黄河小浪底水库水沙调控与流域硫循环

张东; 朱双双; 赵志琦; 李玉红; 杨锦媚; 段慧真; 郭文静; 刘运涛

doi:10.3799/dqkx.2021.109

Volume 47 Issue 2

Feb. 2022

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Article Navigation > Earth Science > 2022 > 47(2): 589-606

Zhang Dong, Zhu Shuangshuang, Zhao Zhiqi, Li Yuhong, Yang Jinmei, Duan Huizhen, Guo Wenjing, Liu Yuntao, 2022. The Water-Sediment Regulation Scheme at Xiaolangdi Reservoir and Its Impact on Sulfur Cycling in the Yellow River Basin. Earth Science, 47(2): 589-606. doi: 10.3799/dqkx.2021.109

Citation:

Zhang Dong, Zhu Shuangshuang, Zhao Zhiqi, Li Yuhong, Yang Jinmei, Duan Huizhen, Guo Wenjing, Liu Yuntao, 2022. The Water-Sediment Regulation Scheme at Xiaolangdi Reservoir and Its Impact on Sulfur Cycling in the Yellow River Basin. Earth Science, 47(2): 589-606. doi: 10.3799/dqkx.2021.109

Citation:

Zhang Dong, Zhu Shuangshuang, Zhao Zhiqi, Li Yuhong, Yang Jinmei, Duan Huizhen, Guo Wenjing, Liu Yuntao, 2022. The Water-Sediment Regulation Scheme at Xiaolangdi Reservoir and Its Impact on Sulfur Cycling in the Yellow River Basin. Earth Science, 47(2): 589-606. doi: 10.3799/dqkx.2021.109

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The Water-Sediment Regulation Scheme at Xiaolangdi Reservoir and Its Impact on Sulfur Cycling in the Yellow River Basin

doi: 10.3799/dqkx.2021.109

1.
School of Resource and Environment, Henan Polytechnic University, Jiaozuo 454000, China
2.
School of Earth Science and Resources, Chang'an University, Xi'an 710054, China
3.
The Fifth Institute of Geo-Exploration, Henan Bureau of Geo-Exploration & Mineral Development, Zhengzhou 450001, China
4.
Henan Province Research Center on Applied Engineering Technology of Hydrogeology, Zhengzhou 450001, China

Received Date: 2021-11-06
Publish Date: 2022-02-25

Abstract

Abstract

Weathering-derived sulfate (SO₄^2-) from the Continent could be transported to the Ocean by river systems, and sulfate flux coupled with sulfur and oxygen isotope compositions (δ³⁴S_SO4 and δ¹⁸O_SO4) were vital to the global sulfur cycling and sulfate isotope compositions in ocean. SO₄^2- contents together with δ³⁴S_SO4and δ¹⁸O_SO4 values were not only controlled by SO₄^2- sources, but affected by sulfate bacterial reduction (SBR) in internal riversystem, however, these effects were still unclear, and particularly the influences from dam and water-sediment regulation scheme (WSRS) on sulfur cycling in watershed were still unknown. The Xiaolangdi Reservoir in the Yellow River was selected to solve this problem, and hydrochemical compositions, water isotope compositions (δD_H2O and δ¹⁸O_H2O), and δ³⁴S_SO4and δ¹⁸O_SO4 were determined to constrain the effects of WSRS on riverine sulfate flux and isotope compositions by comparing the SO₄^2- contents and isotope compositions before and after the WSRS. The results indicated that (1) WSRS occurred in July 2018, sediment discharge in August was due to sediment scoured by precipitation in midstream of Yellow River. The discharged river water during these two sediment removal had average δ¹⁸O_H2O values of -8.1‰ and -8.9‰, and average SO₄^2- concentrations of 1.43 mmol/L and 1.77 mmol/L, and average δ³⁴S_SO4 values of 8.3‰ and 7.4‰, and average δ¹⁸O_SO4 values of 5.4‰ and 5.7‰, respectively. (2) The dischared river water before the WSRS (June) had positive average ¹⁸O_H2O value of -7.0‰, moderate average SO₄^2- concentration of 1.59 mmol/L, positive average δ³⁴S_SO4 and δ¹⁸O_SO4values of 8.0‰ and 7.5‰, resepectively. The dischared river water after the WSRS (October) had negative average δ¹⁸O_H2O value of -9.2‰, low average SO₄^2- concentration of 1.26 mmol/L, negative average δ³⁴S_SO4 value of 6.7‰ and positive average δ¹⁸O_SO4value of 7.3‰, respectively. (3) The WSRS in July resulted in the exposure of sediment, and the organic sulfur and sulfide from SBR had been reoxidized to sulfate, during which water oxygen was incorporated into fresh sulfate with low oxygen isotope composition, but there was small varitaion of δ³⁴S_SO4 and δ¹⁸O_SO4values in downstream river water. (4) The SO₄^2- flux was about 0.061 Tmol/a in 2018, and the proporation of SO₄^2- flux during WSRS was about 14.8%. The flow-weighted average δ³⁴S_SO4 and δ¹⁸O_SO4values of SO₄^2- into the Ocean were 7.6‰ and 6.8‰, respectively. The conclusion is that the WSRS had altered the water-sediment environment in the Yellow River, and corresponding organic and sulfide were released into the air and reoxidized, which changed the sulfate flux and sulfur and oxygen isotope compostion to the Ocean.
- sulfate,
- sulfur and oxygen isotopes,
- Xiaolangdi reservoir in the Yellow River,
- water-sediment regulation scheme,
- sulfur cycling,
- hydrogeology

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The Water-Sediment Regulation Scheme at Xiaolangdi Reservoir and Its Impact on Sulfur Cycling in the Yellow River Basin

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