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| Citation: | Jin Song, Ma Pengfei, Guo Hua, Yu Wenchao, Xu Lingtong, Lin Qian, 2022. Genesis of Mesoproterozoic Gaoyuzhuang Formation Manganese Ore in Qinjiayu, East Hebei: Constraints from Mineralogical and Geochemical Evidences. Earth Science, 47(1): 277-289. doi: 10.3799/dqkx.2021.055
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The Qinjiayu manganese ore in East Hebei occur mainly in manganese-bearing rock series at the bottom of the second member of the Mesoproterozoic Gaoyuzhuang Formation, however, the cause of manganese ore is unclear. In this paper, it uses microscopic observation, electronic microprobe analysis and whole rock geochemical analysis based on the drilling core ZK58-2 samples to provide information on the manganese sources and sedimentary environments which contribute to manganese mineralization. Microscopic examination and electronic microprobe analysis show that manganese-bearing minerals of primary ore belt samples are dominated by rhodochrosite, Fe-Mg rhodochrosite, Ca rhodochrosite and Mn calcite. Compared with based samples, the major elements of the manganese ore belt samples show low TiO2, SiO2, Al2O3, K2O and Na2O contents. Besides, all samples show negative correlation between manganese and Al2O3 contents. The trace elements of all samples show no enrichment relative to the upper crust content (UCC), except Th and U. Th/U ratios and authigenic Th/U ratios have similar stratigraphical tendency, with low Fe/Mn ratios, indicating that paleo-ocean environment was dominated by oxic-suboxic conditions. UCC-normalized REE+Y patterns are flat, showing no Ce anomaly (Ce/Ce*=1.00±0.02, n=39) and low Y/Ho ratios. Initial 87Sr/86Sr ratios of Mn ore belt are between 0.713 383 and 0.725 378, having an average value of 0.720 180, showing a negative correlation with Al2O3 contents. Comprehensive sedimentary and geochemical analyses show that Mn sourced from both hydrothermal fluids and continental weathering input. Manganese sources, combined with paleo-ocean oxidation and sea level fluctuations, controlled the Gaoyuzhuang manganese ore.
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