水化学及硫同位素对大冶矿区地下水硫酸盐污染的指示

曹慧丽; 李伟; 苏春利; 赵乐; 卫方成; 陈志宇; 梁川

doi:10.3799/dqkx.2022.119

Volume 48 Issue 9

Sep. 2023

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Article Navigation > Earth Science > 2023 > 48(9): 3432-3443

Cao Huili, Li Wei, Su Chunli, Zhao Le, Wei Fangcheng, Chen Zhiyu, Liang Chuan, 2023. Indication of Hydrochemistry and δ34S-SO42‒ on Sulfate Pollution of Groundwater in Daye Mining Area. Earth Science, 48(9): 3432-3443. doi: 10.3799/dqkx.2022.119

Citation:

Cao Huili, Li Wei, Su Chunli, Zhao Le, Wei Fangcheng, Chen Zhiyu, Liang Chuan, 2023. Indication of Hydrochemistry and δ³⁴S-SO₄^2‒ on Sulfate Pollution of Groundwater in Daye Mining Area. Earth Science, 48(9): 3432-3443. doi: 10.3799/dqkx.2022.119

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Indication of Hydrochemistry and δ³⁴S-SO₄^2‒ on Sulfate Pollution of Groundwater in Daye Mining Area

doi: 10.3799/dqkx.2022.119

Cao Huili^{1
,
,},
Li Wei²,
Su Chunli^{1
,
,},
Zhao Le¹,
Wei Fangcheng¹,
Chen Zhiyu²,
Liang Chuan²

1.
School of Environmental Studies, China University of Geosciences, Wuhan 430078, China
2.
Geological Environmental Center of Hubei Province, Wuhan 430034, China

Received Date: 2022-01-10
Available Online: 2023-10-07
Publish Date: 2023-09-25

Abstract

Abstract

Sulfate pollution of groundwater around copper and iron mining areas is a hot issue in ecological environment research. It is very important to identify the sources and migration routes of sulfate in the groundwater system for the prevention of groundwater pollution and the safety of water supply in the mining area. Combined with the hydrogeological setting and the distribution of potential pollutant sources in the mining area, the coupled analysis of hydrochemistry and δ³⁴S-SO₄^2‒ was carried to explore the characteristics, sources and migration pathways of groundwater sulfate pollution in the area. The results show that the groundwater in the area included the pore water in the sedimentary aquifers, the karst water of carbonatite and the fissure water of igneous rocks. The main hydrochemical type was HCO₃·SO₄-Ca. The formation of hydrochemical components mainly included the dissolution of silicate, carbonate and sulfate minerals, as well as the oxidation of sulfide. The content of SO₄^2‒ ranged between 44.4 mg/L and 2 089.0 mg/L. The groundwater with elevated SO₄^2‒ concentration occurred near the Hongshan River tailings reservoir, the slag heap and the industrial areas. The value of δ³⁴S in regional groundwater ranged between 2.6‰ and 31.5‰, indicating that SO₄^2‒ came from multiple sources. The sources of sulfate in groundwater included the dissolution of gypsum, the oxidation of sulfide such as pyrite. The maximum of SO₄^2‒ attributed to the oxidization of pyrite. Mine drainage, tailing leakage, the settling of dust and wastewater infiltration were the main pathways of groundwater pollution.
- Daye mining area,
- hydrogeochemistry,
- source of sulfate,
- sulfur isotope,
- groundwater,
- environmental engineering

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Indication of Hydrochemistry and δ34S-SO42‒ on Sulfate Pollution of Groundwater in Daye Mining Area

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Indication of Hydrochemistry and δ³⁴S-SO₄^2‒ on Sulfate Pollution of Groundwater in Daye Mining Area