to constrain the sulfate sources, pollution pathways and sulfate bacterial reduction processes with the presence of anthropogenic activities. The results indicated that there were small variations of monthly hydro-chemical and isotope compositions in respective deep groundwaters, but large spatial differences were found in the hydro-chemical compositions of these deep groundwater. Sulfate in the undisturbed deep groundwater was mainly derived from atmospheric deposition, pyrite oxidation and gypsum dissolution, and the bacterial sulfate reduction obviously occurred; There were two kinds of pollution pathways and processes in the polluted deep groundwater. First was that in the piedmont where deep groundwater was recharged, due to no obvious aquifuge between them, the precipitation and river water containing industrial wastes could easily infiltrate into deep groundwater with the result of increasing sulfate concentrations. Second was that in the discharge zone, increased deep groundwater sulfate was related with leapfrog recharge from the above aquifer where sulfate was rich, and the leapfrog recharge was due to overwhelming deep groundwater pumping. Our results well illustrated the sulfate pollution mechanism in deep groundwater underneath the piedmont alluvial plain in Jiaozuo, and provided vitally scientific evidences on effective management and protection of deep groundwater source.
- sulfate sources,
- groundwater bacterial sulfate reduction,
- sulfur and oxygen isotope tracing,
- Bayesian isotope mixing model,
- Piedmont alluvial plain,
- hydrogeology

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References(76)

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Sources and Pollution Pathways of Deep Groundwater Sulfate Underneath the Piedmont Plain in the North Henan Province

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